全文获取类型
收费全文 | 895篇 |
免费 | 23篇 |
国内免费 | 1篇 |
专业分类
化学 | 561篇 |
晶体学 | 6篇 |
力学 | 40篇 |
数学 | 139篇 |
物理学 | 173篇 |
出版年
2023年 | 5篇 |
2022年 | 30篇 |
2021年 | 29篇 |
2020年 | 10篇 |
2019年 | 13篇 |
2018年 | 16篇 |
2017年 | 11篇 |
2016年 | 19篇 |
2015年 | 14篇 |
2014年 | 26篇 |
2013年 | 71篇 |
2012年 | 65篇 |
2011年 | 64篇 |
2010年 | 30篇 |
2009年 | 39篇 |
2008年 | 53篇 |
2007年 | 62篇 |
2006年 | 36篇 |
2005年 | 40篇 |
2004年 | 31篇 |
2003年 | 20篇 |
2002年 | 15篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 6篇 |
1998年 | 8篇 |
1996年 | 10篇 |
1995年 | 4篇 |
1994年 | 7篇 |
1993年 | 8篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 14篇 |
1984年 | 7篇 |
1983年 | 8篇 |
1982年 | 8篇 |
1981年 | 16篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1978年 | 10篇 |
1977年 | 6篇 |
1976年 | 15篇 |
1975年 | 5篇 |
1974年 | 4篇 |
1973年 | 3篇 |
1970年 | 4篇 |
1906年 | 3篇 |
1905年 | 3篇 |
排序方式: 共有919条查询结果,搜索用时 15 毫秒
61.
The dynamics of the temporal fluctuations of the length of the day (LOD) time series from January 1, 1962 to November 2, 2006 were investigated. The power spectrum of the whole time series has revealed annual, semi-annual, decadal and daily oscillatory behaviors, correlated with oceanic–atmospheric processes and interactions. The scaling behavior was analyzed by using the detrended fluctuation analysis (DFA), which has revealed two different scaling regimes, separated by a crossover timescale at approximately 23 days. Flicker-noise process can describe the dynamics of the LOD time regime involving intermediate and long timescales, while Brownian dynamics characterizes the LOD time series for small timescales. 相似文献
62.
Anna Abatangelo Roberto Gilli Luciano Navarini Roberto Rizzo Stanley F. Osman William F. Fett 《Journal of carbohydrate chemistry》2013,32(4-5):583-598
Abstract The solution properties of the exopolysaccharide marginalan produced by Pseudomonas marginalis HT041B were investigated by means of low-angle laser light-scattering, capillary viscometry, and rheology. Potentiometric and viscosimetric data indicated the absence of a cooperative transition of the disorder-to-order type. The experimental findings obtained in dilute solution (Mark-Houwink coefficients, rigidity coefficient, characteristic ratio) suggested that the polymer behaves like a semiflexible chain which adopts a disordered conformation. The rheological behaviour of more concentrated marginalan solutions, as determined by means of both steady shear and oscillatory measurements, further confirmed the disordered conformational state of the polymer in solution. 相似文献
63.
Aline Lima de Oliveira Carlos Henrique Alves de Oliveira Laura Maia Mairink Francine Pazini Ricardo Menegatti Luciano Morais Lião 《Magnetic resonance in chemistry : MRC》2011,49(8):537-542
Complete assignment of 1H and 13C NMR chemical shifts and J(1H/1H and 1H/19F) coupling constants for 22 1‐phenyl‐1H‐pyrazoles' derivates were performed using the concerted application of 1H 1D and 1H, 13C 2D gs‐HSQC and gs‐HMBC experiments. All 1‐phenyl‐1H‐pyrazoles' derivatives were synthesized as described by Finar and co‐workers. The formylated 1‐phenyl‐1H‐pyrazoles' derivatives were performed under Duff's conditions. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
64.
