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91.
Jing Zhang Dan Shan Shaolin Mu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(23):5573-5582
A copolymer, poly(aniline‐co‐o‐aminophenol), was prepared chemically by using ammonium peroxydisulfate as an oxidant. The monomer concentration ratio of o‐aminophenol to aniline strongly influences the copolymerization rate and properties of the copolymer. The optimum composition of a mixture for the chemical copolymerization consisted of 0.3 M aniline, 0.021 M o‐aminophenol, 0.42 M ammonium peroxydisulfate, and 2 M H2SO4. The result of cyclic voltammograms in a potential region of ?0.20 to 0.80 V (vs.SCE) indicates that the electrochemical activity of the copolymer prepared under the optimum condition is similar to that of polyaniline in more acid solutions. However, the copolymer still holds the good electrochemical activity until pH 11.0. Therefore, the pH dependence of the electrochemical property of the copolymer is improved, compared with poly(aniline‐co‐o‐aminophenol) prepared electrochemically, and is much better than that of polyaniline. The spectra of IR and 1H NMR confirm that o‐aminophenol units are included in the copolymer chain, which play a key role in extending the usable pH region of the copolymer. The visible spectra of the copolymers show that a high concentration ratio of o‐aminophenol to aniline in a mixture inhibits the chain growth. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5573–5582, 2007 相似文献
92.
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94.
Ben-Yuan Gu Yao Lu Tzong-Jer Yang 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(4):493-502
We present numerical investigations of the transmission properties of electrons in a normal quantum wire tangentially attached
to a superconductor ring threaded by magnetic flux. A point scatterer with a δ -function potential is placed at node to model
scattering effect. We find that the transmission characteristics of electrons in this structure strongly depend on the normal
or superconducting state of the ring. The transmission probability as a function of the energy of incident electrons, in the
case of a superconductor ring threaded by one quantum magnetic flux, emerges one deep dip, imposed upon the first broad bump
in spectrum. This intrinsic conductance dip originates from the superconductor state of the ring. When increasing the magnetic
flux from one quantum magnetic flux to two, the spectrum shifts toward higher energy region in the whole. This conductance
dip accordingly shifts and appears in the second bump. In the presence of a point-scatterer at the node, the spectrum is substantially
modified. Based on the condition of the formation of the standing wave functions in the ring and the broken of the time-reserve
symmetry of Schr?dinger equation after switching magnetic flux, the characteristics of transmission of electrons in this structure
can be well understood.
Received 6 November 2001 相似文献
95.
基础房价的相关指标及其走势一直是大众关心的热门话题.本文通过对上海基础房价相关指标的分析,建立了市场房价走势的两个数学模型.模型一:在相关性分析的基础上利用主成分分析消除指标间的共线性,再用回归拟合房价模型并进行预测;模型二:在相关性分析的基础上利用核估计方法预测出房价.继呵对2005年下半年的房价走势进行了预测,得出的结果与实际情况相吻合. 相似文献
96.
97.
Y.-Q. Peng J.-H. Yang F.-P. Lu Q.-S. Yang H.-W. Xing X.-S. Li C.-A. Song 《Applied Physics A: Materials Science & Processing》2007,86(2):225-229
Based on the assumption of Gaussian energy distributions of the lowest unoccupied molecular orbital (LUMO) and the highest occupied molecular orbital (HOMO), analytical expressions of generalized Einstein relation in chemically doped organic semiconductor are developed, by approximation of Coulomb traps with a rectangle potential well. Numerical calculations show that traditional Einstein relations do not hold for chemically doped organic semiconductors. Similar to physical doping, the dependence of diffusion coefficient to mobility D/μ ratio on the carrier concentration has a maximum. An essential difference between chemical doping and physical doping is that, the D/μ ratio in chemically doped organic semiconductors depends not only on carrier concentration and doping concentration, but also on the applied electric field. PACS 71.20.Rv; 72.90.+y; 73.50.-h 相似文献
98.
99.
Journal of the Operational Research Society - Serious environmental problems have accompanied China's remarkable economic growth for decades, which also have direct and indirect impacts on its... 相似文献
100.
Dendritic nanocrystalline CdS film was deposited at liquid-liquid interface of surfactants and an electrolyte containing 4 mmol L−1 cadmium chloride (CdCl2) and 16 mmol L−1 thioacetamide (CH3CSNH2) with an initial pH value of 5 at 15 °C by electrochemical synthesis. The nanofilm was characterized by transmission electron microscopy (TEM), field emission scanning electron microscope (FE-SEM), atomic force microscopy (AFM), ultraviolet visible (UV-vis) absorption spectroscopy and fluorescence spectroscopy. The surface morphology and particle size of the nanofilm were investigated by AFM, SEM and TEM, and the crystalline size was 30-50 nm. The thickness of the nanofilm calculated by optical absorption spectrum was 80 nm. The microstructure and composition of the nanofilm was investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), showing its polycrystalline structure consisting of CdS and Cd. Optical properties of the nanofilm were investigated systematically by UV-vis absorption and fluorescence spectroscopy. A λonset blue shift compared with bulk CdS was observed in the absorption spectra. Fluorescence spectra of the nanofilm indicated that the CdS nanofilm emitted blue and green light. The nanocomposites film electrode will bring about anodic photocurrent during illumination, showing that the transfer of cavities produces photocurrent. 相似文献