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排序方式: 共有196条查询结果,搜索用时 15 毫秒
51.
52.
Carmen I. Fort Mihai M. Rusu Liviu C. Cotet Adriana Vulpoi Ileana Florea Sandrine Tuseau-Nenez Monica Baia Mihaela Baibarac Lucian Baia 《Molecules (Basel, Switzerland)》2021,26(1)
Multifunctional Bi- and Fe-modified carbon xerogel composites (CXBiFe), with different Fe concentrations, were obtained by a resorcinol–formaldehyde sol–gel method, followed by drying in ambient conditions and pyrolysis treatment. The morphological and structural characterization performed by X-ray diffraction (XRD), Raman spectroscopy, N2 adsorption/desorption porosimetry, scanning electron microscopy (SEM) and scanning/transmission electron microscopy (STEM) analyses, indicates the formation of carbon-based nanocomposites with integrated Bi and Fe oxide nanoparticles. At higher Fe concentrations, Bi-Fe-O interactions lead to the formation of hybrid nanostructures and off-stoichiometric Bi2Fe4O9 mullite-like structures together with an excess of iron oxide nanoparticles. To examine the effect of the Fe content on the electrochemical performance of the CXBiFe composites, the obtained powders were initially dispersed in a chitosan solution and applied on the surface of glassy carbon electrodes. Then, the multifunctional character of the CXBiFe systems is assessed by involving the obtained modified electrodes for the detection of different analytes, such as biomarkers (hydrogen peroxide) and heavy metal ions (i.e., Pb2+). The achieved results indicate a drop in the detection limit for H2O2 as Fe content increases. Even though the current results suggest that the surface modifications of the Bi phase with Fe and O impurities lower Pb2+ detection efficiencies, Pb2+ sensing well below the admitted concentrations for drinkable water is also noticed. 相似文献
53.
Prof. Henning Hopf Prof. Peter G. Jones Dr. Alina Nicolescu Prof. Elena Bicu Dr. Lucian M. Birsa Dr. Dalila Belei 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(19):5565-5568
A facile synthesis of Pechmann dyes has been accomplished by the reaction of substituted N‐phenacyl‐4‐dimethylaminopyridinium halides with dimethyl maleate in the presence of DBU. Based on a related 4‐DMAP elimination product and an isolated monolactone intermediate a reaction mechanism has been proposed. The scope of this synthetic method is determined by the availability of α‐haloaroyl or heteroaroyl derivatives. DBU=1,8‐diazabicycloundec‐7‐ene, DMAP=4‐dimethylaminopyridine. 相似文献
54.
Marcela Stoia Mirela Barbu Mircea ?tef?nescu Paul Barvinschi Lucian Barbu-Tudoran 《Journal of Thermal Analysis and Calorimetry》2012,110(1):85-92
In this article, we present a detailed study regarding the preparation of nanosized zinc and magnesium chromites starting from a 4% poly(vinyl)alcohol (PVA) aqueous solution and metal nitrates. The controlled thermal treatment of these solutions has permitted the isolation of an intermediary solid product, used as precursor of the preferred mixed oxides: zinc and magnesium chromites. The as-obtained precursors were characterized by FT-IR spectrometry and thermal analysis. FT-IR spectrometry has evidenced the disappearance of the NO3 ? anions at 140?°C, due to the redox interaction with PVA. The thermal decompositions of the synthesized precursors were different, as resulted from both thermal analysis and FT-IR spectrometry. Thus, while ZnCrPVA precursor decomposes up to 400?°C with formation of zinc chromite, the precursor MgCrPVA decomposes up to 500?°C, with formation of MgCrO4 as intermediary amorphous phase. By thermal decomposition of MgCrO4 at 500?°C, weakly crystallized MgCr2O4 powder is obtained. The obtained chromite powders consist of fine nanoparticles with diameters ranging from 10 to 30?nm at 500?°C; on raising the annealing temperature to 1000?°C, chromite particles become octahedral, with diameter up to 500?nm, but with no sign of sintering. 相似文献
55.
Eva Castillejos Dr. Pierre‐Jean Debouttière Dr. Lucian Roiban Abderrahim Solhy Dr. Victor Martinez Dr. Yolande Kihn Dr. Ovidiu Ersen Dr. Karine Philippot Dr. Bruno Chaudret Dr. Philippe Serp Dr. 《Angewandte Chemie (International ed. in English)》2009,48(14):2529-2533
Are you in? Bimetallic PtRu nanoparticles have been selectively confined inside or deposited outside carbon nanotubes (see picture). The confined nanoparticles display significantly higher selectivity and catalytic activity in hydrogenation reactions.
56.