Lesley A. Chesson Luciano O. Valenzuela Gabriel J. Bowen Thure E. Cerling James R. Ehleringer 《Rapid communications in mass spectrometry : RCM》2011,25(24):3713-3722
Published datasets of proteinaceous animal tissues suggest that co‐variation between amino acid hydrogen (δ2H) and oxygen (δ18O) isotope ratios is a common feature in systems where isotopic variation is driven by geographic or temporal variation in the δ2H and δ18O values of environmental water. This has led to the development of models relating tissue δ2H and δ18O values to those of water, with potential application in a number of fields. However, the strength and ubiquity of the influence of environmental water on protein isotope ratios across taxonomic groups, and thus the relevance of predictive models, is an open question. Here we report strong co‐variation of δ2H and δ18O values across a suite of terrestrial and aquatic animal meats purchased in American food markets, including beef, poultry (chicken and turkey), chicken eggs, pork, lamb, freshwater fish, and marine fish. Significant isotope co‐variation was not found for small collections of marine bivalves and crustaceans. These results imply that isotopic signals from environmental water were propagated similarly through most of the diverse natural and human‐managed foodwebs represented by our samples. Freshwater fish had the largest variation in δ2H and δ18O values, with ranges of 121 ‰ and 19.2 ‰, respectively, reflecting the large isotopic variation in environmental freshwaters. In contrast marine animals had the smallest variation for both δ2H (7 ‰ range, crustaceans) and δ18O (3.0 ‰ range, bivalves) values. Known‐origin beef samples demonstrated direct relationships between the variance of environmental water isotope ratios and that of collected meats. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
65.
L. de Arcangelis H. J. Herrmann M. Kolb René Thomas C. Amitrano L. Peliti M. Saber G. Weisbuch Sara A. Solla F. Bagnoli A. Francescato R. Livi S. Ruffo Pablo Tamayo Michel Droz Peter Jörg Plath S. Romano Yves Pomeau Stéphane Zaleski D. Stauffer Luciano R. da Silva Alex Hansen Stéphane Roux Antonio Coniglio B. Derrida Henrik Flyvbjerg Naeem Jan Dietrich Stauffer Peter Grassberger A. Zippelius K. E. Kurten Werner Krauth Jean -Pierre Nadal Marc Mézard Per Bak Chao Tang Itzhak Webman M. L. Martins H. F. V. Resende C. Tsallis A. C. N. Magalhaes 《Journal of statistical physics》1989,55(5-6):1333-1359
66.
67.
68.
69.
Valeria Califano Francesco Bloisi Luciano R.M. Vicari Paolo Colombi Laura E. Depero 《Applied Surface Science》2008,254(22):7143-7148
Double layers of polyethylene glycol (PEG) and 3-(3,4-dihydroxyphenyl)-2-methyl-l-alanine (m-DOPA) thin films were obtained by matrix assisted pulsed laser evaporation (MAPLE) technique, by depositing a first layer of m-DOPA on Si substrate and a second layer of PEG on top of it. The films were characterized by low angle X-ray diffraction (LAXRD), X-ray reflectivity (XRR), atomic force microscopy (AFM), and micro-Raman spectroscopy. From these analyses it resulted that PEG was deposited without any relevant damage both in terms of chemical structure and molecular weight. Furthermore, PEG chains were mostly in the extended conformation, although PEG micelles appeared. 相似文献
70.
Giorgia Oliviero Nicola Borbone Vincenzo Piccialli Gennaro Piccialli Luciano Mayol 《Tetrahedron》2010,66(10):1931-6144
We report here an efficient solid-phase synthesis of N-1-alkyl-substituted analogues of cyclic inosine-diphosphate-ribose (cIDPR), a mimic of cyclic ADP-ribose (cADPR). Our synthetic strategy makes use of a polystyrene support to which inosine was bonded through a 2′,3′-acetal linkage. Insertion of a ω-hydroxy-polymethylene chain of variable length on N-1, followed by conversion into N-1-alkylinosine-bis-phosphate derivatives and cyclization, allowed to obtain analogues of cIDPR of various ring size. The cyclization step was carried out both in solid-phase and in solution by pyrophosphate bond formation. The effect of the N-1-polymethylene chain length on the cyclization yields as well as the reaction conditions, which led to the solid-phase pyrophosphate bond formation, were thoroughly investigated. 相似文献