全文获取类型
收费全文 | 2733篇 |
免费 | 102篇 |
国内免费 | 7篇 |
专业分类
化学 | 2134篇 |
晶体学 | 7篇 |
力学 | 41篇 |
数学 | 388篇 |
物理学 | 272篇 |
出版年
2024年 | 2篇 |
2023年 | 25篇 |
2022年 | 79篇 |
2021年 | 95篇 |
2020年 | 71篇 |
2019年 | 76篇 |
2018年 | 37篇 |
2017年 | 42篇 |
2016年 | 109篇 |
2015年 | 96篇 |
2014年 | 103篇 |
2013年 | 167篇 |
2012年 | 197篇 |
2011年 | 202篇 |
2010年 | 154篇 |
2009年 | 113篇 |
2008年 | 171篇 |
2007年 | 150篇 |
2006年 | 136篇 |
2005年 | 137篇 |
2004年 | 130篇 |
2003年 | 102篇 |
2002年 | 99篇 |
2001年 | 34篇 |
2000年 | 41篇 |
1999年 | 31篇 |
1998年 | 25篇 |
1997年 | 26篇 |
1996年 | 30篇 |
1995年 | 22篇 |
1994年 | 22篇 |
1993年 | 19篇 |
1992年 | 21篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1989年 | 5篇 |
1988年 | 7篇 |
1987年 | 11篇 |
1986年 | 8篇 |
1985年 | 7篇 |
1984年 | 2篇 |
1983年 | 5篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1970年 | 2篇 |
排序方式: 共有2842条查询结果,搜索用时 0 毫秒
31.
Claudia Patricia Granja-Banguera Daniel Gerardo Silgado-Cortzar Jimmy Alexander Morales-Morales 《Molecules (Basel, Switzerland)》2022,27(5)
This study used substituted barium hexaferrites, which were previously prepared and reported by the authors, to detect acetaminophen by the modification of a conventional glassy carbon electrode (GCE), which led to promising results. The synthesis of this electrode-modifying material was conducted using a citrate sol gel process. A test synthesis using glycerin and propylene glycol revealed that glycerin produced a better result, while less positive anodic potential values were associated with the electrooxidation of N-acetyl-p-aminophenol (NAP). Excellent electroactivity was exhibited by the cobalt-substituted barium-hexaferrite-nanomaterial-modified electrode. A good linear relationship between the concentration and the current response of acetaminophen (paracetamol) was obtained with a detection limit of (0.255 ± 0.005) µM for the Ba1.0Co1.22Fe11.41O18.11 GCE, (0.577 ± 0.007) µM for the Ba1.14Cu0.82Fe11.65O18.02 GCE, and (0.595 ± 0.008) µM for the bare GCE. The levels of NAP in a real sample of urine were quantitatively analyzed using the proposed method, with recovery ranges from 96.6% to 101.0% and 93.9% to 98.4% for the modified electrode with Cobalt-substituted barium hexaferrites (CoFM) and Copper-substituted barium hexaferrites (CuFM), respectively. These results confirm the high electrochemical activity of Ba1.0Co1.22Fe11.41O18.11 nanoparticles and thus their potential for use in the development of sensing devices for substances of pharmaceutical interest, such as acetaminophen (NAP). 相似文献
32.
This work reports the structure and superconducting properties of the superconductor ZrRuP doped with Fe; the ZrRu1−xFexP solid solution was investigated by means of X-ray powder diffraction, SQUID magnetometry and Mößbauer spectroscopy. It is shown that the modification of the superconducting properties by doping with Fe is similar to the effect of chemical pressure and that the Fe doped compounds do not show any magnetic ordering. 相似文献
33.
Lifshitz Transitions Induced by Temperature and Surface Doping in Type‐II Weyl Semimetal Candidate Td‐WTe2 (Phys. Status Solidi RRL 12/2017) 下载免费PDF全文
34.
In this paper, we study the polynomial integrability of natural Hamiltonian systems with two degrees of freedom having a homogeneous potential of degree k given either by a polynomial, or by an inverse of a polynomial. For k=−2,−1,…,3,4, their polynomial integrability has been characterized. Here, we have two main results. First, we characterize the polynomial integrability of those Hamiltonian systems with homogeneous potential of degree −3. Second, we extend a relation between the nontrivial eigenvalues of the Hessian of the potential calculated at a Darboux point to a family of Hamiltonian systems with potentials given by an inverse of a homogeneous polynomial. This relation was known for such Hamiltonian systems with homogeneous polynomial potentials. Finally, we present three open problems related with the polynomial integrability of Hamiltonian systems with a rational potential. 相似文献
35.
Zaragoza-Contreras EA Hernández-Escobar CA Navarrete-Fontes A Flores-Gallardo SG 《Micron (Oxford, England : 1993)》2011,42(3):263-270
In this study, carbon black/polystyrene electrically conductive composites were obtained by suspension polymerization technique. The composite was characterized using transmission electron microscopy, which indicated two outstanding features concerning to the carbon black; first, that the carbon particles were adsorbed onto the surface of the polystyrene particles, similarly as in the Pickering emulsion phenomenon and second, that the primary aggregate structure of the carbon black was significantly affected by the dispersion process. On the other hand, the composite resistivity was in the order of 200 Ωcm, which was attributed to the direct contact of primary carbon black particles (percolation) and not to the tunneling effect. The obtained composite was evaluated as the electrically conductive element in SBR matrix. 相似文献
36.
