全文获取类型
收费全文 | 1678篇 |
免费 | 38篇 |
国内免费 | 4篇 |
专业分类
化学 | 1012篇 |
晶体学 | 5篇 |
力学 | 14篇 |
数学 | 368篇 |
物理学 | 321篇 |
出版年
2021年 | 15篇 |
2020年 | 17篇 |
2019年 | 16篇 |
2016年 | 18篇 |
2015年 | 18篇 |
2014年 | 36篇 |
2013年 | 59篇 |
2012年 | 36篇 |
2011年 | 61篇 |
2010年 | 42篇 |
2009年 | 32篇 |
2008年 | 46篇 |
2007年 | 53篇 |
2006年 | 49篇 |
2005年 | 42篇 |
2004年 | 30篇 |
2003年 | 33篇 |
2002年 | 35篇 |
2001年 | 27篇 |
2000年 | 18篇 |
1998年 | 15篇 |
1997年 | 17篇 |
1996年 | 27篇 |
1995年 | 32篇 |
1994年 | 28篇 |
1993年 | 25篇 |
1992年 | 27篇 |
1991年 | 15篇 |
1990年 | 19篇 |
1989年 | 22篇 |
1988年 | 26篇 |
1987年 | 15篇 |
1986年 | 14篇 |
1985年 | 24篇 |
1983年 | 11篇 |
1982年 | 14篇 |
1981年 | 14篇 |
1979年 | 19篇 |
1978年 | 20篇 |
1977年 | 14篇 |
1975年 | 13篇 |
1974年 | 17篇 |
1973年 | 22篇 |
1971年 | 12篇 |
1970年 | 18篇 |
1969年 | 17篇 |
1968年 | 15篇 |
1966年 | 20篇 |
1923年 | 15篇 |
1885年 | 11篇 |
排序方式: 共有1720条查询结果,搜索用时 21 毫秒
71.
Ludwig Hermann 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-3):176-178
Abstract Human and animal excrements, in particular manure, stand for a significant and undisputable source of plant nutrients and renewable energy. In Europe, only 36% of P-inputs to soils originate from primary resources (rock phosphate) whereas 63% come from animal and human excretions applied to cropland as manure, digestion residues and sewage sludge. Simultaneously these waste flows represent a potential hazard to human health and aquatic bodies because of pathogens and eutrophication. Management of these waste flows is far from being sustainable, in part due to the lack of efficient processing technologies. A cooperative InnoEnergy—EIT financed KIC Knowledge and Innovation Community—research project pursues development and demonstration of highly efficient technologies to overcome the constraints and to yield renewable phosphate fertilizers and energy from waste flows that may have a combined technical energy potential of 3,600 PJ/year and an annual phosphate recovery potential of 4.5–5.5 million tonnes (as P2O5) in Europe. 相似文献
72.
A novel approach for the syntheses of carbene adduct 4 is reported. A ring-enlargement strategy was employed for the synthesis of precursors 5 and 6 and established the mechanism of the formation of azulene derivative 6. Synthesis of target precursor 13, a novel precursor for the synthesis of new mesogenic materials, and its various halogenated derivatives (14–16) was carried out. 相似文献
73.
Emmanuel Urandu Mapesa Ludwig Popp Wycliffe Kiprop Kipnusu Martin Tress Friedrich Kremer 《Soft Materials》2014,12(4):S22-S30
Broadband Dielectric Spectroscopy (BDS) is used to probe the molecular dynamics of Type A polymer, poly(cis-1,4-isoprene), when confined in the 1-dimensional (1D) exploring space of thin layers and the 2-dimensional (2D) constraining geometry of unidirectional anodic aluminum oxide (AAO) nanopores. For both cases, it was observed that the structural relaxation remains bulk-like in its mean relaxation rate, although the distribution of its relaxation times is broadened in 2D confinement. Furthermore, the fluctuation of the end-to-end vector is interrupted, with the 1D case being relatively less pronounced. By this clear-cut comparison, it is demonstrated that the effects of confinement on molecular dynamics depend, inter alia, on the dimensionality of the restricting space. 相似文献
74.
Sren Arlt Vladana Petkovi Gerd Ludwig Thomas Eichhorn Heinrich Lang Tobias Rüffer Sanja Mijatovi Danijela Maksimovi-Ivani Goran N. Kaluerovi 《Molecules (Basel, Switzerland)》2021,26(7)
Neutral [Ru(η6-arene)Cl2{Ph2P(CH2)3SPh-κP}] (arene = benzene, indane, 1,2,3,4-tetrahydronaphthalene: 2a, 2c and 2d) and cationic [Ru(η6-arene)Cl(Ph2P(CH2)3SPh-κP,κS)]X complexes (arene = mesitylene, 1,4-dihydronaphthalene; X = Cl: 3b, 3e; arene = benzene, mesitylene, indane, 1,2,3,4-tetrahydronaphthalene, and 1,4-dihydronaphthalene; X = PF6: 4a–4e) complexes were prepared and characterized by elemental analysis, IR, 1H, 13C and 31P NMR spectroscopy and also by single-crystal X-ray diffraction analyses. The stability of the complexes has been investigated in DMSO. Complexes have been assessed for their cytotoxic activity against 518A2, 8505C, A253, MCF-7 and SW480 cell lines. Generally, complexes exhibited activity in the lower micromolar range; moreover, they are found to be more active than cisplatin. For the most active ruthenium(II) complex, 4b, bearing mesitylene as ligand, the mechanism of action against 8505C cisplatin resistant cell line was determined. Complex 4b induced apoptosis accompanied by caspase activation. 相似文献
75.
