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871.
872.
Luca Cocconi Rosalba Garcia-Millan Zigan Zhen Bianca Buturca Gunnar Pruessner 《Entropy (Basel, Switzerland)》2020,22(11)
The rate of entropy production by a stochastic process quantifies how far it is from thermodynamic equilibrium. Equivalently, entropy production captures the degree to which global detailed balance and time-reversal symmetry are broken. Despite abundant references to entropy production in the literature and its many applications in the study of non-equilibrium stochastic particle systems, a comprehensive list of typical examples illustrating the fundamentals of entropy production is lacking. Here, we present a brief, self-contained review of entropy production and calculate it from first principles in a catalogue of exactly solvable setups, encompassing both discrete- and continuous-state Markov processes, as well as single- and multiple-particle systems. The examples covered in this work provide a stepping stone for further studies on entropy production of more complex systems, such as many-particle active matter, as well as a benchmark for the development of alternative mathematical formalisms. 相似文献
873.
Kristian Piscicchia Johann Marton Sergio Bartalucci Massimiliano Bazzi Sergio Bertolucci Mario Bragadireanu Michael Cargnelli Alberto Clozza Raffaele Del Grande Luca De Paolis Carlo Fiorini Carlo Guaraldo Mihail Iliescu Matthias Laubenstein Marco Miliucci Edoardo Milotti Fabrizio Napolitano Andreas Pichler Alessandro Scordo Hexi Shi Diana Laura Sirghi Florin Sirghi Laura Sperandio Oton Vazquez Doce Johann Zmeskal Catalina Curceanu 《Entropy (Basel, Switzerland)》2020,22(11)
The VIP collaboration is performing high sensitivity tests of the Pauli Exclusion Principle for electrons in the extremely low cosmic background environment of the underground Gran Sasso National Laboratory INFN (Italy). In particular, the VIP-2 Open Systems experiment was conceived to put strong constraints on those Pauli Exclusion Principle violation models which respect the so-called Messiah–Greenberg superselection rule. The experimental technique consists of introducing a direct current in a copper conductor, and searching for the X-rays emission coming from a forbidden atomic transition from the L shell to the K shell of copper when the K shell is already occupied by two electrons. The analysis of the first three months of collected data (in 2018) is presented. The obtained result represents the best bound on the Pauli Exclusion Principle violation probability which fulfills the Messiah–Greenberg rule. 相似文献
874.
Francesco Mambretti Nicol Pedrani Luca Casiraghi Elvezia Maria Paraboschi Tommaso Bellini Samir Suweis 《Entropy (Basel, Switzerland)》2022,24(4)
Molecular ecology uses molecular genetic data to answer traditional ecological questions in biogeography and biodiversity, among others. Several ecological principles, such as the niche hypothesis and the competitive exclusions, are based on the fact that species compete for resources. More in generally, it is now recognized that species interactions play a crucial role in determining the coexistence and abundance of species. However, experimentally controllable platforms, which allow us to study and measure competitions among species, are rare and difficult to implement. In this work, we suggest exploiting a Molecular Dynamics coarse-grained model to study interactions among single strands of DNA, representing individuals of different species, which compete for binding to other oligomers considered as resources. In particular, the well-established knowledge of DNA–DNA interactions at the nanoscale allows us to test the hypothesis that the maximum consecutive overlap between pairs of oligomers measure the species’ competitive advantages. However, we suggest that a more complex structure also plays a role in the ability of the species to successfully bind to the target resource oligomer. We complement the simulations with experiments on populations of DNA strands which qualitatively confirm our hypotheses. These tools constitute a promising starting point for further developments concerning the study of controlled, DNA-based, artificial ecosystems. 相似文献
875.
Gilles Berger Luca Fusaro Michel Luhmer Arie van der Lee Benoit Crousse Franck Meyer 《Tetrahedron letters》2014
We report the synthesis of several new α-trifluoromethylated nitrogen heterocycles, among which azanorbornene and azetidine derivatives, by aza Diels–Alder or iodine-mediated cyclizations. These building blocks were used as starting materials for the formation of fluorinated polymers by ROMP or for ligand design through substitution and click reactions. 相似文献
876.
877.
Gianluca Ambrosi Mauro Formica Vieri Fusi Luca Giorgi Mauro Micheloni 《Coordination chemistry reviews》2008,252(10-11):1121
The coordination properties of a selected series of acyclic and macrocyclic ligands containing one or more phenolic groups are explored. The formation of polynuclear metal complexes was only considered highlighting the key role played by the phenoxide oxygen atom in binding two metal centres in a bridge disposition. This arrangement allows two metal ions to stay close each other and consequently these dinuclear centres are able to mimic many biological sites, especially those where the two metals can cooperate to form an active centre. Catalytic properties of these polynuclear complexes, when studied, have been reported. Also some of the numerous heterodinuclear metal complexes that have been synthesized are here reviewed, included several crystal structures. 相似文献
878.
Luca Vincenzo Ballestra Graziella Pacelli Francesco Zirilli 《Nonlinear Analysis: Hybrid Systems》2008,2(2):568-589
We consider the problem of pricing European interest rate derivatives based on the LIBOR Market Model (LMM) with one driving factor. We derive a closed-form approximation of the transition probability density functions associated to the stochastic dynamical systems that describe the behaviour of the forward LIBOR interest rates in the LMM. These approximate formulae are based on a truncated power series expansion of the solutions of the Fokker–Planck equations associated to the LMM. The approximate probability density functions obtained are used to price European interest rate derivatives using the method of discounted expectations. The resulting integrals are low dimensional when the most commonly traded European interest rate derivatives are considered, and they can be computed efficiently using elementary numerical quadrature schemes (i.e. Simpson’s rule). The algorithm obtained is very well suited for parallel computing and is tested on the problem of pricing several derivatives including an European swaption and an interest rate spread option. In both cases, the method proposed in this paper appears to be accurate (i.e. relative error of order 10−2, 10−3, or even 10−4) and approximately between 278 and 63 000 times faster than previous methods based on the Monte Carlo simulation of the LMM stochastic dynamical systems.
The website http://www.econ.univpm.it/pacelli/ballestra/finance/w2 contains material that helps the understanding of this paper and makes available to the interested users the computer programs that implement the numerical method proposed. 相似文献
879.
Luca Paglieri Giorgina Corongiu Darío A. Estrin 《International journal of quantum chemistry》1995,56(5):615-625
The effects of the solvent on the tautomeric equilibria of cytosine and uracil are studied using Onsager's reaction field model in the framework of density functional theory. In this model, the solute molecule is placed in a spherical cavity of radius ao immersed in a continuous medium with a dielectric constant e, treating the solute-solvent electrostatic interactions at the dipole level. The cavity radius is evaluated by determining the molecular volume with a quantum mechanical approach. The solvent effect brings significant changes in the geometrical parameters of some cytosine tautomers, but only very small changes to those of the uracil tautomers. Our results are in good agreement with available experimental results and confirm that the polarization of the solute by the continuum has important effects on the absolute and relative solvation energies. Frequency shifts and intensity variations in the infrared spectra due to the presence of the solvent are also presented. © 1995 John Wiley & Sons, Inc. 相似文献
880.
Let b?2 be an integer. We prove that real numbers whose b-ary expansion satisfies some given, simple, combinatorial condition are transcendental. This implies that the b-ary expansion of any algebraic irrational number cannot be generated by a finite automaton. To cite this article: B. Adamczewski et al., C. R. Acad. Sci. Paris, Ser. I 339 (2004). 相似文献