全文获取类型
收费全文 | 136篇 |
免费 | 1篇 |
专业分类
化学 | 46篇 |
力学 | 3篇 |
数学 | 23篇 |
物理学 | 65篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 5篇 |
2020年 | 1篇 |
2018年 | 3篇 |
2016年 | 5篇 |
2015年 | 4篇 |
2014年 | 2篇 |
2013年 | 4篇 |
2012年 | 6篇 |
2011年 | 10篇 |
2010年 | 2篇 |
2009年 | 4篇 |
2008年 | 7篇 |
2007年 | 4篇 |
2006年 | 2篇 |
2005年 | 4篇 |
2003年 | 2篇 |
2002年 | 1篇 |
2001年 | 3篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 3篇 |
1997年 | 1篇 |
1996年 | 8篇 |
1995年 | 3篇 |
1994年 | 10篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1969年 | 1篇 |
1934年 | 1篇 |
1933年 | 2篇 |
排序方式: 共有137条查询结果,搜索用时 15 毫秒
11.
Barros W de Sousa PL Engelsberg M 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,165(1):175-179
Intermolecular double-quantum coherence (i-DQC) signals in liquids are usually associated with high magnetic fields. We demonstrate that, in a magnetic field of only 16mT, i-DQC imaging of water protons is feasible thanks to the nuclear magnetization enhancement produced by the Overhauser effect. i-DQC images of a phantom containing an aqueous solution of a trityl free radical, with phase encoding in the DQC evolution period or in the acquisition period, are presented. Possible applications of low field i-MQC images are proposed. 相似文献
12.
Supershell structure in alkali metal nanowires 总被引:1,自引:0,他引:1
Nanowires are formed by indenting and subsequently retracting two pieces of sodium metal. Their cross section gradually reduces upon retraction and the diameters can be obtained from the conductance. In previous work we have demonstrated that when one constructs a histogram of diameters from large numbers of indentation-retraction cycles such histograms show a periodic pattern of stable nanowire diameters due to shell structure in the conductance modes. Here, we report the observation of a modulation of this periodic pattern, in agreement with predictions of a supershell structure. 相似文献
13.
S.A. Loureiro A.Z. Salustiano D.S. dos Santos 《Journal of Physics and Chemistry of Solids》2007,68(10):1845-1855
The present work aims to correlate, in time, macroscale and microscale phenomenological evolutions of the microstructure of Fe and FeZn alloys processed by mechanical milling (MM) and alloying (MA), respectively. Powders were characterized for particle size distribution (PSD), particle morphology (optical microscopy, OM, scanning electron microscopy, SEM), microhardness, crystallite size, differential scanning calometry (DSC) and transmission electron microscopy (TEM). Two macroscopic regimes of PSD behavior were distinguished: the first one dominated by the cold welding process; and, the other where both fracture and agglomeration play a significant role. Solid solubilization of Zn on bcc Fe was found to reduce the final microhardness as well as increase the lattice parameter and is very well predicted by Miedema's thermodynamical approach. Microhardness and solid solution formation kinetics were correlated in time and both could be precisely described by a logistic function. After 5 h of planetary milling, microhardness and the lattice parameter become stable as well as the PSD and particle morphology, indicating that the system has already reached steady state. Indeed, this condition can be monitored by both macroscopic and microscopic parameters. Prior to an homogeneous powder, DSC results suggest an endothermic solid-state amorphization reaction for samples processed for up to 1 h as a result of the formation of clean Fe/Zn interfaces during MA. 相似文献
14.
Cristiana Loureiro de Mendonça Couto 《Ambix》2015,62(4):345-362
Brazilian cuisine is much admired by present-day international chefs. However, in the nineteenth century, local ingredients and recipes were looked down upon by the Portuguese colonists, as well as by visiting European naturalists. This fact, together with medical and chemical views formulated throughout the 1800s, led locally trained doctors to attribute the occurrence of countless diseases that devastated Rio de Janeiro to local staple foods, particularly corn and manioc flour. In the first part of the present article, I review the dietary habits of Brazilians through the eyes of European naturalists who travelled across the country in the early nineteenth century. In the second part, I summarise the ideas formulated by French and German chemists on the components, and consequent nutritional value, of cereals and other sources of flour, and then analyse the appropriation of such ideas—particularly those of Justus Liebig—by Brazilian doctors and their adaptation to local conditions. 相似文献
15.
Near-wall data for the strongly perturbed flow in a neutrally stable boundary layer encountering a steep, smooth, two-dimensional
hill are presented. Observations were made on the centerplane of a water channel at thirteen stations relative to the hill
by laser Doppler anemometry. The large reverse flow region that is formed on the lee of the hill was particularly scrutinized
through seven measuring stations. Results are presented for the mean and turbulent properties of the flow. Wall shear stress
was evaluated through fitting procedures that resorted to the near wall behavior of the velocity profile. Logarithmic fits
as well as predictions through the Reynolds stress profiles are also presented. 相似文献
16.
17.
First we show that the quadratic decomposition of the Appell polynomials with respect to the q-divided difference operator is supplied by two other Appell sequences with respect to a new operator \(\mathcal{M}_{q;q^{-\varepsilon}}\), where ε represents a complex parameter different from any negative even integer number. While seeking all the orthogonal polynomial sequences invariant under the action of \(\mathcal{M}_{\sqrt{q};q^{-\varepsilon/2}}\) (the \(\mathcal{M}_{\sqrt{q};q^{-\varepsilon/2}}\)-Appell), only the Wall q-polynomials with parameter q ε/2+1 are achieved, up to a linear transformation. This brings a new characterization of these polynomial sequences. 相似文献
18.
Anthony JM Garrett 《Contemporary Physics》2013,54(2):163-165
The dynamic electronic structure of atoms and molecules can be directly observed by means of the (e, 2e) reaction, which measures the distribution of energies and momenta of two electrons in coincidence after a knockout reaction initiated by an electron beam of known momentum incident on a molecular gas target. The molecular state for each event is identified by the electron separation energy. The recoil momentum for each event is known from the difference of measured initial and final momenta. It has been verified that values of this momentum are equal under suitable conditions to the momentum of the electron in the target immediately before knockout. Thus the spherically-averaged electron momentum distribution for each molecular orbital is measured. This is directly related to molecular orbitals calculated by the methods of quantum chemistry. Properties obtained by this method for different types of molecules are discussed. 相似文献
19.
A conceptual model of resistive magnetic reconnection via a stochastic plasmoid chain is proposed. The global reconnection rate is shown to be independent of the Lundquist number. The distribution of fluxes in the plasmoids is shown to be an inverse-square law. It is argued that there is a finite probability of emergence of abnormally large plasmoids, which can disrupt the chain (and may be responsible for observable large abrupt events in solar flares and sawtooth crashes). A criterion for the transition from the resistive magnetohydrodynamic to the collisionless regime is provided. 相似文献
20.
Cletus A D'Souza Vikramjit Chopra Richard Varhol Yuan-Yun Xie Slavita Bohacec Yongjun Zhao Lisa LC Lee Mikhail Bilenky Elodie Portales-Casamar An He Wyeth W Wasserman Daniel Goldowitz Marco A Marra Robert A Holt Elizabeth M Simpson Steven JM Jones 《BMC neuroscience》2008,9(1):1-14