Finite Distributive Semilattices

Applied Categorical Structures - The present article aims to develop a categorical duality for the category of finite distributive join-semilattices and $$wedge $$ -homomorphisms (maps that...     

Algebraic linkage and homological algebra

Ricerche di Matematica - We prove that some of the main results of linkage theory can be extended to a more general context in homological algebra. Our main result states that, under suitable...     

Thermodynamic study of mixtures containing dibromomethane. II: volumes and enthalpies at 298.15 K

Journal of Thermal Analysis and Calorimetry - Excess molar volumes, VE, of binary mixtures of dibromomethane (DBM) with n-hexane, n-heptane, n-octane, cyclohexane, tetrachloromethane, dipropyl and...     

On abstract stochastic differential equation in hilbert spaces with dissipative drift

A multi–operative Markovian machine interference model with arbitrary inital number of breakdowns is studied by taking mean breakdown of each machine as λ^-1 and the mean repairtime of each machine as μ^-1. The transient state probabilities of number of breakdowns and initial busy period distributions of a given number of operatives have been obtained in closed form using Laplace transform and matrix theory. The efficacy of the method is tested by computing the state probabilities and measures of effectiveness such as machine availability function and operating efficiency function for various values of traffic intensity ρ=λ/μ.     

Small-angle X-ray scattering and light scattering on lysozyme and sodium glycocholate micelles

Small-angle X-ray scattering (SAXS) together with static (SLS) and dynamic light scattering (DLS) measurements were carried out on aqueous solutions of lysozyme (LY) and of the ionic biological detergent sodium glycocholate (NaGC). Apparent diffusion coefficients (D app), excess Rayleigh ratio, and SAXS spectra were measured for 0.1 M NaGC solutions at different ionic strengths (0.05-0.30 M NaCl). The same data were collected for LY in sodium acetate buffer 50 mM without and with 92 mM NaCl as a function of protein concentration (10-80 g L(-1)). A correlated analysis of SLS data and SAXS spectra was first tested on the LY samples and then extended to the interpretation of the NaGC data to infer information on particle structure and interaction potential. A hard-core (HC) interaction shell of uniform thickness, a screened Coulomb potential of the electric double layer (EDL) or the complete DLVO potential were alternatively used to represent the long-range tail of the interaction potential. Whenever an essentially repulsive tail is expected, all the representations give reasonable results, but the data analysis does not allow the discrimination between the oblate and the prolate symmetries of the NaGC aggregates. The DLVO model allows the interpretation of the data even when the attractive component determines the tail character. With this model an overall fit of the micelle data at all the NaCl concentrations was successfully performed by assuming a simple spherical symmetry of the micelles and invariant values of their ionization degree and Hamaker constant, thus considering just the screening effect of the added electrolyte. Whatever model is used, the results point out that the aggregates are quite hydrated (26-38 water molecules per monomer) and very slightly grow by increasing the NaCl concentration. When spherical symmetry is assumed the aggregate radii for all the samples fall in the range 15-16 A. From the SAXS and SLS, best fitting geometrical parameters, and interparticle structure factor, a D app value was calculated for each sample. An excellent consistence is achieved for LY results. On the contrary, calculated D app values systematically lower than the experimental values are always obtained for the NaGC micelles. Micelle polydispersity and internal dynamics seem to be the most probable reasons of the bad agreement.     

Lyapunov exponents estimation for hysteretic systems

This article discusses the Lyapunov exponent estimation of non-linear hysteretic systems by adapting the classical algorithm by Wolf and co-workers [Wolf, A., Swift, J.B., Swinney, H.L., Vastano, J.A., 1985. Determining Lyapunov exponents from a times series. Physica D 16, 285–317.]. This algorithm evaluates the divergence of nearby orbits by monitoring a reference trajectory, evaluated from the equations of motion of the original hysteretic system, and a perturbed trajectory resulting from the integration of the linearized equations of motion. The main issue of using this algorithm for non-linear, rate-independent, hysteretic systems is related to the procedure of linearization of the equations of motion. The present work establishes a procedure of linearization performing a state space split and assuming an equivalent viscous damping in order to represent hysteretic dissipation in the linearized system. The dynamical response of a single-degree of freedom pseudoelastic shape memory alloy (SMA) oscillator is discussed as an application of the proposed algorithm. The restitution force of the oscillator is provided by an SMA element described by a rate-independent, hysteretic, thermomechanical constitutive model. Two different modeling cases are considered for isothermal and non-isothermal heat transfer conditions, and numerical simulations are performed for both cases. The evaluation of the Lyapunov exponents shows that the proposed procedure is capable of quantifying chaos capturing the non-linear dissipation of hysteretic systems.