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81.
Loratadine, a potent antihistamine drug, is not directly electroreducible at a dropping mercury electrode; however, by means of a nitration procedure it is possible to obtain a nitro-loratadine derivative which has been identified as 4-(8-chloro-7-nitro-5,6-dihydro-11 H-benzo-[5,6]-cyclohepta-[l,2-b]-pyridin-l l-ylidene)-1-piperidine carboxylic acid ethyl ester. The electrochemical reduction of this derivative at different pHs and concentrations using polarography and cyclic voltammetry was studied. The derivative exhibits a differential pulse polarographic peak due to the reduction of the nitro group. This peak was used in order to develop an analytical procedure for determining loratadine in pharmaceutical dosage forms.
The recovery study shows adequate accuracy and precision for the developed assay and the excipients do not interfere in the determination. 相似文献
82.
On Chalcogenolates. 94. Studies on Trithioallophanic Acid. 3. Esters of Trithioallophanic Acid. The esters of trithioallophanic acid H2N? CS? NH? CS(SR) with R = CH3, CH2C6H5 have been characterized by means of electron absorption spectra, infrared spectra, 1H NMR spectra, and mass spectra. 相似文献
83.
Seger C Sturm S Strasser EM Ellmerer E Stuppner H 《Magnetic resonance in chemistry : MRC》2004,42(10):882-886
The NMR signal assignments of a series of structurally divergent benzylisoquinolines isolated from Fumaria officinalis L. (Fumariaceae, Papaverales), namely adlumine, corlumine, corydamine, cryptopine, fumarophycine, O-methylfumarophycine, hydrastine, parfumine, protopine and sinactine, are presented. 相似文献
84.
On Chalcogenolates. 135. Studies on Esters of Haloformic Acids. 3. Synthesis and Characterization of Alkyl Esters of Fluoro- and Bromothioformic Acid nC3H7S? CO? F, C2H5S? CS? F, and nC3H7S? CS? F have been prepared by reaction of the corresponding chloro compound with KF by use of phase transfer catalysts. The esters RS? CS? Br, where R ? C2H5 and nC3H7, are formed by reaction between RSH and SCBr2 in the presence of pyridine. The compounds have been characterized by means of diverse spectroscopic methods. 相似文献
85.
On Chalcogenolates. 137. Alkyl Esters of Isothiocyanoformic, Isothiocyanomonothioformic and Isothiocyanodithioformic Acids The esters RO? CO? NCS, where R = CH3, C2H5, as well as RS? CO? NCS and RS? CS? NCS with R = C2H5, nC3H7 have been prepared by three different methods. The reaction between the corresponding chloro compound and KSCN in the presence of the phase transfer catalyst 18-crown-6 gives the highest yields. The electron absorption, infrared, nuclear magnetic resonance, and mass spectra of these compounds are reported. 相似文献
86.
87.
Peńkin M. Boulyga S. Dabbs B. Fischer D. Humphrey M. Kochetkov A. Koepf A. Sturm M. 《Journal of Radioanalytical and Nuclear Chemistry》2018,316(2):791-798
Journal of Radioanalytical and Nuclear Chemistry - Reference information on isotopic composition of various uranium materials, determined with high accuracy and precision, is of essential value for... 相似文献
88.
Ludmilla Kolokolova Li Liu Michael I. Mishchenko 《Journal of Quantitative Spectroscopy & Radiative Transfer》2011,112(13):2175-2181
We study a new optical effect, a spectral manifestation of coherent backscattering, which reveals itself as systematic variations in the depth of absorption bands with changing phase angle. We used Cassini VIMS near-infrared spectra of Saturn's icy satellite Rhea in order to identify and characterize the spectral change with phase angle, focusing on the change in the depth of water-ice absorption bands. To model realistic characteristics of the surfaces of icy satellites, which are most likely covered by micron-sized densely packed particles, we perform simulations using a theoretical approach based on direct computer solutions of the macroscopic Maxwell equations. Our results show that this approach can reproduce the observed phase-angle variations in the depth of the absorption bands. The modeled changes in the absorption bands are strongly affected by physical properties of the regolith, especially by the size and packing density of the ice particles. Thus, the phase-angle spectral variations demonstrate a promising remote-sensing capability for studying properties of the surfaces of icy bodies and other objects that exhibit a strong coherent backscattering effect. 相似文献
89.
90.
A. Heiduschka F. Muth W. Sturm H. Fincke J. Großfeld A. Simmer W. Plücker A. Steinruck F. Starck und W. Schmandt 《Fresenius' Journal of Analytical Chemistry》1930,79(3-4):150-153
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