超分子模糊识别

在超分子主-客体识别系统中,由专一作用如多重氢键、拓扑捕捉、金属-配体驱动的识别虽然具有高选择性,但要求主体具有严格的尺寸、形状和电子环境;同时识别通常限于那些具有拓扑特征和电子特征的分子,这类识别机制称为静态识别。另一方面,由超支化聚合物衍生的核-壳两亲大分子(CAM),方便易得且有广泛的客体亲合性,但客体选择性通常较低。近年的研究表明,CAM的核经过合适的电子性质改性后,竞争客体分子间的差异可被放大,从而实现高选择性包裹与分离,而CAM最大的特点是核内有大量随机分布的官能团,从而可以进行各种精细的改性。这一由复杂系统的非线性特征导致的识别不需要专一作用的推动,适合于复杂分子的识别,被称为超分子模糊识别。实验表明,超分子模糊识别主体可以用于各种离子客体的高效分离,还可以识别拓扑特征和电子特征非常相似的分子。本文就超分子模糊识别的机制、特点以及应用作了综述。     

A time-varying hyperchaotic system and its realization in circuit

A hyperchaotic system is often used to generate secure keys or carrier wave for secure communication and the realistic hyperchaotic circuit often is made of capacitor, nonlinear resistor unit and induction coil. Parameters are often fixed in these hyperchaotic circuits and the hyperchaotic property of the system can be estimated by using a scheme of synchronization and time series analysis. In this paper, a time-varying hyperchaotic system is proposed by introducing changeable electric power source into the circuit; the changeable electric power source is combined with induction coil or capacitor in series to generate changeable output signals to excite the system. The diagrams of improved circuit are illustrated and critical parameters in experimental circuits are presented; the Lyapunov exponent spectrum vs. external applied electric power source is calculated. It is confirmed that the improved circuit always holds two positive Lyapunov exponents when the external electric power source works, and the chaotic attractors are much too different from the original one; thus, a more changeable hyperchaotic system is constructed in experiment.     

Coherent beam combining of hybrid phase control in master oscillator-power amplifier configuration

A novel scalable architecture for coherent beam combining with hybrid phase control involving passive phasing and active phasing in master oscillator-power amplifier configuration is presented. Wide-linewidth mutually injected passive phasing fibre laser arrays serve as master oscillators for the power amplifiers, and the active phasing using stochastic parallel gradient descent algorithm is induced. Wide-linewidth seed laser can suppress the stimulated Brillouin scattering effectively and improve the output power of the fibre laser amplifier, while hybrid phase control provides a robust way for in-phase mode coherent beam combining simultaneously. Experiment is performed by active phasing fibre laser amplifiers with passive phasing fibre ring laser array seed lasers. Power encircled in the main-lobe increases1.57 times and long-exposure fringe contrast is obtained to be 78% when the system evolves from passive phasing to hybrid phasing.     

弹道靶开式微波谐振腔测量系统研究

The principle and experimental results of the open microwave resonant cavity measurement system were introduced. The models were steel ball models and the ball models coated with copper. The diameter of the models was 10mm. The models were launched in ballistic range. The model velocity was 5.44 km.s^-1. The wake electron density of the models was obtained. The experimental results presents that the response time of the open microwave resonant cavity measurement system was quicker than 1ms. The results showed the wake electron density ranged from 10⁹cm^-3 to 10¹¹cm^-3 could be achieved.     

Numerical and experimental study on coherent beam combining of fibre amplifiers using simulated annealing algorithm

We present the numerical and experimental study on the coherent beam combining of fibre amplifiers by means of simulated annealing (SA) algorithm. The feasibility is validated by the Monte Carlo simulation of correcting static phase distortion using SA algorithm. The performance of SA algorithm under time-varying phase noise is numerically studied by dynamic simulation. It is revealed that the influence of phase noise on the performance of SA algorithm gets stronger with an increase in amplitude or frequency of phase noise; and the laser array that contains more lasers will be more affected from phase noise. The performance of SA algorithm for coherent beam combining is also compared with a widely used stochastic optimization algorithm, i.e., the stochastic parallel gradient descent (SPGD) algorithm. In a proof-of-concept experiment we demonstrate the coherent beam combining of two 1083~nm fibre amplifiers with a total output power of 12~W and 93% combining efficiency. The contrast of the far-field coherently combined beam profiles is calculated to be as high as 95%.     

