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211.
P. Rudolf R. Raval P. Dumas G.P. Williams 《Applied Physics A: Materials Science & Processing》2002,75(1):147-153
Infrared (IR) spectroscopy of chemisorbed C60 on Ag (111), Au (110) and Cu (100) reveals that a non-IR-active mode becomes active upon adsorption, and that its frequency
shifts proportionally with the charge transferred from the metal to the molecule by about 5 cm-1 per electron. The temperature dependence of the frequency and the width of this IR feature have also been followed for C60/Cu (100) and were found to agree well with a weak anharmonic coupling (dephasing) to a low-frequency mode, which we suggest
to be the frustrated translational mode of the adsorbed molecules.
Additionally, the adsorption is accompanied by a broadband reflectance change, which is interpreted as due to the scattering
of conduction electrons of the metal surface by the adsorbate. The reflectance change allows determination of the friction
coefficient of the C60 molecules, which results in rather small values (∼2×109 s-1 for Ag and Au, and ∼1.6×109 s-1for Cu), consistent with a marked metallic character of the adsorbed molecules.
Pre-dosing of alkali atoms onto the metal substrates drastically changes the IR spectra recorded during subsequent C60 deposition: anti-absorption bands, as well as an increase of the broadband reflectance, occur and are interpreted as due
to strong electron–phonon coupling with induced surface states.
Received: 6 June 2001 / Accepted: 23 October 2001 / Published online: 3 April 2002 相似文献
212.
A.R. DegheidyM.T. Attia M. Sallah 《Journal of Quantitative Spectroscopy & Radiative Transfer》2002,74(3):285-297
The time-independent radiative transfer problem in a scattering and absorbing planar random medium with general boundary conditions and internal energy source is considered. The medium is assumed to consist of two randomly mixed immiscible fluids, with the mixing statistics described as a two-state homogeneous Markov process. The problem is solved in terms of the solution of the corresponding free-source problem with simple boundary conditions which is solved using Pomraning-Eddington approximation in the deterministic case. A formalism, developed to treat radiative transfer in statistical mixtures, is used to obtain the ensemble-averaged solution. The average partial heat fluxes are calculated in terms of the albedoes of the source-free problem. Results are obtained for isotropic and anisotropic scattering for specular and diffused reflecting boundaries. 相似文献
213.
214.
The method described in this paper allows an investigator to determine the intrinsic stress of a polymer layer in a way that
does not result in damage to devices or test structures. The method requires that a small area of the polymer be released
from the substrate to form a diaphragm. The diaphragm is stimulated with acoustic white noise and the diaphragm movement is
monitored with a laser vibrometer. The first few resonance frequencies of the diaphragm are obtained using a laser vibrometer
and then those frequencies are used to calculate the membrane intrinsic bi-axial tension. 相似文献
215.
The pure state space of Quantum Mechanics is investigated as Hermitian Symmetric Kähler manifold. The classical principles of quantum mechanics (Quantum Superposition Principle, Heisenberg Uncertainty Principle, Quantum Probability Principle) and Spectral Theory of observables are discussed in this non-linear geometrical context. 相似文献
216.
Mutual–temporal coherence of the supercontinuum (SC) generation has been experimentally investigated using a diffraction grating based interferometer. A broadband SC generation was produced in a pyrex glass plate with a 1.6-μm coherence length at 550-nm center wavelength. The degree of mutual coherence of 0.34 was measured for a wavefront shift for zero and first diffraction orders of half of the beam diameter. A design of SC source with the capability of manipulating the amplitudes and phases of optical frequency components within the SC pulse is presented for coherence applications. 相似文献
217.
218.
M Lepère R Gobeille V.Malathy Devi M.A.H Smith B Aoaeh A.W Mantz 《Journal of Molecular Spectroscopy》2004,224(1):7-12
We have analyzed the methyl fluoride RQ(J,0)Q branch lines located near 1475 cm−1 using a simultaneous multi-spectrum fitting technique. In this analysis we have used previously recorded diode-laser data in which we collected many data points covering only one or two Q branch lines in a particular run. The analysis consists of simultaneously fitting 57 spectra collected with numerous pressure and path length conditions for all absorption lines. The data are concatenated to create one continuous spectrum of the Q branch. We have determined the intensity and self-broadened widths at 296 K for 23 RQ(J,0) lines. 相似文献
219.
Thin films of Ti1−xCoxO2 (x=0 and 0.03) have been prepared on sapphire substrates by spin-on technique starting from metalorganic precursors. When heat treated in air at 550 and 700 °C, respectively, these films present pure anatase and rutile structures as shown both by X-ray diffraction and Raman spectroscopy. Optical absorption indicate a high degree of transparency in the visible region. Such films show a very small magnetic moment at 300 K. However, when the anatase and the rutile films are annealed in a vacuum of 1×10−5 Torr at 500 and 600 °C, respectively, the magnetic moment, at 300 K, is strongly enhanced reaching 0.36μB/Co for the anatase sample and 0.68μB/Co for the rutile one. The ferromagnetic Curie temperature of these samples is above 350 K. 相似文献
220.
The results of experimental investigations on thermal nonequilibrium ionization in CO2: N2: He mixtures are presented. Measurements of electron density, ne, in vibrationally excited nitrogen were made in a supersonic flow with different CO2 contents as well as in a CO2: N2: He = 1 : 5 : 4 mixture laser gas. The mixtures were heated in a shock tube and expanded through a supersonic nozzle. Furthermore, supersonic mixing of N2 and CO2 + He was used in some experiments. The measured values of ne in the plenum chamber and in the supersonic nozzle are reported, and the processes responsible for nonequilibrium ionization in a laser-active medium are discussed. 相似文献