排序方式: 共有55条查询结果,搜索用时 171 毫秒
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Qiaoli Lin Ping Shen Longlong Yang Feng Qiu Qichuan Jiang 《Surface and interface analysis : SIA》2011,43(10):1360-1364
The wetting of polycrystalline B4C by a molten Cu‐1 at.% Cr alloy was investigated at 1373 K using a modified sessile drop method. The triple line warped after the contact angle reached a certain degree. The mechanism for this unusual phenomenon was presumably ascribed to the large disparity in the wettability for the liquid on the CrB2 reaction layer and the precipitated graphite phase, as well as to their formation kinetics, rather than to the capillary flow driven by the surface tension gradient, as observed in the Cu/Si system. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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以Ni/CMK-3为催化剂,采用BET比表面积、X射线衍射和氢气程序升温还原对催化剂进行了表征.考察了不同Ni负载量、反应温度、反应初始压力及反应时间条件下,甲醇水相重整制氢与邻甲酚原位加氢的耦合反应.结果表明,当Ni负载量为20%、反应温度为230℃、反应前冷压为0.1 MPa、水-甲醇-模型化合物摩尔比为50∶15∶1及反应9 h时,邻甲酚转化率最高为45.4%.分别对比了甲醇、甲酸、甘油和异丙醇作为供氢溶剂对原位加氢反应的影响,其中以甲酸为供氢溶剂时,邻甲酚的转化率最高达82.2%.对比了甲酚3种同分异构体原位加氢的效果,发现邻甲酚和间甲酚的反应效果相差不大,而对甲酚的转化率则远低于邻甲酚和间甲酚.对20%Ni/CMK-3在原位加氢实验中的使用寿命进行了考察. 相似文献
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Although supramolecular one‐dimensional (1D) and two‐dimensional (2D) structures with various unique properties have been extensively studied, the reversible switching between tubules and sheets via lateral association remains challenging. Here, we report the unique structures of a supramolecular tubular bamboo culm in which the hollow‐tubular interior is separated, at intervals, by nodes per 1.3 nm. Interestingly, the discrete tubules are able to hierarchically assemble into a flat sheet in response to an aromatic guest. The addition of trans‐azobenzene, as a guest, enables the tubules to form a hierarchical sheet assembly via the lateral interaction. The hierarchical sheet structures are disassembled into their constituent tubules upon UV irradiation due to trans‐cis isomerization. The recovery from cis‐azobenzene to trans‐form induces repeatedly the hierarchical sheet assembly, indicative of a reversible switching behavior between tubules and sheets triggered by an external stimulus. 相似文献
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激光尘埃粒子计数器微型光学传感器的研究 总被引:9,自引:1,他引:8
研制成功便携式激光尘埃粒子计数器的核心部件———微型光学传感器。该传感器采用直角散射光收集形式,以高功率半导体激光器作为光源,同时采用高性能的PIN型光电二极管作为光电探测器。散射光收集系统为单一大数值孔径的球面反射镜,其对粒子散射光的收集角范围从20°到160°。粒子散射光信号是脉冲信号,其频谱成份主要在高频段,所以在PIN型光电二极管后用一个带通式前置放大器来消除外界的低频噪声,根据米氏散射理论计算了该光学传感器的光散射响应特性,并用聚苯乙烯标准粒子实测了该光学传感器的性能。结果表明,该系统具有高的信噪比、计数效率和尺寸分辨本领。 相似文献
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以钛酸四丁酯为前驱体,采用水热法合成二氧化钛纳米片(TiO2),通过3-氨基丙基-三甲氧基硅烷(APTMS)分子对TiO2表面进行氨基修饰后,将其与Vulcan XC-72活性炭复合作为载体,吸附钯前驱体后,再进行液相还原制得Pd/TiO2/C-APTMS复合催化剂.用透射电子显微镜(TEM)、X射线能量色散谱(EDS)、电感耦合等离子体原子发射光谱(ICP-AES)、X射线衍射谱(XRD)和X射线光电子能谱(XPS)表征了催化剂的形貌、组成和结构.电化学测试结果表明,与传统液相混合还原制备的Pd/TiO2/C复合催化剂和Pd/C相比,经氨基修饰后的Pd/TiO2/C-APTMS复合催化剂在碱性溶液中对乙醇氧化具有更高的电催化活性和稳定性. 相似文献
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Ni/HZSM-5催化剂的结构及其催化山梨醇水相加氢合成烷烃性能 总被引:1,自引:0,他引:1
采用浸渍法制备了Ni/HZSM-5双功能催化剂,考察了焙烧温度对催化剂结构及其催化山梨醇水相加氢合成C5~C6烷烃性能的影响.结果表明,在金属中心和酸性载体的协同作用下,通过山梨醇中C-O键加氢和异构化高选择性合成了C5~C6烷烃.经500°C焙烧的Ni/HZSM-5催化剂上山梨醇水相加氢的活性最高,山梨醇转化率为62.0%,戊烷和己烷的总选择性为76.4%,其中异己烷选择性达45.4%.对催化剂进行N2物理吸附、X射线衍射、NH3程序升温脱附和H2程序升温还原等表征后发现,经500°C焙烧催化剂的有效比表面积和孔体积均明显增大,HZSM-5负载的硝酸镍分解成较小晶粒的NiO,表面酸量适中,且Ni物种与载体相互作用较强,较易被H2还原,Ni还原度达100%.这是其催化活性最高的原因. 相似文献
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Yuanyuan Li Yunxiang Lei Lichao Dong Longlong Zhang Assoc. Prof. Junge Zhi Assoc. Prof. Jianbing Shi Prof. Bin Tong Prof. Yuping Dong 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(2):573-581
Five organic luminophores, 1,2,5-triphenylpyrrole (TPP) derivatives 3 a – e bearing electron-withdrawing or electron-donating groups, have been synthesized by Pd-catalyzed Suzuki coupling of 1-phenyl-2,5-di(4′-bromophenyl)pyrrole and para-substituted phenylboronic acid derivatives. They possess good thermal stabilities with high decomposition temperatures above 310 °C. Investigation of the photophysical properties of the luminogens 3 a – e indicated that they exhibited dual intense photoluminescence in both solution and the solid state due to their twisted conformations, and their fluorescence quantum yields (ΦF) were determined as 68.7–94.9 % in THF solution and 19.1–52.0 % in solid powder form. Compounds 3 a – c bearing electron-accepting groups exhibited remarkable solvatochromism with large Stokes shifts, attributable to their D-π-A structure and intramolecular charge-transfer effect. In particular, 3 a , bearing aldehyde groups, displayed an obvious red-shift of the emission band from 445 to 564 nm with increasing solvent polarity. However, no obvious solvatochromic behavior was observed for compounds 3 d , e bearing electron-donating groups. The luminophore 3 a exhibited polymorphic luminescence properties and crystallization-induced emission enhancement. 相似文献
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