Simin Cao Haoyang Li Zenan Zhao Sanjun Zhang Jinquan Chen Jianhua Xu Jay R. Knutson Ludwig Brand 《Molecules (Basel, Switzerland)》2021,26(1)
In this review, the experimental set-up and functional characteristics of single-wavelength and broad-band femtosecond upconversion spectrophotofluorometers developed in our laboratory are described. We discuss applications of this technique to biophysical problems, such as ultrafast fluorescence quenching and solvation dynamics of tryptophan, peptides, proteins, reduced nicotinamide adenine dinucleotide (NADH), and nucleic acids. In the tryptophan dynamics field, especially for proteins, two types of solvation dynamics on different time scales have been well explored: ~1 ps for bulk water, and tens of picoseconds for “biological water”, a term that combines effects of water and macromolecule dynamics. In addition, some proteins also show quasi-static self-quenching (QSSQ) phenomena. Interestingly, in our more recent work, we also find that similar mixtures of quenching and solvation dynamics occur for the metabolic cofactor NADH. In this review, we add a brief overview of the emerging development of fluorescent RNA aptamers and their potential application to live cell imaging, while noting how ultrafast measurement may speed their optimization. 相似文献
76.
We study the interaction between two adjacent but electrically isolated quantum point contacts (QPCs). At high enough source-drain bias on one QPC, the drive QPC, we detect a finite electric current in the second, unbiased, detector QPC. The current generated at the detector QPC always flows in the opposite direction than the current of the drive QPC. The generated current is maximal, if the detector QPC is tuned to a transition region between its quantized conductance plateaus and the drive QPC is almost pinched-off. We interpret this counterflow phenomenon in terms of an asymmetric phonon-induced excitation of electrons in the leads of the detector QPC. 相似文献
77.
Leon N. Schneider Dr. Eva-Maria Tanzer Krauel Dr. Carl Deutsch Dr. Klaus Urbahns Tobias Bischof Kristina A. M. Maibom Dr. Johannes Landmann Dr. Fabian Keppner Dr. Christoph Kerpen Dr. Michael Hailmann Ludwig Zapf Tanja Knuplez Dr. Rüdiger Bertermann Dr. Nikolai V. Ignat'ev Prof. Dr. Maik Finze 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(42):10973-10978
Fluorinated groups are essential for drug design, agrochemicals, and materials science. The bis(trifluoromethyl)amino group is an example of a stable group that has a high potential. While the number of molecules containing perfluoroalkyl, perfluoroalkoxy, and other fluorinated groups is steadily increasing, examples with the N(CF3)2 group are rare. One reason is that transfer reagents are scarce and metal-based storable reagents are unknown. Herein, a set of CuI and AgI bis(trifluoromethyl)amido complexes stabilized by N- and P-donor ligands with unprecedented stability are presented. The complexes are stable solids that can even be manipulated in air for a short time. They are bis(trifluoromethyl)amination reagents as shown by nucleophilic substitution and Sandmeyer reactions. In addition to a series of benzylbis(trifluoromethyl)amines, 2-bis(trifluoromethyl)amino acetate was obtained, which, upon hydrolysis, gives the fluorinated amino acid N,N-bis(trifluoromethyl)glycine. 相似文献
78.
79.
Aysu Yarman Christopher Schulz Cristoph Sygmund Roland Ludwig Lo Gorton Ulla Wollenberger Frieder W. Scheller 《Electroanalysis》2014,26(9):2043-2048
For the first time the direct electron transfer of an enzyme ‐ cellobiose dehydrogenase, CDH ‐ has been coupled with the hexokinase catalyzed competition for glucose in a sensor for ATP. To enhance the signal output for ATP, pyruvate kinase was coimmobilized to recycle ADP by the phosphoenolpyruvate driven reaction. The new sensor overcomes the limit of 1 : 1 stoichiometry of the sequential or competitive conversion of ATP by effective enzymatic recycling of the analyte. The anodic oxidation of the glucose converting CDH proceeds at electrode potentials below 0 mV vs. Ag|AgCl thus potentially interfering substances like ascorbic acid or catecholamines do not influence the measuring signal. The combination of direct electron transfer of CDH with the enzymatic recycling results in an interference‐free and oxygen‐independent measurement of ATP in the lower µmolar concentration range with a lower limit of detection of 63.3 nM (S/N=3). 相似文献
80.
Formation of “Quasi” Contact or Solvent‐separated Ion Pairs in the Local Environment of Probe Molecules Dissolved in Ionic Liquids 下载免费PDF全文
Matthias Strauch Dr. Christian Roth Falk Kubatzki Prof. Dr. Ralf Ludwig 《Chemphyschem》2014,15(2):265-270
The change from “quasi” contact to “quasi” solvent‐separated ion‐pair configuration in the local environment of a probe molecule in ionic liquids depends on the varying interaction strength of the chosen anions. The ion speciation in these Coulomb fluids could be shown by combining infrared spectroscopy, density functional theory calculations, and natural bond orbital analysis using a low‐self‐clustering probe molecule. 相似文献