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11.
M. Alves Da Silva M. Helena Gil A. P. Piedade J. S. Redinha A. M. Oliveira Brett J. M. Caridade Costa 《Journal of polymer science. Part A, Polymer chemistry》1991,29(2):269-274
The immobilization of catalase on grafted membranes of poly(ethylene)-g-co-acrylic acid and poly(tetrafluoroethylene)-g-co-acrylic acid and their application in hydrogen peroxide electrochemical sensors is described. The introduction of carboxylic acid groups onto a hydrophobic support provides a good environment for subsequent enzyme immobilization. This single membrane, hydrogen peroxide sensor showed significant improvement with respect to the double membrane versions. The response is very rapid, the linear range being from 10 μM up to 6 mM, with a detection limit of 4.7 μM, and a lifetime of more than 4 months. 相似文献
12.
Eggenhffner R. Masini R. Bellingeri E. Cimberle M. R. Ferdeghini C. Costa G. A. Kaiser E. Signorelli E. 《Il Nuovo Cimento D》1994,16(10):1659-1664
Il Nuovo Cimento D - The formation of Hg-based HTSC materials was investigated through the development of non-conventional techniques. The former was based on a singlestep synthesis at temperatures... 相似文献
13.
The fully frustrated planar rotator and fully frustrated XY models in two dimensions have two phase transitions: one of the Berezinskii–Kosterlitz–Thouless type and other in the Ising universality class. We use Monte Carlo simulation to study both models. We fix our attention in the Ising-like transition, which we show can be understood as a percolation transition. We obtain the critical temperature as well as the critical exponents of the mean cluster size, γ, and Fisher's exponent τ. The critical temperature agree very well with other calculations. We found that the critical exponents are smaller than in the pure two-dimensional percolation case. We interpret this as due to the long-range interaction between vortex and antivortex. 相似文献
14.
Renata S da Costa Luciano F Almeida Márcio J.C Pontes Simone S Simões 《Microchemical Journal》2004,78(1):27-33
A novel strategy to evaluation of adulteration in alcoholic beverages based on the measurement of the Schlieren effect using an automated FIA system with photometric detection is proposed. The assay is based on the Schlieren effect produced when beverage samples are injected in a single-line FIA system that uses water as carrier stream and a light-emitting diode-phototransistor photometer controlled by microcomputer as detector. The flow system presents limited mixing conditions which make possible to create gradients of refractive index (Schlieren effect) in the injected sample zone. These gradients are reproducible, characteristic of each alcoholic beverage and undergo specific modifications when adulterations with water or ethanol are imposed. Schlieren effect data of brandies, cachaças, rums, whiskies and vodkas were treated by SIMCA to elaborate class models applied in the evaluation of alcoholic beverages adulteration. Samples of the original matrix of each sort of beverages were adulterated in laboratory by adding water, methanol and ethanol in levels of 5% and 10% (v/v). These samples were used as test set to validate SIMCA class models. The verification of authenticity using Schlieren effect measurements presented good results making possible to identify 100% of the beverages samples adulterated in laboratory and 93% of the actual adulterated alcoholic beverages with confidence levels of 95%. As principal advantage, the automated system does not use reagents to carry out the analysis. 相似文献
15.
Some basic concepts about curvature collineations are reviewed and the existing results on this topic are applied to the case of perfect fluids, giving a characterization of those amongst them which admit proper curvature collineations. 相似文献
16.
Statisticians are accustomed to processing numerical, ordinal or nominal data. In many circumstances, such as socio-economic, epidemiologic sample surveys and documentary data bases, this data is juxtaposed with textual data (for example, responses to open questions in surveys). This article presents a series of language-independent procedures based upon applying multivariate techniques (such as correspondence analysis and clustering) to sets of generalized lexical profiles. The generalized lexical profile of a text is a vector whose components are the frequencies of each word (graphical form) or ‘repeated segment’ (sequence of words appearing with a significant frequency in the text). The processing of such large (and often sparse) vectors and matrices requires special algorithms. The main outputs are the following: (1) printouts of the characteristic words and characteristic responses for each category of respondent (these categories are generally derived from available nominal variables); (2) graphical displays of the proximities between words or segments and categories of respondents; (3) when analysing a combination of several texts: graphical displays of proximities between words or segments and each text, or between words or segments and groupings of texts. The systematic use of ‘repeated segments’ provides a valuable help in interpreting the results from a semantic point of view. 相似文献
17.
This paper is concerned with a study of bounded perturbations of resonant linear problems. It follows from our results that for certain types of bounded domains Ω ? Rn, n ≥ 2, the Dirichlet problem $\matrix{\Delta u+\lambda_{1}u+g(u)=h(x),\ \ \ x\in\Omega\cr \quad\quad\quad\quad\quad\quad u=0,\ \ \ x\in\partial\Omega,}$ has infinitely many positive solutions, in case λ1 is the principal eigenvalue of ?Δ subject to trivial Dirichlet boundary conditions, g is a nontrivial periodic nonlinearity of zero mean and ∫03A9h(x)?(x)dx = 0, where ? is an eigenfunction corresponding to λ1. 相似文献
18.
Simulation of aerated lagoon using artificial neural networks and multivariate regression techniques
Karla Patricia Oliveira-Esquerre Aline C. da Costa Roy Edward Bruns Milton Mori 《Applied biochemistry and biotechnology》2003,106(1-3):437-449
The aim of this study was to develop an empirical model that provides accurate predictions of the biochemical oxygen demand
of the output stream from the aerated lagoon at International Paper of Brazil, one of the major pulp and paper plants in Brazil.
Predictive models were calculated from functional link neural networks (FLNNs), multiple linear regression, principal components
regression, and partial least-squares regression (PLSR). Improvement in FLNN modeling capability was observed when the data
were preprocessed using the PLSR technique. PLSR also proved to be a powerful linear regression technique for this problem,
which presents operational data limitations. 相似文献
19.
Margarita Valero Silvia M. B. Costa José R. Ascenso M. Mercedes Velázquez Licesio J. Rodríguez 《Journal of inclusion phenomena and macrocyclic chemistry》1999,35(4):663-677
The inclusion of the anti-inflammatory drug, Nabumetone, in -, - and hydroxypropyl--cyclodextrin (CDs) is studied using UV-VIS absorption and steady-state fluorescence emission. Binding constants and thermodynamic parameters of complex formation are determined by spectrofluorimetry. The inclusion phenomena of Nabumetone with the three cyclodextrins is compared with that of the well known similar anti-inflammatory drug Naproxen. In the case of Nabumetone pronounced differences are observed in the complexation process with each cyclodextrin whereas the respective Naproxen complexes are nearly identical. 1H-NMR experiments show that the inclusion process in Nabumetone can occur either through the substituents in the -2 (butanone) or -6 (methoxy) positions in the naphthalene ring. 相似文献
20.