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201.
用磁控溅射方法制各纯Fe薄膜,并硫化合成FeS2. 采用同步辐射X射线近边吸收谱与X射线光电子能谱研究了薄膜的电子结构. 结果表明,合成的FeS2薄膜,在费米能级附近,有较强的Fe 3d态密度存在,同时,在价带谱中2—10eV处有强度较大的S 3p态密度存在;Fe的3d轨道在八面体配位场作用下分别为t2g和eg轨道,实验中由Fe的吸收谱计算得到两分裂能级之差为2.1eV;实验测得FeS2价带结构中导带宽度约为2.4eV,导带上方仍存在第二能隙,其宽度约为2.8eV.
关键词:
磁控溅射
二硫化铁
X射线吸收近边结构
电子结构 相似文献
202.
利用中子飞行时间技术和BC501A液体闪烁探测器的粒子分辨特性,测量了0°方向、20 MeV氘束轰击厚金属铍靶反应产生的中子源能谱,测量的中子能谱范围为0.7~25.0 MeV。在60°方向放置芪晶体闪烁探测器,由刻度好的BC501A液体闪烁探测器归一校正后,用于中子源强度监测。利用Be(d, n) 反应中子源,采用单粒子灵敏度标定方法,实验标定了0.75~15.75 MeV能量范围内的薄膜闪烁探测器中子能量响应曲线,实验结果与蒙特卡罗模拟计算结果在8%的不确定度范围内一致。 相似文献
203.
204.
Electronic band structure of a type-II ’W’ quantum well calculated by an eight-band k·p model 下载免费PDF全文
In this paper, we present an investigation of type-II 'W' quantum wells for the InAs/Ga1-xInxSb/AlSb family, where 'W' denotes the conduction profile of the material. We focus our attention on using the eight-band k?p model to calculate the band structures within the framework of finite element method. For the sake of clarity, the simulation in this paper is simplified and based on only one period---AlSb/InAs/Ga1-xInxSb/InAs/AlSb. The obtained numerical results include the energy levels and wavefunctions of carriers. We discuss the variations of the electronic properties by changing several important parameters, such as the thickness of either InAs or Ga1-xInxSb layer and the alloy composition in Ga1-xInxSb separately. In the last part, in order to compare the eight-band k?p model, we recalculate the conduction bands of the 'W' structure using the one-band k?p model and then discuss the difference between the two results, showing that conduction bands are strongly coupled with valence bands in the narrow band gap structure. The in-plane energy dispersions, which illustrate the suppression of the Auger recombination process, are also obtained. 相似文献
205.
Carbon onions produced by DC arc discharge method were deposited on highly oriented pyrolytic graphite (HOPG) surface and their adsorption and manipulation was studied using an atomic force microscopy (AFM). Well-dispersed adsorption of carbon onions on HOPG surface was obtained and aggregations of onions were not observed. The van der Waals interaction between the onion and HOPG surface and that between two onions, were calculated and discussed using Hamaker's theory. The manipulation of adsorbed onions on HOPG surface was realized using the AFM in both the raster mode and the vector mode. The controllability and precision of two manipulation modes were compared and the vector mode manipulation was found superior, and is a useful technique for the construction of nano-scale devices based on carbon onions. 相似文献
206.
Zhihang Long Yingqing Zhan Fei Li Xinyi Wan Yi He Chunyan Hou Hai Hu 《Journal of nanoparticle research》2017,19(9):318
In this work, highly activated graphene oxide/multiwalled carbon nanotube/Fe3O4 ternary nanocomposite adsorbent was prepared from a simple hydrothermal route by using ferrous sulfate as precursor. For this purpose, the graphene oxide/multiwalled carbon nanotube architectures were formed through the π-π attractions between them, followed by attaching Fe3O4 nanoparticles onto their surface. The structure and composition of as-prepared ternary nanocomposite were characterized by XRD, FTIR, XPS, SEM, TEM, Raman, TGA, and BET. It was found that the resultant porous graphene oxide/multiwalled carbon nanotube/Fe3O4 ternary nanocomposite with large surface area could effectively prevent the π-π stacking interactions between graphene oxide nanosheets and greatly improve sorption sites on the surfaces. Thus, owing to the unique ternary nanocomposite architecture and synergistic effect among various components, as-prepared ternary nanocomposite exhibited high separation efficiency when they were used to remove the Cu (II) and methylene blue from aqueous solutions. Furthermore, the adsorption isotherms of ternary nanocomposite structures for Cu (II) and methylene blue removal fitted the Langmuir isotherm model. This work demonstrated that the graphene oxide/multiwalled carbon nanotube/Fe3O4 ternary nanocomposite was promising as an efficient adsorbent for heavy metal ions and organic dye removal from wastewater in low concentration. 相似文献
207.