We investigate the interaction between a nanoparticle and an oil-water interface with particular emphasis on the particle crossing through the interface. The formation of a three-phase contact line is investigated in two cases, namely in the presence and in the absence of surface forces. We carefully examine the interplay between capillary and surface forces in such systems. Two instabilities of the interface (snap-in/snap-out) as the particle is moved through the interface are identified and quantitatively described. While the snap-in instability was observed in some AFM studies, the precise interface position and configuration relative to the particle at the instability depends on the nature of the surface forces present in the system. After the snap-in, the particle is adsorbed and must overcome an energy barrier due to the interface deformation in order to cross-over to the other liquid. We make quantitative predictions on the interface configuration at the instabilities and the free energy barrier height. The roles of particle size and different interaction parameters characterizing the system in determining the magnitude of the energy barrier for crossing and in the formation of a three-phase contact line are discussed. Ultimately, this study will enable us to make quantitative predictions on capillary effects in nanoparticle-microemulsions mixtures and other colloidal systems. For particles in the micrometer range and larger the capillary forces dominate over the surface forces and dictate how the snap-in occurs. However, the situation becomes different for particle sizes smaller than about 100 nm. The presence of surface forces modifies the interface configuration and the free energy jump at the snap-in instability. 相似文献
57.
Camelia Albu Simona Carmen Litescu Gabriel Lucian Radu Hassan Y. Aboul-Enein 《Journal of fluorescence》2013,23(3):381-386
The natural methyl donor group, S-adenosylmethionine and its product, S-adenosylhomocysteine play an important role in many biochemical reactions involving transmethylation reactions. These compounds can be used as biomarkers in incipient diagnosis of various pathological disorders therefore the validation of a suitable method to routinely analysis of these compounds is very important. In this paper, a high performance liquid chromatrography method for S-adenosylmethionine and S-adenosylhomocysteine measurement as fluorescent 1,N 6-ethanoderivatives from biological samples was validated in terms of selectivity, linearity range of the response (R?>?0.9993), detection limit (9?×?10?9 and 4.4?×?10?9 molL?1), the limit of quantitation (9.7?×?10?9 and 5.7?×?10?9?mol?L?1), precision, trueness and robustness. The method for quantification simultaneous of these compounds is rapid, sensitive and precise and appropriate for clinical analysis. 相似文献
58.
Suppose that U is the resolvent of a Borel right process on a Lusin space X. If is a U-excessive measure on X then we show by analytical methods that for every U-excessive measure with the Radon–Nikodym derivative d/d possesses a finely continuous version. (Fitzsimmons and Fitzsimmons and Getoor gave a probabilistic approach for this result.) We extend essentially a technique initiated by Mokobodzki and deepened by Feyel. The result allows us to establish a Revuz type formula involving the fine versions, and to study the Revuz correspondence between the -finite measures charging no set that is both -polar and -negligible (U being the potential component of ) and the strongly supermedian kernels on X. This is an analytic version of a result of Azéma, Fitzsimmons and Dellacherie, Maisonneuve and Meyer, in terms of additive functionals or homogeneous random measures. Finally we give an application to the context of the semi-Dirichlet forms, covering a recent result of Fitzsimmons. 相似文献
59.
Dippong Thomas Cadar Oana Levei Erika-Andrea Borodi Gheorghe Barbu-Tudoran Lucian 《Journal of Thermal Analysis and Calorimetry》2019,138(6):3845-3855
Journal of Thermal Analysis and Calorimetry - The paper presents the synthesis of ZnFe2O4/SiO2, NiFe2O4/SiO2, Ni0.4Zn0.6Fe2O4/SiO2 and Ni0.4Zn0.6Fe2O4/PVA-SiO2 nanocomposites by a modified... 相似文献
60.
Adina Arvinte Federica Valentini Antonio Radoi Fabiana Arduini E. Tamburri Lucian Rotariu Giuseppe Palleschi Camelia Bala 《Electroanalysis》2007,19(14):1455-1459
In this work, the capability of carbon nanofibers to be used for the design of catalytic electrochemical biosensors is demonstrated. The direct electrochemistry of NADH was studied at a glassy carbon electrode modified using carbon nanofibers. A decrease of the oxidation potential of NADH by more than 300 mV is observed in the case of the assembled carbon nanofiber‐glassy carbon electrode comparing with a bare glassy carbon electrode. The carbon nanofiber‐modified electrode exhibited a wide linear response range of 3×10?5 to 2.1×10?3 mol L?1 with a correlation coefficient of 0.997 for the detection of NADH, a high specific sensitivity of 3637.65 (μA/M cm2), a low detection of limit (LOD=3σ) of 11 μM, and a fast response time (3 s). These results have confirmed the fact that the carbon nanofibers represent a promising material to assemble electrochemical sensors and biosensors. 相似文献