全文获取类型
收费全文 | 189篇 |
免费 | 6篇 |
专业分类
化学 | 153篇 |
晶体学 | 2篇 |
数学 | 4篇 |
物理学 | 36篇 |
出版年
2022年 | 5篇 |
2021年 | 8篇 |
2019年 | 4篇 |
2017年 | 2篇 |
2016年 | 6篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 4篇 |
2012年 | 9篇 |
2011年 | 17篇 |
2010年 | 7篇 |
2009年 | 7篇 |
2008年 | 10篇 |
2007年 | 8篇 |
2006年 | 6篇 |
2005年 | 10篇 |
2004年 | 8篇 |
2003年 | 10篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1996年 | 2篇 |
1994年 | 4篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1988年 | 2篇 |
1985年 | 2篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1969年 | 2篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1960年 | 1篇 |
1958年 | 1篇 |
1912年 | 1篇 |
1892年 | 1篇 |
1891年 | 2篇 |
1887年 | 1篇 |
1885年 | 1篇 |
1882年 | 2篇 |
1878年 | 2篇 |
1867年 | 2篇 |
1865年 | 1篇 |
排序方式: 共有195条查询结果,搜索用时 312 毫秒
191.
Orilall MC Abrams NM Lee J DiSalvo FJ Wiesner U 《Journal of the American Chemical Society》2008,130(28):8882-8883
A combined assembly of soft and hard chemistries is employed to generate highly crystalline three-dimensionally ordered macroporous (3DOM) niobia (Nb2O5) and titania (TiO2) structures by colloidal crystal templating. Polystyrene spheres with sp2 hybridized carbon are used in a reverse-template infiltration technique based on the aqueous liquid phase deposition of the metal oxide in the interstitial spaces of a colloidal assembly. Heating under inert atmosphere as high as 900 degrees C converts the polymer into sturdy carbon that acts as a scaffold and keeps the macropores open while the oxides crystallize. Using X-ray diffraction it is demonstrated that for both oxides this approach leads to highly crystalline materials while heat treatments to lower temperatures commonly used for polymer colloidal templating, in particular for niobia, results in only weakly crystallized materials. Furthermore it is demonstrated that heat treatment directly to higher temperatures without generating the carbon scaffold leads to a collapse of the macrostructure. The approach should in principle be applicable to other 3DOM materials that require heat treatments to higher temperatures. 相似文献
192.
Van Hoof S Lacey CJ Röhrich RC Wiesner J Jomaa H Van Calenbergh S 《The Journal of organic chemistry》2008,73(4):1365-1370
(E)-1-Hydroxy-2-methyl-but-2-enyl 4-diphosphate (HMBPP) is an intermediate in the non-mevalonate pathway for the biosynthesis of isoprenoids and also serves as a very strong activator of human gamma delta T cells expressing Vgamma9Vdelta2 receptors. This paper describes the synthesis of analogues of HMBPP, in which the diphosphate group is replaced by potential isosteric moieties, i.e., carbamate, N-acyl-N'-oxy sulfamate, or aminosulfonyl carbamate functionalities. The potential of the synthesized analogues to stimulate Vgamma9/Vdelta2 T cell response or to inhibit GcpE and LytB, the last enzymes in the non-mevalonate pathway, was assessed. 相似文献
193.
Gong XY Dobrunz D Kümin M Wiesner M Revell JD Wennemers H Hauser PC 《Journal of separation science》2008,31(3):565-573
The separation and detection of small oligopeptides in CE with contactless conductivity detection were demonstrated. A strongly acidic separation buffer (0.5 M acetic acid) was employed in order to render the species cationic. Separation of the stereoisomers was achieved in typically 10-15 min by using either dimethyl-beta-CD (DM-beta-CD), (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid (18C(6)H(4)), a combination of the two substances, or of histidine, as buffer additives. Calibration curves were determined for isomers of Gly-Asp and H-Pro-Asp-NH(2), in the range of 0.05-0.5 mM and 0.1-1 mM, respectively, and were found to be linear. LODs were determined to be in the order of 1.0 microM. The determination of isomeric impurities down to about 1% was found possible. Species showing good separation could also be successfully determined on an electrophoretic lab-on-chip device, with analysis times of a few minutes. 相似文献
194.
Ursula Tracht Ricarda Leiberich Udo Wiesner Hanns-Ingolf Paul 《Macromolecular Symposia》2011,302(1):208-215
Summary: Catalyst systems for polymerization often exhibit variable and poorly controllable activity because of strong influences of trace components and catalyst preparation conditions. In cationic polymerizations in particular, determining catalytic activity and hence the amount of catalyst to be used is challenging. The assessment of a given initiator system typically requires testing it in polymerization reactions. Determining catalytic activity before using the initiator in a polymerization reaction is a desirable approach. This contribution describes the development of such an activity monitoring tool. In the first part, results from a fundamental characterization of the system diethylaluminum chloride/ethylaluminum dichloride/water by different NMR measurements and elemental analysis are reported. Structures characteristic of catalytically active systems are presented. The second part describes the application of transmission IR to the characterization of this system and the correlation of IR results to catalytic activity in dimerization and polymerization reactions. Implementation of the IR analysis as an on-line measurement is demonstrated. 相似文献
195.