排序方式: 共有63条查询结果,搜索用时 31 毫秒
51.
West KR Ludlow RF Corbett PT Besenius P Mansfeld FM Cormack PA Sherrington DC Goodman JM Stuart MC Otto S 《Journal of the American Chemical Society》2008,130(33):10834-10835
A simple water-soluble naphthalenedithiol building block is converted quantitatively into a series of octameric [2]-catenanes, composed of two interlocked molecular squares. When this mixture is re-equilibrated in the presence of an adamantyl ammonium guest, the catenanes disassemble into their macrocyclic components that bind the guest with nanomolar affinity in water. 相似文献
52.
Reports on dynamic combinatorial chemistry have almost exclusively involved small libraries of 10-100 compounds. We now show how more than 9000 compounds can be screened in a single LC-MS analysis to reveal a series of new receptors that bind ephedrine in water. These results demonstrate the feasibility of screening DCLs that are substantially larger than the solution-phase libraries reported thus far. 相似文献
53.
Boyd MM Ludlow AD Blatt S Foreman SM Ido T Zelevinsky T Ye J 《Physical review letters》2007,98(8):083002
Aided by ultrahigh resolution spectroscopy, the overall systematic uncertainty of the 1S0-3P0 clock resonance for lattice-confined 87Sr has been characterized to 9 x 10(-16). This uncertainty is at a level similar to the Cs-fountain primary standard, while the potential stability for the lattice clocks exceeds that of Cs. The absolute frequency of the clock transition has been measured to be 429 228 004 229 874.0(1.1) Hz, where the 2.5 x 10(-15) fractional uncertainty represents the most accurate measurement of a neutral-atom-based optical transition frequency to date. 相似文献
54.
Ludlow AD Huang X Notcutt M Zanon-Willette T Foreman SM Boyd MM Blatt S Ye J 《Optics letters》2007,32(6):641-643
We demonstrate phase and frequency stabilization of a diode laser at the thermal noise limit of a passive optical cavity. The system is compact and exploits a cavity design that reduces vibration sensitivity. The subhertz laser is characterized by comparison with a second independent system with similar fractional frequency stability (1x10(-15) at 1 s). The laser is further characterized by resolving a 2 Hz wide, ultranarrow optical clock transition in ultracold strontium. 相似文献
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56.
Ludlow AD Boyd MM Zelevinsky T Foreman SM Blatt S Notcutt M Ido T Ye J 《Physical review letters》2006,96(3):033003
With ultracold 87Srconfined in a magic wavelength optical lattice, we present the most precise study (2.8 Hz statistical uncertainty) to date of the 1S0-3P0 optical clock transition with a detailed analysis of systematic shifts (19 Hz uncertainty) in the absolute frequency measurement of 429 228 004 229 869 Hz. The high resolution permits an investigation of the optical lattice motional sideband structure. The local oscillator for this optical atomic clock is a stable diode laser with its hertz-level linewidth characterized by an octave-spanning femtosecond frequency comb. 相似文献
57.
The pore connectivity, pore size distribution and pore spatial distribution of the porous structure of native and silanized silica particles were determined by matching the experimental nitrogen sorption data with the theoretical results obtained from pore network model simulations. The agreement between theory and experiment is found to be good. The results clearly indicate that the deposition of the silane layer to the pore surfaces of the native silica particles produces a silanized silica particle with a mean pore diameter and pore connectivity smaller than that of the native silica particle. Furthermore, the evaluation of the pore diffusivity of ribonuclease under unretained conditions shows that the lower values of the pore connectivity found in the samples of silanized silica particles, when compared with the values of the pore connectivity obtained for the native silica particles, increase the diffusional mass transfer resistance within the porous structure of the silanized silica particles. 相似文献
58.
T Madhusoodhanan Samit Mandal MP Sathyavathiamma Ramani NG Puttaswamy TS Mudhole A Mandal DK Avasthi R Shyam SK Datta 《Pramana》1999,53(3):541-544
The inclusive and exclusive measurements were carried out for 7Li projectile breakup on 27Al target at 48 MeV. In the inclusive data we have observed a broad peak around the beam velocity for alphas and tritons.
The exclusive data for alpha-triton coincidences show good agreement with the post-form DWBA theory of breakup reactions. 相似文献
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60.
Julia D. Edgar Christine M. Sapienza Kimberly Bidus Christy L. Ludlow 《Journal of voice》2001,15(3):362
Speech of patients with abductor spasmodic dysphonia (ABSD) was analyzed using acoustic analyses to determine: (1) which acoustic measures differed from controls and were independent factors representing patients' voice control difficulties, and (2) whether acoustic measures related to blinded perceptual counts of the symptom frequency in the same patients. Patients' voice onset time for voiceless consonants in speech were significantly longer than the controls (p = 0.015). A principle components analysis identified three factors that accounted for 95% of the variance: the first factor included sentence and word duration, frequency shifts, and aperiodic instances; the second was phonatory breaks; and the third was voice onset time. Significant relationships with perceptual counts of symptoms were found for the measures of acoustic disruptions in sentences and sentence duration. Finally, a multiple regression demonstrated that the acoustic measures related well with the perceptual counts (r2 = 0.84) with word duration most highly related and none of the other measures contributing once the effect of word duration was partialed out. The results indicate that some of the voice motor control deficits, namely aperiodicity, phonatory breaks, and frequency shifts, which occur in patients with ABSD, are similar to those previously found in adductor spasmodic dysphonia. Results also indicate that acoustic measures of intermittent disruptions in speech, voice onset time, and speech duration are closely related to the perception of symptom frequency in the disorder. 相似文献