Analysis of linear alkylbenzene sulfonate homologues in environmental water samples by mixed admicelle-based extraction and liquid chromatography/mass spectrometry

Hemimicelles and admicelles of cetyltrimethylammonium bromide (CTAB) and cetylpyridinium chloride (CPC), adsorbed onto silica, were tested as sorbents for the solid phase extraction (SPE) of linear alkylbenzene sulfonate (LAS) homologues from environmental water samples. LASs were quantitatively retained on both surfactants due to high hydrophobic and ionic interactions, which led to the formation of analyte-extractant mixed aggregates. Parameters affecting the SPE of LASs were optimised. Recoveries of analytes from wastewater influent and effluent and river water samples ranged between 86 and 110%. Combination of SPE with liquid chromatography/mass spectrometry provided detection limits for the different LAS homologues of about 4 ng L(-1). The precision of the method, expressed as relative standard deviation, ranged from 5 to 9%. The method was applied to the analysis of LASs in wastewater and river samples using sample volumes between 10 and 25 mL. The LAS concentrations found ranged from 9 to 503 microg L(-1). No cleaning step was required to get accurate results.     

Diffraction aperture non-ideal behaviour of air coupled transducers array elements designed for NDT

Air coupled piezoelectric ultrasonic array transducers are a novel tool that could lead to interesting advances in the area of non-contact laminar material testing using Lamb wave's propagation techniques. A key issue on the development of such transducers is their efficient coupling to air media (impedance mismatch between the piezoelectric material and air is 90 dB or more). Adaptation layers are used in order to attain good matching and avoid possible serious signal degradation. However, the introduction of these matching layers modify the transducer surface behaviour and, consequently, radiation characteristics are altered, making the usual idealization criteria (of uniform surface movement) adopted for field simulation purposes inaccurate. In our system, we have a concave linear-array transducer of 64 elements (electrically coupled by pairs) working at 0.8 MHz made of PZ27 rectangular piezoceramics (15 mm x 0.3 mm) with two matching layers made of polyurethane and porous cellulose bonded on them. Experimental measurements of the acoustic aperture of single excited array elements have shown an increment on the geometrical dimensions of its active surface. A sub-millimeter vibrometer laser scan has revealed an extension of the aperture beyond the supposed physical single array element dimensions. Non-uniform symmetric apodized velocity surface vibration amplitude profile with a concave delay contour indicates the presumed existence of travelling wave phenomena over the surface of the outer array matching layer. Also, asymptotic propagation velocities around 2500 m/s and attenuation coefficient between 15 and 20 dB/mm has been determined for the travelling waves showing clear tendencies. Further comparisons between the experimental measurements of single array element field radiation diagram and simulated equivalent aperture counterpart reveal good agreement versus the ideal (uniform displaced) rectangular aperture. For this purpose an Impulse Response Method (IRM) has been used.     

Toward Tailor‐Made Biocide Materials Based on Poly(propylene)/Copper Nanoparticles

A set of poly(propylene) composites containing different amounts of copper nanoparticles (CNP) were prepared by the melt mixed method and their antimicrobial behavior was quantitatively studied. The time needed to reduce the bacteria to 50% dropped to half with only 1 v/v % of CNP, compared to the polymer without CNP. After 4 h, this composite killed more than 99.9% of the bacteria. The biocide kinetics can be controlled by the nanofiller content; composites with CNP concentrations higher than 10 v/v % eliminated 99% of the bacteria in less than 2 h. X‐ray photoelectron spectroscopy did not detect CNP at the surface, therefore the biocide behavior was attributed to copper in the bulk of the composite.

     

Mechanical, chemical and acoustic properties of new hybrid ceramic-polymer varnishes for musical instruments

Novel ceramic-polymer hybrid varnishes were designed to protect the wood surface of musical instruments. These hybrid coatings consist of chemically functionalized silica nanoparticles and synthetic solvent-based acrylic- and alkyd-polyurethanes. The nanoparticles were added to increase the abrasion resistance. An alkoxide was used to increase the number and reactivity of OH’s groups on the wood surface improving the adhesion with the coating through a chemical link between them. The properties of the synthetic coatings were compared with those of a traditional varnish (based on alcohol and natural resins) to obtain a better performance. Two types of woods were used: maple and spruce. The samples were characterized by UV-Vis, mechanical and abrasion tests, water’s absorption, acoustic properties, chemical resistance and SEM.     

Ultrasonic monitoring of malolactic fermentation in red wines

The progress of malolactic fermentation in red wines has been monitored by using ultrasonic techniques. The evolution of ultrasonic velocity of a tone burst 1 MHz longitudinal wave was measured, analyzed and compared to those parameters of oenological interest obtained simultaneously by analytical methods. Semi-industrial tanks were used during measurements pretending to be in real industrial conditions. Results showed that the ultrasonic velocity mainly changes as a result of the conversion by lactic acid bacteria of malic acid into lactic acid and CO₂. Overall, the present study has demonstrated the potential of the ultrasonic technique in monitoring the malolactic fermentation process.     

