The additive multiboxes

We introduce the new notion of additive “multibox” for linear logic proof-nets. Thanks to this notion, we define a cut-elimination procedure which associates with every proof-net of multiplicative and additive linear logic a unique cut-free one.     

Densely-packed self-assembled monolayers on gold surfaces from a conformationally constrained helical hexapeptide

A novel hexapeptide was functionalized at the N-terminus by a lipoyl group for binding to gold substrates. Owing to the high content of α-aminoisobutyric acid residues, the peptide adopts a rigid helical conformation despite the shortness of its main chain. Binding of the peptide to gold was investigated by quartz crystal microbalance, cyclic voltammetry, X-ray photoelectron spectroscopy, and scanning tunneling microscopy under ultra-high vacuum conditions. Scanning tunneling microscopy experiments revealed that the peculiar self-assembly properties of this short helical peptide determine the complex morphology of the monolayer, showing ‘stripes’, i.e. peptide aggregates horizontally layered on the gold surface, and ‘holes’, i.e. Au vacancy islands coated by the peptide monolayer.     

A symmetric family of Yang-Mills fields

We examine a family of finite energySO(3) Yang-Mills connections overS ⁴, indexed by two real parameters. This family includes both smooth connections (when both parameters are odd integers), and connections with a holonomy singularity around 1 or 2 copies ofRP ². These singular YM connections interpolate between the smooth solutions. Depending on the parameters, the curvature may be self-dual, anti-self-dual, or neither. For the (anti)self-dual connections, we compute the formal dimension of the moduli space. For the non-self-dual connections we examine the second variation of the Yang-Mills functional, and count the negative and zero eigenvalues. Each component of the non-self-dual moduli space appears to consist only of conformal copies of a single solution.This work was partially supported by an NSF Mathematical Sciences Postdoctoral Fellowship     

Unexpected high ordering of a [60]Fullerene nitroxide in the nematic phase of 4-4'-azoxyanisole

A nitroxide [60]fullerene adduct containing a pyrrolidine-1-oxyl group has been synthesized. Its orientational order in the nematic phase of the liquid crystal solvent 4,4'-azoxyanisole (PAA) has been measured from the variation of the EPR spectral parameters on passing from the isotropic to the nematic phase. Highly resolved EPR lines allow for precise evaluation of the shifts of the g , a N and a H values. Since the g and the hyperfine tensors are known, the order matrix could be obtained. This is compared with the one calculated with a theoretical model based on short range solute-solvent interactions, which predicts a considerable degree of orientation of the molecular axes, despite the almost spherical shape of the molecule. The agreement with experimental findings is quite good and it is further improved if a bent structure of the pyrrolidine ring is taken into account.     

J/psi production in Indium-Indium collisions at 158 GeV/nucleon

The NA60 experiment studies muon pair production at the CERN Super Proton Synchrotron. In this Letter we report on a precision measurement of J/psi in In-In collisions. We have studied the J/psi centrality distribution, and we have compared it with the one expected if absorption in cold nuclear matter were the only active suppression mechanism. For collisions involving more than approximately 80 participant nucleons, we find that an extra suppression is present. This result is in qualitative agreement with previous Pb-Pb measurements by the NA50 experiment, but no theoretical explanation is presently able to coherently describe both results.     

Variable Order and Distributed Order Fractional Operators

Many physical processes appear to exhibit fractional order behavior thatmay vary with time or space. The continuum of order in the fractionalcalculus allows the order of the fractional operator to be considered asa variable. This paper develops the concept of variable and distributedorder fractional operators. Definitions based on the Riemann–Liouvilledefinition are introduced and the behavior of the new operators isstudied. Several time domain definitions that assign different argumentsto the order q in the Riemann–Liouville definition are introduced. Foreach of these definitions various characteristics are determined. Theseinclude: time invariance of the operator, operator initialization,physical realization, linearity, operational transforms, and memorycharacteristics of the defining kernels.A measure (m ₂) for memory retentiveness of the order history isintroduced. A generalized linear argument for the order q allows theconcept of `tailored' variable order fractional operators whose m ₂ memory may be chosen for a particular application. Memory retentiveness (m ₂) andorder dynamic behavior are investigated and applications are shown.The concept of distributed order operators where the order of thetime based operator depends on an additional independent (spatial)variable is also forwarded. Several definitions and their Laplacetransforms are developed, analysis methods with these operators aredemonstrated, and examples shown. Finally operators of multivariable anddistributed order are defined and their various applications areoutlined.     

The Vectorial Parameterization of Rotation

The parameterization of rotation is the subject of continuous research and development in many theoretical and applied fields of mechanics, such as rigid body, structural, and multibody dynamics, robotics, spacecraft attitude dynamics, navigation, image processing, and so on. This paper introduces the vectorial parameterization of rotation, a class of parameterization techniques encompassing many formulations independently developed to date for the analysis of rotational motion. The exponential map of rotation, the Rodrigues, Cayley, Gibbs, Wiener, and Milenkovic parameterization all are special cases of the vectorial parameterization. This generalization parameterization sheds additional light on the fundamental properties of these techniques, pointing out the similarities in their formal structure and showing their inter-relationships. Although presented in a compact manner, all of the formulae needed for a complete implementation of the vectorial parameterization of rotation are included in this paper.     

Optical Activity in the Near‐IR Region: The λ=980 nm Multiplet of Chiral Yb3+ Complexes

We used a very simplified electrostatic model based on charge and polarizability of atoms and groups on an organic ligand around a lanthanide ion to predict the near‐infrared electronic circular dichroism (NIR ECD) spectra of Yb³⁺ (a monoelectronic ion). We tuned our method by using two widely different complexes. The first was the heterobimetallic species CsYb(hfbc)₄ [hfbc=(?)‐3‐heptafluorobutyrylcamphorate], in which the ligand is a diketonate and, as such, is endowed with a chromophore with strong UV absorption (π–π^*). Its oxygen atoms define a square antiprism, which provides a symmetric coordination polyhedron. The second system was Yb DOTMA [DOTMA=(1R,4R,7R,10R)‐α,α′,α′′,α′′′‐tetramethyl‐1,4,7,10‐tetraazacyclododecane‐1,4,7,10‐tetraacetic acid], a chiral Yb analogue of Gd DOTA (DOTA=1,4,7,10‐tetraazacyclododecane‐1,4,7,10‐tetraacetic acid), in which the ligand lacks relevant electronic transitions and provides a dissymmetric cage. The relative weights of dynamic (ligand polarization) and static contributions to Yb NIR ECD were evaluated, and the spectra appear to have been well predicted by theory through the introduction of a heuristic weight factor. To validate the approach and to confirm the value of the weight factor, we applied it to two other compounds, namely, Na₃Yb(BINOLate)₃ and Yb(BINOLAM)₃ [BINOLate=2,2′‐dihydroxy‐1,1′‐binaphthyl; BINOLAM=3,3′‐bis(diethylaminomethyl)‐1‐1′‐bi‐2‐naphthol].