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排序方式: 共有387条查询结果,搜索用时 437 毫秒
31.
Sun R Colin E Ajitanand NN Alexander JM Barton MA DeYoung PA Drake KL Elmaani A Gelderloos CJ Gualtieri EE Guinet D Hannuschke S Jaasma JA Kowalski L Lacey RA Lauret J Norbeck E Pak R Peaslee GF Stern M Stone NT Sundbeck SD Vander Molen AM Westfall GD Yang LB Yee J 《Physical review letters》2000,84(1):43-46
For central collisions of (17-115)A MeV 40Ar+Cu, Ag, Au, an overall balance is determined for the average mass, energy, and longitudinal momentum. Light charged particles and fragments are separated into forward-focused and isotropic components in the frame of the heaviest fragment. Energy removal by the isotropic component reaches 1-2 GeV. For such high deposition energies, statistical multifragmentation models predict much more extensive nuclear disassembly than is observed. 相似文献
32.
Hemigossypol (3), a sesquiterpene natural product, was previously isolated from Gossypium barbadense and was shown to display improved anti-fungal activity compared to gossypol (1), the disesquiterpene dimer of hemigossypol (3). Gossypol exhibits multiple biological activities. In order to study whether hemigossypol and its derivatives retain the various bioactivities of gossypol, we developed a short and convenient synthetic scheme to synthesize hemigossypol. This is the first de novo synthesis of this natural product. In addition derivatives of hemigossypol with various 2,5-alkyl substituents were synthesized. Modification of the synthetic scheme also afforded the natural product hemigossylic lactone (4) and its 2,5-substituted derivatives. 相似文献
33.
Alaerts G Dejaegher B Smeyers-Verbeke J Vander Heyden Y 《Combinatorial chemistry & high throughput screening》2010,13(10):900-922
The use of chromatographic fingerprints from herbal products where the whole chromatographic profile is applied to evaluate the quality of the investigated product. In this paper, recent developments in the set-up and data analysis of chromatographic fingerprints for herbal products are discussed. First different set-ups for fingerprint development are reviewed. Prior to fingerprint development, a suitable sample preparation, e.g. extraction, should be considered. In a second instance, this review focuses on the data analysis with regards to the different applications of fingerprints. Usually, chemometric data pretreatment is necessary. This is discussed first, followed by a short overview of the data handling techniques used in the two main application areas of herbal fingerprints, i.e. quality assurance and classification or calibration. The quality assurance, which involves the identification and quality control of the herbal products, is reviewed, followed by the use of fingerprints in classification or modelling. The different application areas are illustrated and discussed with several case studies. 相似文献
34.
Halewyck H Oita I Thys B Dejaegher B Vander Heyden Y Rombaut B 《Electrophoresis》2010,31(19):3281-3287
Poliovirions, purified from infected cell extracts with anion-exchange chromatography, can be analyzed and identified by CE in untreated fused silica capillaries using UV detection. Other subviral particles can be eluted as well from the same infected cell extract using a higher salt concentration buffer on the ion-exchange chromatography. Virions can be identified because of their conversion into empty capsids upon heating at 56°C. As a result of heating, the viral genome is released from the capsid. Here, we show that during this incubation some intermediate particles were found. The latter were identified by enzymatic peak shift analysis. The high salt concentration eluate subviral particles were analyzed with preincubation affinity CE together with their sensitivity for RNase and proteinase K treatment. Electropherograms of the higher salt concentration eluate display a mixture of at least four different subviral particles. One particle proved to have an [N1, H] antigenicity and was resistant to RNase and proteinase K digestion. The remaining particles were all sensitive to proteinase K treatment. This CE method proved to be valuable in the detection, identification and analysis of poliovirions and poliovirus particles offering an alternative powerful, cheap, fast and easy analysis method. 相似文献
35.
Bernard Masereel Mustapha Dinguizli Caroline Bouzin Nicolas Moniotte Olivier Feron Bernard Gallez Thierry Vander Borght Carine Michiels Stéphane Lucas 《Journal of nanoparticle research》2011,13(4):1573-1580
Nanoscale materials are used in the biomedical field for magnetic resonance imaging, protein detection and drug/gene delivery.
Gold nanoparticles (AuNPs) are particularly investigated in cancer treatment and imaging. In this study, we described a simple
and reliable liquid method to coat AuNPs (diameter: 21 nm) layer-by-layer with alternative cationic polyallylamine and anionic
polystyrenesulfonate. The C-terminal amino acid of the antibody directed against anti-bovine serum albumin was activated by
EDC/NHS, and then condensed with the amino functions of the external polyallylamine layer. An ELISA test confirmed that the
antigen recognition of the bioconjugate antibody was conserved. This AuNP coating and the covalently coupling could be used
as a generic process for binding other specific antibodies, particularly those overexpressed in cancer cells and angiogenesis. 相似文献
36.
D.F. Sanchez F.P. Luce Z.E. Fabrim M.A. Sortica P.F.P. Fichtner P.L. Grande 《Surface science》2011,605(7-8):654-658
Medium energy ion scattering (MEIS) measurements and transmission electron microscopy (TEM) observations are applied to characterize a buried Pb nanoparticle (NP) system synthesized by ion implantation. The NPs are located at the SiO2/Si film interface, forming a dense two-dimensional array. Full 2D (energy and angle) experimental MEIS spectra are compared with Monte Carlo simulated ones. The results demonstrate that MEIS measurements provide microstructural information (mean NP volume of about 150 nm3 and areal density of about 4 × 1011 NP/cm2), but no accurate information on the NP geometrical shape. 相似文献
37.
D. Parenthoine L.-P. Tran-Huu-HueL. Haumesser F. Vander MeulenM. Lematre M. Lethiecq 《Ultrasonics》2011,51(2):109-114
Quadratic nonlinear equations of a piezoelectric element under the assumptions of 1D vibration and weak nonlinearity are derived by the perturbation theory. It is shown that the nonlinear response can be represented by controlled sources that are added to the classical hexapole used to model piezoelectric ultrasonic transducers. As a consequence, equivalent electrical circuits can be used to predict the nonlinear response of a transducer taking into account the acoustic loads on the rear and front faces. A generalisation of nonlinear equivalent electrical circuits to cases including passive layers and propagation media is then proposed. Experimental results, in terms of second harmonic generation, on a coupled resonator are compared to theoretical calculations from the proposed model. 相似文献
38.
We report on an experimental demonstration of linear precompensation of nonlinear phase and amplitude transfer functions. We show the effective compensation with a linear all-fiber system of phase-to-amplitude modulation conversion due to a complete frequency conversion system including plane gratings and a nonlinear crystal. 相似文献
39.
We report on what we believe is the first experimental demonstration of the linear precompensation of a nonlinear transfer function due to frequency conversion. As a proof of principle, we show the effective precompensation with an interferometric filter of FM-to-AM conversion due to second-harmonic generation in a potassium titanyl phosphate crystal. 相似文献
40.
Justin J Heynekamp Lucy A Hunsaker Thomas A Vander Jagt Lorraine M Deck David L Vander Jagt 《BMC chemical biology》2006,6(1):1-11