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71.
A polymer-supported diphenylphosphoryl azide was prepared. This polymer-supported version of DPPA is useful due to its lower toxicity, moisture tolerance and ease of workup after reaction. The synthetic application of this solid-phase reagent was explored by conversion of a variety of carboxylic acids to urethanes and ureas through Curtius rearrangement reactions. Carboxylic acids bearing different functional groups (aromatic, aliphatic and heterocyclic carboxylic acids) were subjected to the reaction. The corresponding products were isolated with satisfactory yields. 相似文献
72.
Zhao Zheng Zhang Jian-hua Jiang Ya-ling 《International Journal of Theoretical Physics》1997,36(6):1359-1368
The Hawking effect of a nonuniformly rectilinearly accelerating Kinnersley black hole is studied. Its horizons are rotationally
symmetric. Its Hawking temperature depends not only on the time, but also on the polar angle. When a Kinnersley black hole
touches its Rindler horizon, the Hawking temperature at the contact point is reduced to zero. But at the opposite pole of
the black hole, the Hawking temperature increases rapidly. A jet appears as a tail of the accelerating black hole. 相似文献
73.
报道了KDP晶体中的三倍频产生的实验研究,计算了比较了直接三倍频过程和级联过程对KDP晶体三阶有效非线性系数的贡献,并探讨了KDP作为非线性晶体材料三阶非线性系数测量基准的可行性。 相似文献
74.
Song Jiang 《Mathematische Nachrichten》1998,190(1):169-183
We consider initial boundary value problems for the equations of the one-dimensional motion of a viscous, heat-conducting gas with density-dependent viscosity that decreases (to zero) with decreasing density. We prove that if the viscosity does not decrease to zero too rapidly, then smooth solutions exist globally in time. 相似文献
75.
Space time-index plots for probing dynamical nonstationarity 总被引:3,自引:0,他引:3
We propose a simple method to efficiently probe dynamical nonstationarity in observed time series. In a space time-index plot, the density distributions as a function of normalized time-index are V-shaped due to nonstationarity. We show that this method is workable for short data sets and typical examples are illustrated. 相似文献
76.
周期系数三种群Lotka-Volterra混合模型分析 总被引:3,自引:0,他引:3
考虑三种群Lotka-Volterra周期系数模型,种群间既有捕食关系又有竞争关系,得到唯一存在全局渐近稳定周期解的条件,并举例说明条件的可行性. 相似文献
77.
本文证明了周期单元中带有某些硬相互作用的相对论Boltzmann方程初值问题在初值满足质量、能量和熵有限的条件下具有一个整体温和解. 相似文献
78.
79.
80.
The structural stability of heat-treated CoN/CN soft X-ray multilayers fabricated by dual-facing-target sputtering has been investigated by using complementary measurement techniques. The high temperature annealing results imply that the destructive threshold of the Co/C multilayers is improved by 100–200 degrees centigrade through doping with N. The low-angle X-ray diffraction of CoN/CN soft X-ray multilayers indicates that the period expansion of the multilayers is only 4 % at 400°C, and the interface pattern still exists even if they were annealed at 700°C. The Raman spectra analyses give the evidence that the formation of the sp3 bonding in the CN sublayers can be suppressed effectively by doping N with atoms, and thus the period expansion resulting from the changes in the density of CN layers can be decreased considerably. The X-ray photoelectron spectra analyses present the information of the existence of the strong covalent bonding betweenC andN atoms, and the ionic bonding between Co and N atoms, which can slow down the tendency of the structural relaxation. The interstitial N atoms decrease the mobility of Co atoms, and thus the fcc-Co and hcp-Co coexist even though the annealing temperature is much higher than the phase transformation temperature of 420°C, leading to the suppression of the grain growth. 相似文献