Stochastic resonance (SR) in an over-damped linear system subjected to an excitation of bias signal modulated noise with multiplicative and additive noises is investigated. We obtain the exact expressions of the first two moments and the signal-to-noise ratio (SNR) of the output by using linear-response theory. The SNR depends non-monotonically on the intensity and the correlation time of multiplicative noise, the correlation time of additive noise, the intensity of the cross noise between multiplicative and additive noise, as well as the external field frequency. The conventional SR, the SR in a broad sense and the bona fide SR are found in the system. The influences of the asymmetries of multiplicative and additive noise, the correlation rate of the cross noise, the intensity of additive noise, the amplitude of signal and the bias on the SNR are analyzed. Moreover, we pointed out that SR can be realized by tuning the system parameter with fixed noise, i.e., parameter-induced stochastic resonance (PSR) exists. 相似文献
208.
209.
Chao‐Zhi Zhang Ting Li Yang Yuan Cheng‐Yue Gu Meng‐Xiao Niu Hui Cao 《Journal of Physical Organic Chemistry》2017,30(5)
Substituents significantly affect optical properties of organic compounds. In this study, a series of organic compounds were synthesized. Ultraviolet‐visible and cyclic voltammetry spectra were determined. The relationships between the number of π electron in an aryl ring and the redshift (and molecular orbital energy levels) were studied. To investigate mechanisms of the bromine substituent effects, theoretical calculations were carried out. Ultraviolet‐visible spectra of bromine‐containing compounds exhibit obvious redshifts (0.04‐0.17 eV) of the maximal absorption wavelengths and enhanced absorbance (11%‐57%) compared with corresponding reference compounds. The lowest unoccupied and highest occupied molecular orbital energy levels of compounds containing bromine substituents are 0.05 to 0.60 and 0.02 to 0.40 eV lower than that of corresponding reference compounds. On the whole, the redshifts and the reduced molecular orbital energy levels caused by bromine substituent decrease with the increase in the number of π electron in an aryl ring. The effects would be attributed to strong p‐π conjugation between p electron in the bromine substituent and π electrons in aryl rings. Therefore, this paper suggests a useful way for tuning optical absorption and molecular orbital energy levels of aryl compounds. 相似文献
210.
Jingzhou Li Saifeng Zhang Hongxing Dong Yunfei Ma Bin Xu Jun Wang Zhiping Cai Zhanghai Chen Long Zhang 《Particle & Particle Systems Characterization》2017,34(1)
Ultrafast saturable absorption (SA) materials that are capable of blocking the optical absorption under strong excitation have extensive applications in photonic devices. This work presents core/shell colloidal quantum dots (CQDs) which have the quantized energy levels, excellent band gap tunability, and possess significant SA performance. When the band gap is close to the pump pulse energy, the CQDs show significant resonant SA response. At the same excitation conditions, the core/shell CQDs dispersions show better SA response than graphene dispersions, and comparable to the recently reported molybdenum disulfide. The carrier dynamics of the SA of the CQDs is analyzed systematically. The research has also found that the two‐photon absorption of the CQDs show nearly cubic power law of the band gap, while the SA performance keeps almost the same in the nonresonant regime. Further, superior passive Q‐switched laser behavior is observed using the CQDs as a saturable absorber. The results directly reveal the physical processes of this basic problem and broaden the applications of CQDs in photonic devices. 相似文献