To minimize a convex function, we combine Moreau-Yosida regularizations, quasi-Newton matrices and bundling mechanisms. First
we develop conceptual forms using “reversal” quasi-Newton formulae and we state their global and local convergence. Then,
to produce implementable versions, we incorporate a bundle strategy together with a “curve-search”. No convergence results
are given for the implementable versions; however some numerical illustrations show their good behaviour even for large-scale
problems. 相似文献
37.
Davor Pavuna Daniel Ariosa Dominique Cloetta Claudia Cancellieri Mike Abrecht 《Pramana》2008,70(2):237-243
Since 1997 we systematically perform direct angle resolved photoemission spectroscopy (ARPES) on in-situ grown thin (<30 nm) cuprate films. Specifically, we probe low-energy electronic structure and properties of high-T
c superconductors (HTSC) under different degrees of epitaxial (compressive vs. tensile) strain. In overdoped and underdoped
in-plane compressed (the strain is induced by the choice of substrate) ≈15 nm thin La2 − x
Sr
x
CuO4 (LSCO) films we almost double T
c to 40 K, from 20 K and 24 K, respectively. Yet the Fermi surface (FS) remains essentially two-dimensional. In contrast, ARPES
data under tensile strain exhibit the dispersion that is three-dimensional, yet T
c drastically decreases. It seems that the in-plane compressive strain tends to push the apical oxygen far away from the CuO2 plane, enhances the two-dimensional character of the dispersion and increases T
c, while the tensile strain acts in the opposite direction and the resulting dispersion is three-dimensional. We have established
the shape of the FS for both cases, and all our data are consistent with other ongoing studies, like EXAFS. As the actual
lattice of cuprates is like a ‘Napoleon-cake’, i.e. rigid CuO2 planes alternating with softer ‘reservoir’, that distort differently under strain, our data rule out all oversimplified two-dimensional
(rigid lattice) mean field models. The work is still in progress on optimized La-doped Bi-2201 films with enhanced T
c.
相似文献
38.
The Team Orienteering Problem (TOP) is the generalization to the case of multiple tours of the Orienteering Problem, known
also as Selective Traveling Salesman Problem. A set of potential customers is available and a profit is collected from the
visit to each customer. A fleet of vehicles is available to visit the customers, within a given time limit. The profit of
a customer can be collected by one vehicle at most. The objective is to identify the customers which maximize the total collected
profit while satisfying the given time limit for each vehicle. We propose two variants of a generalized tabu search algorithm
and a variable neighborhood search algorithm for the solution of the TOP and show that each of these algorithms beats the
already known heuristics. Computational experiments are made on standard instances. 相似文献
39.
Monia Vadrucci Anna Mazzinghi Beatrice Sorrentino Stella Falzone Claudia Gioia Patrizia Gioia Ersilia M. Loreti Massimo Chiari 《X射线光谱测定》2020,49(6):668-678
Scientific investigation is very important in studies addressing issues of archaeological and historical objects. Ion beam analysis (IBA) and macro X-ray fluorescence (MA-XRF) spectroscopy are remarkable tools to obtain information about elemental composition and imaging of historical artefacts with a non-invasive character. These investigation techniques were employed in the framework of a project aimed at supporting the characterization of materials and techniques related with the Roman wall painting. The archaeological excavations at Villa della Piscina in Rome have revealed a luxury building with a large pool (about 50 m long) and thermal baths and numerous fragments of plaster, coming from intentional demolitions referable to two distinct architectural contexts of the Villa during the imperial age, have been found. This work deals with studying the interesting wall pictorial apparatus of great cultural value of the heritage inherited from the Roman age in the area of the ancient city of Rome. The colour palette of the pigments investigated, in particular, by MA-XRF and particle-induced X-ray emission (PIXE) and has revealed Fe, Cu, Pb, Si and Hg as main elements. Traces of other constituents uncover the choice of the different colours chosen by the artists who had embellished the rooms of the Villa. 相似文献
40.
We consider semilinear evolution equations for which the linear part generates a strongly continuous semigroup and the nonlinear part is sufficiently smooth on a scale of Hilbert spaces. In this setting, we prove the existence of solutions which are temporally smooth in the norm of the lowest rung of the scale for an open set of initial data on the highest rung of the scale. Under the same assumptions, we prove that a class of implicit, A-stable Runge–Kutta semidiscretizations in time of such equations are smooth as maps from open subsets of the highest rung into the lowest rung of the scale. Under the additional assumption that the linear part of the evolution equation is normal or sectorial, we prove full order convergence of the semidiscretization in time for initial data on open sets. Our results apply, in particular, to the semilinear wave equation and to the nonlinear Schrödinger equation. 相似文献