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101.
2-Amino-2,4-anhydro-psicofuranose derivative was synthesized starting from d-fructose. 相似文献
102.
103.
Recent experiments revealed that the dielectric dispersion spectrum of fission yeast cells in a suspension was mainly composed of two sub-dispersions. The low-frequency sub-dispersion depended on the cell length, while the high-frequency one was independent of it. The cell shape effect was simulated by an ellipsoidal cell model but the comparison between theory and experiment was far from being satisfactory. Prompted by the discrepancy, we proposed the use of spectral representation to analyze more realistic cell models. We adopted a shell-spheroidal model to analyze the effects of the cell membrane. It is found that the dielectric property of the cell membrane has only a minor effect on the dispersion magnitude ratio and the characteristic frequency ratio. We further included the effect of rotation of dipole induced by an external electric field, and solved the dipole-rotation spheroidal model in the spectral representation.Good agreement between theory and experiment has been obtained. 相似文献
104.
环上矩阵的广义Moore-Penrose逆 总被引:14,自引:0,他引:14
本文给出带有对合的有1的结合环上一类矩阵的广义Moore-Penrose逆存在的充要条件,而这类矩阵概括了左右主理想整环,单Artin环上所有矩阵。 相似文献
105.
B—模糊集合代数和广义互信息公式 总被引:1,自引:0,他引:1
基于两种概率的区分,推导出了一个广义Shannon熵公式和一个广义互信息公式。后者和模糊性有关,并且柯用于语言和感觉中的信息度量。为了由原子语句为真的条件概率求出合语句为真的条件概率,提出了一个遵循存尔运算的模糊集合代数。所谓的模糊信息被还原为概率信息。新的理论在经典理论-概率论,集合论及Shannon信息论-的基础上容易理解。 相似文献
106.
This paper examines the capabilities of cryogenic sample handling to examine composition and structure of hydrogel materials where siloxane components are central to the analysis. XPS analysis of multicomponent polymers with cryogenic sample handling following exposure to aqueous environments has revealed the composition and kinetics of near surface reorganization for siloxane and fluorocarbon containing polymers. In this study we report results from a ToF-SIMS protocol for cryogenic sample handling applied to the analysis of surface changes upon hydration/dehydration of hydrogel polymers. Comparison of results from angle dependent XPS and ToF-SIMS are discussed for a range of commercial soft contact lens materials. Both methods detected changes in surface chemistry between the hydrated (frozen) and dehydrated surfaces. Analysis of the hydrated surfaces detected polymer components indicative of the commercial formulation as well as ice clusters. Analysis of the dehydrated materials detected changes in surface chemistry relative to the hydrated surface in addition to loss of water due to sample dehydration. A quantitative standard additions method for ToF-SIMS data was used to determine submonolayer amounts of PDMS impurities at the surface of the hydrogels. ToF-SIMS analysis of a series of seven poly (allyl methacrylate-g-dimethylsiloxane), AMA-g-DMS, graft copolymers in the hydrated state revealed high mass oligomeric ion distributions for systems with bulk PDMS content greater than 25 wt.%. This marks the first time that detection of high mass oligomeric ion distributions from hydrated (frozen) surfaces has been reported. Analysis of the dehydrated surface detected formation of high mass oligomeric ion distributions for systems with PDMS bulk content greater than 15 wt.%, but only detected these ion distributions in wet (frozen) samples when the bulk concentration was greater than 25 wt.%. 相似文献
107.
Chih-Wei Lu 《Optics Communications》2006,259(1):281-285
We demonstrate experimentally and theoretically a method for enhancing the axial resolution of optical low-coherence reflectometry (OLCR) beyond the Fourier transform limit of light source spectrum. The resolution enhancement originates from the superposition of multiple OLCR scans with different offsets of the center-wavelength light-ray with respect to the rotation axis of the mirror mounted on the galvanometer optical scanner in the used optical phase delay line. After certain software process of the multiple scan fringe patterns of different offsets, the superposition leads to an OLCR axial resolution beyond the transform limit. Experimentally, by using four different offsets for superposition, about 1.5 times enhancement of the transform-limit resolution is obtained. 相似文献
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110.
The prediction of the peak width at half height is an important aspect in the optimization of the chromatographic operating conditions. In this paper, a linear relationship, between the peak widths at half height and the retention values with various isocratic elution is observed. In gradient elution, however, the relationship between the peak widths at half height and the so-called invented retention values that correspond to the mobile phase composition by eluting the solute from the column end is developed. We believe that there is almost the same band width at half height inside the column (in unit of length) for different solutes. The peak width at half height in the chromatogram (in unit of time) is mainly determined by the capacity factor of the solute when it is eluted from the column end. The larger the capacity factor of a solute eluted from the column end, the more slowly will be the solute eluted from the column end and the wider will be the peak width at half height. It is possible to predict the peak width at half height in various isocratic and gradient elutions by using this linear relationship. 相似文献