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61.
The intermittent route to spatiotemporal complexity is analyzed in simple models which display a subcritical bifurcation without hysteresis. A new type of spatiotemporal complex behavior is found, induced by fronts which "clean" the perturbations around an unstable state. The mechanism which generates these "retracting fronts" through nonlinear dispersion is analyzed in the frame of the complex Ginzburg-Landau equation. For sufficiently strong nonlinear dispersion the effects also occur for a supercritical bifurcation. 相似文献
62.
Field-induced reentrant novel phase and a ferroelectric-magnetic order coupling in HoMnO3 总被引:1,自引:0,他引:1
A reentrant novel phase is observed in the hexagonal ferroelectric HoMnO3 in the presence of magnetic fields in the temperature range defined by a plateau of the dielectric constant anomaly. The plateau evolves with fields from a narrow dielectric peak at the Mn-spin rotation transition at 32.8 K in zero field. The anomaly appears both as a function of temperature and as a function of magnetic field without detectable hysteresis. This is attributed to the indirect coupling between the ferroelectric (FE) and antiferromagnetic (AFM) orders, arising from an FE-AFM domain wall effect. 相似文献
63.
Park B Lorenz CD Chandross M Stevens MJ Grest GS Borodin OA 《Langmuir : the ACS journal of surfaces and colloids》2004,20(23):10007-10014
The frictional dynamics of fluorine-terminated alkanethiol (S(CH2)8CF3) self-assembled monolayers (SAMs) on gold are studied using molecular dynamics simulations. The simulations treat the interactions between two SAMs on flat surfaces. The structure and frictional behavior are investigated as a function of applied pressure (200 MPa to 1 GPa) for a shear velocity of 2 m/s and compared to methyl-terminated alkanethiol SAMs. The maximum adhesive pressure between the SAMs is 220 MPa for both end groups. In agreement with experiments on the molecular scale, the shear stress and the coefficient of friction for CF3-terminated alkanethiols are larger than for CH3-terminated alkanethiols. The main source for the difference is primarily the tighter packing of the fluorinated terminal group resulting in a higher degree of order. The molecular scale coefficient of friction is correlated with the degree of order among all the systems. 相似文献
64.
Using neon and its dimer as a specific example, it is shown that excited Auger decay channels that are electronically stable in the isolated monomer can relax in a cluster by electron emission. The decay mechanism, leading to the formation of a tricationic cluster, is based on an efficient energy-transfer process from the excited, dicationic monomer to a neighbor. The decay is ultrafast and expected to be relevant to numerous physical phenomena involving core holes in clusters and other forms of spatially extended atomic and molecular matter. 相似文献
65.
Pathak Madhvesh Bohra Rakesh Mehrotra Ram C. Lorenz Ingo-Peter Piotrowski Holger 《Transition Metal Chemistry》2003,28(2):187-192
Reactions of cis-dialkoxy-bis(acetylacetonato)titanium(IV), [(acac)2Ti(OR)2] (R = Et, Pr
i
) with alkoxyalkanols (ROCH2CH2OH) (R = Me, Et, n-Bu) in 1:1 and 1:2 molar ratios in refluxing benzene under anhydrous conditions yield [(acac)2Ti(OR)2–n
(OCH2CH2OR)
n
] (n = 1 or 2) complexes, which were purified by distillation under reduced pressure. On the basis of i.r. and n.m.r. (1H- and 13C-) spectral studies, a cis-octahedral environment around TiIV is proposed. On keeping the distilled dark brown-red viscous liquid [(acac)2Ti(OEt)(OCH2CH2OBu)] for 2 weeks, orange yellow crystals of [(acac)2TiO]2 were obtained. A single crystal X-ray diffraction study suggests the product is a new modification of [(acac)2TiO]2. 相似文献
66.
Steady, nonpropagating, fronts in reaction diffusion systems usually exist only for special sets of control parameters. When varying one control parameter, the front velocity may become zero only at isolated values (where the Maxwell condition is satisfied, for potential systems). The experimental observation of fronts with a zero velocity over a finite interval of parameters, e.g., in catalytic experiments [Barelko et al., Chem. Eng. Sci., 33, 805 (1978)], therefore, seems paradoxical. We show that the velocity dependence on the control parameter may be such that velocity is very small over a finite interval, and much larger outside. This happens in a class of reaction diffusion systems with two components, with the extra assumptions that (i) the two diffusion coefficients are very different, and that (ii) the slowly diffusing variables has two stable states over a control parameter range. The ratio of the two velocity scales vanishes when the smallest diffusion coefficient goes to zero. A complete study of the effect is carried out in a model of catalytic reaction. (c) 2000 American Institute of Physics. 相似文献
67.
H. von Wenckstern M. Brandt H. Schmidt G. Biehne R. Pickenhain H. Hochmuth M. Lorenz M. Grundmann 《Applied Physics A: Materials Science & Processing》2007,88(1):135-139
We have investigated donor-like defects in ZnO substrate material grown by three different methods, and in epitaxial ZnO thin
films grown on sapphire by pulsed laser deposition. Temperature dependent Hall effect measurements yield information about
dominant donors. The thermal activation energies lie in a wide range from about 20 meV to about 370 meV. Deep level transient
spectroscopy is used to obtain parameters of deep donor-like defects. For that, a high-speed diode contact configuration was
laid out for the epitaxial thin films in order to determine the defect parameters with high precision. The identified levels
are E1, E3 and E4, though the level E4 is observed only in single crystals grown by seeded chemical vapor transport.
PACS 72.10.Fk; 72.80.Ey; 73.50.-h 相似文献
68.
A radial inhomogeneous magnetic field produced by counter-propagating currents in anti-Helmholtz configuration coils has been
superimposed to a Penning trap. The confinement properties of electrons in such a trap have been studied experimentally. Without
the radial B-field we find a number of operating conditions where instabilities occur, arising from higher order contributions
to the quadrupolar trapping field. When we apply the radial field the trap properties remain essentially unchanged until the
strength of this field at the boundary of the electron cloud is of the same order as the homogeneous Penning field. Then a
sudden breakdown in the confinement appears. The experiments have been performed in low magnetic fields. The equations of
motions of the trapped particles can be cast in a dimensionless form and our results can be considered as independent of the
field strength.
Contribution was presented at the TCP06, Vancouver Island, 2006. 相似文献
69.
R. Schmidt-Grund B. Rheinlnder C. Czekalla G. Benndorf H. Hochmut A. Rahm M. Lorenz M. Grundmann 《Superlattices and Microstructures》2007,41(5-6):360
In this paper we report on planar and microscopic cylindrical resonators with ZnO as the cavity and active medium surrounded with ZrO2/MgO Bragg reflectors. We have observed resonator behaviour of these structures and, for the planar resonators, exciton–polariton coupling with a mode splitting of about 50 meV. 相似文献
70.