Major factors involved in the inhibition of ultrasound-induced free radical production and cell killing by pre-sonication incubation or by high cell density

To identify the factors involved in the inhibition of ultrasound (US)-induced free radical production and cell killing by pre-sonication incubation or by high cell density, we used different densities of U937 cells, and with (up to 2 h) or without pre-sonication incubations, the cell suspensions were exposed to 1 MHz US (10% duty factor at 100 Hz pulse rate; intensities 0.1-0.5 W/cm(2) for 1 min). The intensity 0.3 W/cm(2) was used for cell killing experiments and 0.5 W/cm(2) for free radical experiments. Free radical production was determined by electron paramagnetic resonance (EPR)-spin trapping with DMPO while cell killing was determined by assays for lysis, loss of cell viability, apoptosis and necrosis. The results show that at higher cell densities, CO(2) in the medium rapidly increased, with shorter pre-sonication incubation required to attain complete inhibition of both free radical production and cell killing. Cell killing at 0.3 W/cm(2) and free radical production at 0.5 W/cm(2) were both inhibited at 10 million cells/ml without incubation, and at 2 million cells/ml incubated for 2 h before sonication. Level of CO(2) alone could not account for the inhibition; consumption of gases in the medium is also considered in the inhibitory effect of pre-sonication, while suppression of cavitational activities due to the "viscosity effect" is considered a more important factor in the inhibition by high cell density.     

On ≤k-Edges, Crossings, and Halving Lines of Geometric Drawings of K n

Let P be a set of points in general position in the plane. Join all pairs of points in P with straight line segments. The number of segment-crossings in such a drawing, denoted by $\operatorname {cr}(P)$ , is the rectilinear crossing number of P. A halving line of P is a line passing through two points of P that divides the rest of the points of P in (almost) half. The number of halving lines of P is denoted by h(P). Similarly, a k-edge, 0??k??n/2?1, is a line passing through two points of P and leaving exactly k points of P on one side. The number of ??k-edges of P is denoted by E _??k (P). Let $\overline {\mathrm {cr}}(n)$ , h(n), and E _??k (n) denote the minimum of $\operatorname {cr}(P)$ , the maximum of h(P), and the minimum of E _??k (P), respectively, over all sets P of n points in general position in the plane. We show that the previously best known lower bound on E _??k (n) is tight for k<?(4n?2)/9? and improve it for all k???(4n?2)/9?. This in turn improves the lower bound on $\overline {\mathrm {cr}}(n)$ from $0.37968\binom{n}{4}+\varTheta (n^{3})$ to $\frac{277}{729}\binom{n}{4}+\varTheta (n^{3})\geq 0.37997\binom{n}{4}+\varTheta (n^{3})$ . We also give the exact values of $\overline {\mathrm {cr}}(n)$ and h(n) for all n??27. Exact values were known only for n??18 and odd n??21 for the crossing number, and for n??14 and odd n??21 for halving lines.     

Effects of the induced birefringence in photorefractive crystals on speckle optical vortices

In this work, we show that it is possible to change the properties of an optical vortex formed in a speckle pattern by the control of an external electric field applied to a sillenite-type photorefractive material in a non-holographic configuration. To show it, a scheme that allows the recovering of both, the polarization state and the phase distribution of an optical field was implemented. Changes in the polarization state of the light in the neighborhood of the vortex were observed with the application of an external electric field. Likewise, changes in the phase structure around the vortex and displacements of the vortices themselves were measured. These displacements have a fairly linear dependence on the applied field to the photorefractive crystal. Experimental results are qualitatively explained with the theoretical treatment of non-holographic recording in photorefractive crystals.     

Amperometric biosensor for oxalate determination in urine using sequential injection analysis

An amperometric flow biosensor for oxalate determination in urine samples after enzymatic reaction with oxalate oxidase immobilized on a modified magnetic solid is described. The solid was magnetically retained on the electrode surface of an electrode modified with Fe (III)-tris-(2-thiopyridone) borate placed into a sequential injection system preceding the amperometric detector. The variables involved in the system such as flow rate, aspired volumes (modified magnetic suspension and sample) and reaction coil length were evaluated using a Taguchi parameter design. Under optimal conditions, the calibration curve of oxalate was linear between 3.0-50.0 mg·L^-1, with a limit of detection of 1.0 mg·L^-1. The repeatability for a 30.0 mg·L^-1 oxalate solution was 0.7%. The method was validated by comparing the obtained results to those provided by the spectrophotometric method; no significant differences were observed.     

Algebras of Convolution Type Operators with Piecewise Slowly Oscillating Data. I: Local and Structural Study

Let ${\mathcal{B}_{p,w}}$ be the Banach algebra of all bounded linear operators acting on the weighted Lebesgue space ${L^{p}(\mathbb{R}, w)}$ , where ${p \in (1, \infty)}$ and w is a Muckenhoupt weight. We study the Banach subalgebra ${\mathfrak{A}_{p,w}}$ of ${\mathcal{B}_{p,w}}$ generated by all multiplication operators aI ( ${a \in PSO^{\diamond}}$ ) and all convolution operators W ⁰(b) ( ${b \in PSO_{p,w}^{\diamond}}$ ), where ${PSO^{\diamond} \subset L^{\infty}(\mathbb{R})}$ and ${PSO_{p,w}^{\diamond} \subset M_{p,w}}$ are algebras of piecewise slowly oscillating functions that admit piecewise slowly oscillating discontinuities at arbitrary points of ${\mathbb{R} \cup \{\infty\}}$ , and M _p,w is the Banach algebra of Fourier multipliers on ${L^{p}(\mathbb{R}, w)}$ . Under some conditions on the Muckenhoupt weight w, we construct a Fredholm symbol calculus for the Banach algebra ${\mathfrak{A}_{p,w}}$ and establish a Fredholm criterion for the operators ${A \in \mathfrak{A}_{p,w}}$ in terms of their Fredholm symbols. To study the Banach algebra ${\mathfrak{A}_{p,w}}$ we apply the theory of Mellin pseudodifferential operators, the Allan–Douglas local principle, the two idempotents theorem and the method of limit operators. The paper is divided in two parts. The first part deals with the local study of ${\mathfrak{A}_{p,w}}$ and necessary tools for studying local algebras.