Isomerisation Catalysee Par le Gel de Silice et L'argile Activee de N-Acyl-2,2-Dimethylaziridines: Approche Mecanistique

Silica gel and activated clay, behaving as Lewis acids, reacted with N-acyl-2,2-dimethylaziridines 1 to lead to pentacoordinated aziridinium silicate ions. The regiospecific ring opening on the CMe₂ carbon side of the intermediate I involves, after removal of the catalyst, the zwitterion II. The zwitterion II undergoes either a transfer of proton leading to the N-methallylamide 2 or intramolecular cyclization reaction leading to the oxazoline 3. The unstable oxazoline 3 on catalyst is hydrated in turn into amidoalcohol 4 via the oxazolinium silicate III.     

Centralized resource allocation for enhanced Russell models

This paper proposes a centralized resource allocation (CRA) model for the enhanced Russell model. All the DMUs can be easily projected onto the efficient frontier by solving only one model. This projection can be made by transforming the proposed model to a linear programming problem. In this paper, instead of non-radially increasing or decreasing the inputs or outputs individually, we increase or decrease non-radially all of the inputs and outputs at the same time. By solving a single model, we can provide targets for all DMUs. By the proposed approximation, different targets can be found for all DMUs, as compared to those obtained by the previous approximations. The proposed model can be developed to CRA models. Finally, an applied example emphasizes the importance of the proposed model.     

An improved method for ranking alternatives in multiple criteria decision analysis

Scoring rules are an important disputable subject in data envelopment analysis (DEA). Various organizations use voting systems whose main object is to rank alternatives. In these methods, the ranks of alternatives are obtained by their associated weights. The method for determining the ranks of alternatives by their weights is an important issue. This problem has been the subject at hand of some authors. We suggest a three-stage method for the ranking of alternatives. In the first stage, the rank position of each alternative is computed based on the best and worst weights in the optimistic and pessimistic cases, respectively. The vector of weights obtained in the first stage is not a singleton. Hence, to deal with this problem, a secondary goal is used in the second stage. In the third stage of our method, the ranks of the alternatives approach the optimistic or pessimistic case. It is mentionable that the model proposed in the third stage is a multi-criteria decision making (MCDM) model and there are several methods for solving it; we use the weighted sum method in this paper. The model is solved by mixed integer programming. Also, we obtain an interval for the rank of each alternative. We present two models on the basis of the average of ranks in the optimistic and pessimistic cases. The aim of these models is to compute the rank by common weights.     

Cost evaluation in M/G/1 queue with T-policy revisited, technical note

This note clarifies the concept of regeneration cycle used in evaluating the average operating cost of the M/G/1 queue with T-policy studied in 70s. Two ways of defining the regeneration cycle are compared and advantages and disadvantages of each way are pointed out. In addition, we establish the convexity of the cost function based on the service cycle.     

Electrical characterization and modeling of Au/MEH-PPV/porous n+-GaAs/n+-GaAs heterojunction in direct and alternating current mode

Assembled heterojunction was fabricated by spin-coating poly[2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylene-vinylene)] (MEH-PPV) thin layers on straight and porous n⁺-GaAs substrates. The current–voltage and capacitance–voltage studies have shown an abrupt junction behavior with current conduction governed by SCLC and thermionic modes. Andersons' rules were used to determine depletion width and balance bands discontinuities for both heterojunctions. Capacitance and conductance vs. frequency techniques were used to evaluate the density of interface states. Density values obtained from both techniques were in a good agreement.     

An H‐matrix Type Preconditioner For Frictional Contact Problems

The bilateral or unilateral contact problem with Coulomb friction between two elastic bodies is considered [1]. An algorithm is introduced to solve the resulting finite element system by a non‐overlapping domain decomposition method [2, 3]. The global problem is transformed to a independant local problems posed in each bodie and a problem posed on the contact surface (the interface problem). The solution is obtained by using a successive approximation method, in each step of this algorithm we solve two intermediate problems the first with prescribed tangential pressure and the second with prescribed normal pressure [8]. Our preconditioner construction is based on the application of the H‐matrix technique [6, 7] together with the representation of the H^1/2 seminorm by a sum of partial seminorms [4]. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Bosonic quartic couplings at LEP2

We list the set of and conserving anomalous quartic vector bosons self-couplings which can be tested at LEP2 through triple vector boson production. We show how this set can be embedded in manifestly gauge invariant operators exhibiting an global symmetry. We derive bounds on these various couplings and show the most relevant distributions that can enhance their contribution. We also find that an collider running at 500 GeV can improve the LEP2 limits by as much as three-orders of magnitude. Received: 9 September 1999 / Revised version: 19 October 1999 / Published online: 17 February 2000     

Palm cryobanking

We describe the development of an efficient cryopreservation protocol for proembryogenic masses (PEMs) of date palm variety 'Barhee'. Proembryos were induced by inoculating small pieces of juvenile leaves on MS medium supplemented with 0.3 mg per liter 2,4-D. Application of these in vitro conditions led to true-to-type plants as observed after plant fructification. When compared to the standard vitrification protocol, the ultra-rapid droplet-vitrification technique proved to be superior. Sucrose preculture considerably increased post-cryopreservation recovery. The highest regeneration after cryogenic exposure reached 63.3 percent when PEMs were treated with PVS2 for 30 min at 0 degree C and 56.7 percent when PVS2 treatment lasted for 15 min at 25 degree C. The first signs of regrowth of cryopreserved PEMs were observed after 2 to 3 weeks. Cryopreservation did not affect the morphogenetic capacities of the plant material. Moreover, highly proliferating suspension cultures could be established from the cryopreserved material. The overall production of somatic embryos from 500 mg cryopreserved PEMs reached 1030 +/- 50 units after 1 month. The morphological study of date palms regenerated from cryopreserved material confirmed the stability of clonal material following cryopreservation.     

Double Higgs production at the linear colliders and the probing of the Higgs self-coupling

We study double Higgs production in the e⁺e^? and γγ modes of the linear collider. It is also shown how one can probe the scalar potential in these reactions. We discuss the effective longitudinal W approximation in γγ processes and the W _LW_L luminosities in the two modes of a high-energy linear collider. A generalised non-linear gauge-fixing condition, which is particularly useful for tree-level calculations of electroweak processes for the laser induced collider, is presented. Its connection with the background-field approach to gauge fixing is given.     

Effect of the server capacity distribution on the optimal control of a bulk service queueing system

In this paper the optimal control of a single-channel bulk service queueing system with random server capacity is investigated. Given an accumulation level r, the server stops processing new customers whenever the queue falls below r and resumes service when the queue reaches level r again. Server capacity becomes random following an idle period. A quick search procedure is designed to determine the value of r that yields the minimum expected total cost per unit of time. The effect of the server capacity distribution on the optimal control is then studied. Finally, a sensitivity analysis is conducted in order to assess the extent to which our results are valid.