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Loo YL Hiszpanski AM Kim B Wei S Chiu CY Steigerwald ML Nuckolls C 《Organic letters》2010,12(21):4840-4843
Fluorinated, contorted hexabenzocoronenes (HBCs) have been synthesized in a facile manner via Suzuki-Miyaura coupling of fluorinated phenyl boronic acids followed by photocyclization and Scholl cyclization. In addition to the molecular conformation observed in previous HBC derivatives, close-contact fluorine-fluorine intramolecular interactions result in a metastable conformation not previously observed. Heating the metastable HBCs above 100 °C irreversibly converts them to the stable conformation, suggesting that the metastable conformation arises from a kinetically arrested state during cyclization. 相似文献
67.
Zhishuang Yao Loo Hay Lee Wikrom Jaruphongsa Vicky Tan Chen Fei Hui 《European Journal of Operational Research》2010
We consider a joint facility location–allocation and inventory problem that incorporates multiple sources of warehouses. The problem is motivated by a real situation faced by a multinational applied chemistry company. In this problem, multiple products are produced in several plants. Warehouse can be replenished by several plants together because of capabilities and capacities of plants. Each customer in this problem has stochastic demand and certain amount of safety stock must be maintained in warehouses so as to achieve certain customer service level. The problem is to determine number and locations of warehouses, allocation of customers demand and inventory levels of warehouses. The objective is to minimize the expected total cost with the satisfaction of desired demand weighted average customer lead time and desired cycle service level. The problem is formulated as a mixed integer nonlinear programming model. Utilizing approximation and transformation techniques, we develop an iterative heuristic method for the problem. An experiment study shows that the proposed procedure performs well in comparison with a lower bound. 相似文献
68.
An integrated digital microfluidic chip for multiplexed proteomic sample preparation and analysis by MALDI-MS 总被引:2,自引:0,他引:2
To realize multiplexed sample preparation on a digital microfluidic chip for high-throughput Matrix Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS), several fluidic functions need to be integrated. These include the generation of multiple droplets from a reservoir and parallel in-line sample purification. In this paper, we develop two critical new functions in handling protein solutions and standard proteomic reagents with electrowetting-on-dielectric (EWOD) actuation, leading to an integrated chip for multiplexed sample preparation for MALDI-MS. The first is a voltage sequence designed to generate a series of droplets from each of the three reservoirs--proteomic sample, rinsing fluid, and MALDI reagents. It is the first time that proteomic reagents have been dispensed using EWOD in an air (as opposed to oil) environment. The second is a box-in-box electrode pattern developed to allow droplet passing over dried sample spots, making the process of in-line sample purification robust for parallel processing. As a result, parallel processing of multiple sample droplets is demonstrated on the integrated EWOD-MALDI-MS chip, an important step towards high-throughput MALDI-MS. The MS results, collected directly from the integrated devices, are of good quality, suggesting that the tedious process of sample preparation can be automated on-chip for MALDI-MS applications as well as other high-throughput proteomics applications. 相似文献
69.
Multi-objective simulation-based evolutionary algorithm for an aircraft spare parts allocation problem 总被引:1,自引:0,他引:1
Simulation optimization has received considerable attention from both simulation researchers and practitioners. In this study, we develop a solution framework which integrates multi-objective evolutionary algorithm (MOEA) with multi-objective computing budget allocation (MOCBA) method for the multi-objective simulation optimization problem. We apply it on a multi-objective aircraft spare parts allocation problem to find a set of non-dominated solutions. The problem has three features: huge search space, multi-objective, and high variability. To address these difficulties, the solution framework employs simulation to estimate the performance, MOEA to search for the more promising designs, and MOCBA algorithm to identify the non-dominated designs and efficiently allocate the simulation budget. Some computational experiments are carried out to test the effectiveness and performance of the proposed solution framework. 相似文献
70.
Four types of polyhedral oligosilsesquioxane (POSS)–octaanion, octaammonium, octanitrophenyl, and octaaminophenyl–were incorporated into chitosan (CS) to fabricate inorganic–organic hybrid membranes. The hybrid membranes were employed for the pervaporation dehydration of ethanol aqueous solutions. The performance of the hybrid membranes was found to be influenced by the type and loading amount of POSS. In comparison with the neat CS membranes which showed a separation factor of 65.2 for 10 wt % water in the feed at 303 K, the hybrid membranes containing 5 wt % of octaanion and octaaminophenyl POSS showed high separation factors of 305.6 and 373.3, respectively. The effects of the operating conditions such as the feed composition and temperature on the pervaporation performance of the membranes were investigated. Activation energies for permeation in the membranes were estimated from Arrhenius relationship. The activation energies for ethanol permeation in the hybrid membranes were much higher than that in the CS membrane, which may account for the large enhancements in the selectivity of the hybrid membranes. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2010 相似文献