Temperature dependence of magnetization in nanocrystalline FeCoZr alloy

The temperature dependence of magnetization of a nanocrystalline Fe₆₀Co₃₀Zr₁₀ alloy annealed at various temperatures to varying crystal sizes was investigated down to 5 K in the field range up to 5 T. The fitting procedure gave T^3/2 as the leading term irrespective of the crystal size. We suggest that the increase of the coefficient by this term for smaller crystals may be connected to an increased relative volume of their surface.     

The use of sulfide cluster-derived catalysts to understand the promotional effect in hydrotreatment catalysis

Sulfide cluster-derived ensembles are promising models of the active sites in commercial hydrotreatment catalysts. A series of sulfide clusters were adsorbed intact onto high-surface-area γ-alumina, magnesium oxide and activated carbon supports, then pretreated to produce highly dispersed catalytic ensembles with sizes similar to those of their precursor clusters. The activities of the bimetallic cluster-derived catalysts were significantly higher than those of the monometallic catalysts. We took this as evidence that direct interactions between molybdenum and the promoter element cause the promotional effect observed in commercial hydrotreatment catalysts. The hydrodesulfurization and hydrodenitrogenation activities correlated with the extent of molybdenum reduction. Our results suggested that the active sites in promoted hydrotreatment catalysts are centered on molecular-scale ensembles containing molybdenum, sulfur and the promoter element.     

NMR Study of the propagation center in the cationic polymerization of N-benzoyl-8-octanelactam. II. Investigation of the propagation center

The nature of the propagation center in the cationic polymerization of N-benzoyl-8-octanelactam initiated by octanoylium hexachlcroantimonate, SbCl₅, and Ph₃CAsF₆ in perdeuterated tetrachloroethane or its mixture with o-dichlorobenzene was studied using ¹H, ¹³C, ¹⁹F, ³¹P, ⁷⁵As, and ¹²¹Sb nuclear magnetic resonance (NMR) of model oligomers and the products of their end-capping with triphenylphosphine. In all cases, the nature of the propagation center has been found to be of an acylium ion pair with an SbCl₆^? or AsF₆^? counterion coordinated with the nearest benzoylamide group and cosolvated by the solvent. © 1994 John Wiley & Sons, Inc.     

Investigation of natural compounds by the HPLC method II. HPLC fingerprint method for the epigeal organs of Ferula kuhistanica and F. tenuisecta

A microcolumn HPLC fingerprint method has been developed for the epigeal organs ofFerula kuhistanica andF. tenuisecta. The possibility has been shown of control by the microcolumn HPLC method of the qualitative and quantitative yields of ferutinin in the initial plant raw material and in preparations extracted from it, and also at each stage of the isolation of the desired product. The method is universal and does not depend on species and chemical composition of the plant. Institute of the Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 635–636, November–December, 1992.     

Spectrophotometric study of holmium complexation in KOH solutions at 25°C

The complexation of Ho³⁺ in HoCl₃ and KOH solutions at 25°C and saturated vapor pressure was studied by an indicator spectrophotometric technique, and the pH values of the investigated solutions were determined. The stability constants of the hydroxo complexes of Ho³⁺ were measured over a range of pH 9.25–10.10 and at μ≤ 4 × 10^?4 and extrapolated to zero ionic strength.     

Kondo lattice and heavy fermions in Heusler phases: CeInAg2−xCux

Magnetic properties, electrical resistivity, specific heat and magnetic excitations have been investigated in Heusler phases CeInAg_2–xCu_x. The hybridization continuously increases from CeInAg₂ (antiferromagnetic Kondo lattice) to CeInCu₂ (heavy fermion compound). The specific heat coefficient for this last compound is found to reach 1.2 J/mole. K² at 1.4 K, the Kondo temperature is 6 K and the Wilson ratio is close to 2.     

The force on a lattice defect in an elastic body

It is shown that the force on a lattice defect in an elastic body is, like the force on a disclination in a nematic liquid crystal, a real force which, for equilibrium, must be balanced by an external force applied to the closed surface enclosing the defect.     

On accurate boundary conditions for a shape sensitivity equation method

This paper studies the application of the continuous sensitivity equation method (CSEM) for the Navier–Stokes equations in the particular case of shape parameters. Boundary conditions for shape parameters involve flow derivatives at the boundary. Thus, accurate flow gradients are critical to the success of the CSEM. A new approach is presented to extract accurate flow derivatives at the boundary. High order Taylor series expansions are used on layered patches in conjunction with a constrained least‐squares procedure to evaluate accurate first and second derivatives of the flow variables at the boundary, required for Dirichlet and Neumann sensitivity boundary conditions. The flow and sensitivity fields are solved using an adaptive finite‐element method. The proposed methodology is first verified on a problem with a closed form solution obtained by the Method of Manufactured Solutions. The ability of the proposed method to provide accurate sensitivity fields for realistic problems is then demonstrated. The flow and sensitivity fields for a NACA 0012 airfoil are used for fast evaluation of the nearby flow over an airfoil of different thickness (NACA 0015). Copyright © 2005 John Wiley & Sons, Ltd.     

Study of pairing deformations by means of two-particle transfer reactions

The macroscopic approach for two-particle transfer reactions is applied in normal spherical nuclei and pairing deformation parameters β_p are estimated. For Ni isotopes the macroscopic approach works reasonably well while for the lead region strong energy dependence of theβ _p values has been observed. It is shown that alpha-transfer reactions can also be treated within this formalism as couplings of the two-neutron and two-proton channels.