两相流测量的三光束偏振型LDV装置

两相流的测量是许多工业装置中遇到的一个十分重要的课题,本文引入了一种新的测量装置。它采用三光束偏振型光路消除了边缘效应,输出信号由计算机软件处理,采用双阁值法方便、有效地对两相流的速度进行测量。适当改进后,本装置能同时对两相流的粒子尺度及粒子速度进行测量。     

Sobolev embeddings into BMO, VMO, andL ∞

LetX be a rearrangement-invariant Banach function space onR ⁿ and letV ¹ X be the Sobolev space of functions whose gradient belongs toX. We give necessary and sufficient conditions onX under whichV ¹ X is continuously embedded into BMO or intoL _∞. In particular, we show thatL _{n, ∞} is the largest rearrangement-invariant spaceX such thatV ¹ X is continuously embedded into BMO and, similarly,L _{n, 1} is the largest rearrangement-invariant spaceX such thatV ¹ X is continuously embedded intoL _∞. We further show thatV ¹ X is a subset of VMO if and only if every function fromX has an absolutely continuous norm inL _{n, ∞} . A compact inclusion ofV ¹ X intoC ⁰ is characterized as well.     

XRD,SAXS, and PALS investigations of three different polymers reinforced with tetraoctylammonium exchanged montmorillonite

Three different polymer nanocomposites were prepared using clay modified with tetraoctylammonium (4C8) surfactant. The dispersion of clay silicate layers was studied using X-ray diffraction and small-angle scattering. Free-volume cavity sizes were studied with positron annihilation lifetime spectroscopy. Scattering methods confirmed disruption of all polymer lamellae organization upon organoclay addition and the creation of partially intercalated systems for polyamide and polycaprolactone. The presence of organoclay in the polymers enlarges the lower value of average positronium lifetime τ₃ of polyamide and reduces the higher value of τ₃ for polycaprolactone and polyethylene.     

Miniaturisation of solid phase extraction method for determination of retinol,alpha- and gamma-tocopherol in human serum using new technologies

The aim of this study was to develop rapid and simple solid phase extraction (SPE) and HPLC methods for simultaneous determination of retinol, gamma- and alpha-tocopherol in human serum using a special auto sampler with micro titration plates.

Separation of vitamins was performed at ambient temperature using monolithic column on a HPLC containing rack changer for micro titration plates. As the mobile phase methanol with flow rate 2.5 mL min^?1 was used. The injection volume was 20 µL. Retinol was detected at 325 nm, gamma- and alpha-tocopherol were carried out at 295 nm, respectively. The total time of analysis was 1.8 minutes. Extraction method was developed using Spe-ed 96 C18, 100 mg/2 mL micro titration plates and SPE vacuum manifold. The consumption of the sample was 50 µL. Time of the analysis for 96 samples on one micro titration plate was 1.5 hour. In order to validate the developed method, precision, accuracy, linearity, detection and quantitation limits were evaluated. This method is suitable for rapid automated large-batch analysis of retinol, alpha- and gamma-tocopherol in small sample volumes of human serum.     

К ТЕОРИИ СПОНТАННОЙ Н АМАГНИЧЕННОСТИ ТОНК ИХ СЛОЕВ. I. ЧАСТЬ

- - , - . - . -, - [6]. 1956 . , .     

The quantum theory of the spontaneous magnetization of ferrimagnetics,anti-ferromagnetics and thin films with arbitrary spin at high temperatures

Using Van Vleck's modification of the Heisenberg theory of ferro-magnetism for substances with arbitrary spin per atom, a generalization of the theory is given for the case of ferrimagnetics, anti-ferromagnetics and thin films with an arbitrary number of sub-lattices and with arbitrary spin per atom. The exchange part of the energy operator is formulated by means of rotated spin operators. The theory contains the quantum-mechanical generalization of non-quantum theories given by Néel and later generalized by Yafet and Kittel. It also contains the theory of thin films proposed recently by the author. The magnetization laws are completely analogous to the relations derived from the theory of molecular fields. The constants of the molecular fields are interpreted by means of exchange integrals. For the special case of spin S=1/2the theory agrees with the results of the work of Vlasov and Imuchametov for ferrimagnetics and anti-ferromagnetics and with the author's for thin films.

---

,

, , , . . - , . , . , . . S=1/2 .

     

Geometric aspects of robust testing for normality and sphericity

Stochastic robustness of control systems under random excitation motivates challenging developments in geometric approach to robustness. The assumption of normality is rarely met when analyzing real data and thus the use of classic parametric methods with violated assumptions can result in the inaccurate computation of p-values, effect sizes, and confidence intervals. Therefore, quite naturally, research on robust testing for normality has become a new trend. Robust testing for normality can have counterintuitive behavior, some of the problems have been introduced in Stehlík et al. [Chemometrics and Intelligent Laboratory Systems 130 (2014 Stehlík, M., St?elec, L., and Thulin, M. 2014. On robust testing for normality in chemometrics. Chemometrics and Intelligent Laboratory Systems 130:98–108.[Crossref], [Web of Science ®] , [Google Scholar]): 98–108]. Here we concentrate on explanation of small-sample effects of normality testing and its robust properties, and embedding these questions into the more general question of testing for sphericity. We give geometric explanations for the critical tests. It turns out that the tests are robust against changes of the density generating function within the class of all continuous spherical sample distributions.     

Growth and kinetics of in vitro poly([R]‐(–)‐3‐hydroxybutyrate) granules interpreted as particulate polymerization with coalescence

Transmission electron microscopy (TEM) and Cryo‐TEM were used to study the growth kinetics of poly(3‐hydroxybutyrate) granules produced by in vitro polymerization. The in vitro formation of poly(3‐hydroxybutyrate) uses a recombinant form of the PHA synthase to polymerize [R]‐(–)‐3‐hydroxybutyryl‐CoA. Since the in vitro reaction contains only synthase and monomer, it is a simpler system than the in vivo biosynthesis of poly(3‐hydroxybutyrate). TEM and Cryo‐TEM were used in conjunction with image analysis to examine the granules that were formed in the in vitro reaction. The in vitro reaction yielded spherical granules of rapidly increasing size; the initially observed granules were already larger than 0.1 μm. While the average granule diameter and volume increased with reaction time, the number of granules decreased throughout the reaction due to coalescence. Basic kinetic parameters, including K_M and V_max were determined and compared to those reported for the in vivo biosynthesis of poly(3‐hydroxybutyrate). In addition it was found that the granules formed by this process were essentially noncrystalline. A computer simulation of the reaction, based on initial formation of relatively large microporous granules that consolidate by expulsion of water during polymerization, accounted for the shape of the kinetic curves.