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81.
Reactions of MoNCl3 and WNCl3 with Elemental Fluorine. Crystal Structures of [MoO2F2(THF)2] and [WF4(NCl)(CH3CN)] The nitrido chlorides MoNCl3 and WNCl3 as well as WCl4(NCl) react with elemental fluorine forming the N-chloro imido complexes MoF4(NCl) and WF4(NCl), which were characterized by IR spectroscopy. With tetrahydrofurane MoF4(NCl) reacts to give [MoF4(NCl)(THF)], which in THF solution slowly converts into [MoO2F2(THF)2]. From WF4(NCl) with acetonitrile the complex [WF4(NCl)(CH3CN)] is obtained. Both donor acceptor complexes were characterized by crystal structure determinations. [MoO2F2(THF)2] : Space group P21/n, Z = 4, structure solution with 1823 unique reflections, R = 0.033 for reflections with I > 2σ(I). Lattice dimensions at ?40°C: a = 636.2, b = 1119.5, c = 1625.2 pm; β = 93.92(1)º. The compound has a monomeric molecular structure with the fluorine atoms in trans-position to one another and with the oxygen atoms of the THF molecules in trans to the oxo ligands. [WF4(NCl)(CH3CN)] : Space group P21/m, Z = 2, structure solution with 1119 unique reflections, R = 0.038 for reflections with I > 2σ(I). Lattice dimensions at 20°C: a = 511.7, b = 714.9, c = 1002.5 pm; β = 102.59(10)º. The compound has a monomeric molecular structure in which the nitrogen atom of the acetonitrile molecule coordinates in trans-position to the N-chloro imido group W?N? Cl. The structural parameters of this group are WN = 172.2 pm, NCl = 161.1 pm, WNCl = 178.6º. 相似文献
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Free vibration problems of lattice sandwich beams under several typical boundary conditions are investigated in the present paper. The lattice sandwich beam is transformed to an equivalent homogeneous three-layered sandwich beam. Unlike the traditional analytical model in which the rotation angles of the face sheets and the core are assumed the same, different rotation angles are considered in this paper to characterize the real response of sandwich beams. The analytical solutions of the natural frequencies for several typical boundary conditions are obtained. The effects of material properties and geometric parameters on the natural frequencies are also investigated. 相似文献
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Zirui Song Kangyu Zou Xuhuan Xiao Xinglan Deng Shuo Li Prof. Dr. Hongshuai Hou Prof. Dr. Xiaoming Lou Prof. Dr. Guoqiang Zou Prof. Dr. Xiaobo Ji 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(65):16082-16092
Nowadays sodium-based energy storage systems (Na-based ESSs) have been widely researched as it possesses the possibility to replace traditional energy storage media to become next generation energy storage system. However, due to the irreversible loss of sodium ions in the first cycle, development of Na-based ESSs is limited. Presodiation, as a strategy of adding excess sodium ions to the system in advance, accomplishes the enhancement of electrochemical performance. In this minireview, different presodiation strategies applied in sodium-based energy storage systems will be summarized in detail, their functions and corresponding mechanisms will be discussed as well. Furthermore, the current novel application of presodiation method in other aspects of Na-based ESSs will be mentioned additionally. At last, in the view of present research status of presodiation, issues that can be mitigated are put forward and guidelines are given on how to deliberate in-depth presodiation technology in the future, dedicating to promote the further development of Na-based ESSs. 相似文献
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Lou Ching-Wen Wu Zong-Han Lee Mong-Chuan Lin Jia-Horng 《Research on Chemical Intermediates》2018,44(8):4957-4970
Research on Chemical Intermediates - A highly efficient oligomer antimicrobial agent, polyhexamethylene guanidine hydrochloride (PHMGH), is added to mixtures of polyvinylpyrrolidone (PVP)/chitosan... 相似文献
90.
Selective Oxidation of Alcohols with a New Reagent: Iron(III) Nitrate Supported on Aluminum Silicate
A selective and effective oxidation of alcohols, except aliphatic alcohols, such as 1‐hexanol or 1‐octyl alcohol, to the corresponding aldehydes and ketones using a new reagent, iron(III) nitrate supported on aluminum silicate, under heterogeneous conditions with reflux with 85–98% yield is described. 相似文献