热处理温度对化学溶液沉积GdBiO_3薄膜生长的影响

以铋、钆的硝酸盐等制备前驱溶胶体系,用CSD法在SrTiO3(100)基底上制备出c轴织构良好的可作为涂层导体缓冲层的GdBiO3(GBO)薄膜。首先利用差热分析的结果对GBO薄膜分解过程的吸、放热情况进行了研究,确定了较为适当的有机物分解工艺。在此基础上研究了不同外延成相热处理温度对GBO薄膜生长的影响,并对较高温度处理后样品产生裂纹的原因进行了初步分析。GBO薄膜的相组成和微结构利用XRD和SEM进行分析。研究结果表明,在Ar气氛中适宜于GBO薄膜生长的最佳温度在770℃度附近,在此条件下可以制备出表面平整致密的GBO薄膜。     

Self-assembly of Polyaniline: Mechanism Study

在水热环境下合成出\掺杂电荷诱导自组装纳米纤维阵列结构的聚苯胺平板,并通过一系列设计实验研究了这种自组装微观结构的形成机理,例如在反应溶液中引入不参与反应、对电荷组装起干扰作用的电解质,以及用计算模拟体系静电能与纳米纤维阵列夹角的相互关系等实验．实验结果发现,由掺杂离子引起的静电相互作用在形成聚苯胺自组装结构的过程中起了重要的作用．     

轴向隐失波激励的回音壁模式光纤激光器

采用轴向隐失波激励增益的方式,使激光增益区域局限在光纤回音壁模式的模场区域内,显著地降低了回音壁模式光纤激光辐射的抽运阈值,由此形成一种低阈值的回音壁模式光纤激光器.在微焦耳量级的低抽运能量条件下,用回音壁模式光纤激光器研究了激光染料的浓度效应.实验结果表明,随着激光染料浓度的增加,回音壁模式激光辐射的波长向长波方向移动,激光波长范围变宽.用回音壁模式染料激光的四能级模型得到激光上能级和所有能级上的分子数比值γ(λ)曲线后,很好地解释了实验结果.低抽运阈值的回音壁模式光纤激光器,为研究液体激光现象提供了极为便利的手段.     

Singularities and spectral changes of Gaussian beams focused by a lens with spherical aberration

We address the effect of the truncation parameter and spherical aberration (SA) on the singularity transformation and spectral behavior of the polychromatic Gaussian beams focused by an aperture lens with SA in detail. The numerical simulation results, based on the derived equations of the intensity and the spectral density, are given. It is found that the axial singularities vanished with the change of the truncated parameter. The intensity and drastic spectral change fade away with an annihilation process of the phase singularities, and the drastic spectral change does not disappear immediately at the moment the phase singularity annihilates. The singularities in the focal region will redistribute with the increment of SA coefficient, some singularities will vanish, some will spilt into two new singularities, and other off-axial singularities will appear and split into two new singularities as well. When SA coefficient changed, we can find that the axial singularities disappear as well with the decreasing value of truncation parameter. These new splitted singularities due to the change of SA coefficient will converge into one singularity again and disappear gradually.     

Mott relation for anomalous Hall and Nernst effects in Ga1-xMnxAs ferromagnetic semiconductors

The Mott relation between the electrical and thermoelectric transport coefficients normally holds for phenomena involving scattering. However, the anomalous Hall effect (AHE) in ferromagnets may arise from intrinsic spin-orbit interaction. In this work, we have simultaneously measured AHE and the anomalous Nernst effect (ANE) in Ga1-xMnxAs ferromagnetic semiconductor films, and observed an exceptionally large ANE at zero magnetic field. We further show that AHE and ANE share a common origin and demonstrate the validity of the Mott relation for the anomalous transport phenomena.