Free-radical cross-linking of serum albumin molecules on the surface of magnetite nanoparticles in aqueous dispersion

A novel universal approach to cross-linking of protein macromolecules on the surface of magnetite nanoparticles has been developed. The approach is based on protein liability to free-radical modification, leading to the formation of intermolecular covalent cross-links. Free radicals are locally generated on the surface of nanoparticles. Stable coatings of serum albumin 3 nm thick are formed on the surface of magnetite nanoparticles. Using a set of physicochemical methods, it has been proven that stable coatings composed of protein macromolecules are formed around individual nanoparticles. The presence of reactive groups in the protein structure makes it possible to perform subsequent modification of the surface layers-in particular, to graft nonprotein drugs. The approach developed can be used to create superfine systems with desired surface properties for targeted delivery of drugs and biologically active substances.     

Effect of vibration stabilization of the process of postcritical deformation

Results of the experimental study of vibration stabilization of the process of postcritical deformation during the tensile testing of solid cylindrical specimens made of 20 and 40Cr structural steels under additional vibrations are presented. The vibrations are implemented using cyclic torsion of the specimens at a small amplitude and a frequency of 10–30 Hz.     

The effect of graphite nanoslabs on thermal oxidative destruction of polyethylene

The impact of graphite nanoslabs on thermal oxidation of polyethylene is studied via the methods of dynamic thermogravimetry and isothermal oxidation. Graphite nanoslabs are shown to exert an inhibiting effect on thermal oxidation of polyethylene, which leads to an increase in the induction period and in the oxygen-absorption rate. That there is an abnormal effect of the nanofiller content on the resistance to thermal oxidative destruction of composites, mainly for diffusion reasons, is established as well.     

Refined Stress Analysis in Applied Elasticity Problems Accounting for Gradient Effects

Doklady Physics - An extension of the approaches to gradient theories of deformable media is proposed. It consists in using the fundamental property of solutions of the elasticity gradient theory,...     

Chloroauric Acid Effect on Electrical Properties of SWCN Networks Synthesized with Anthracite Addition Using Aerosol CVD Method

Russian Physics Journal -     

Low threshold gain metal coated laser nanoresonators

We introduce a low refractive index layer between the metal and the gain medium in metal-coated laser resonators and demonstrate that it can significantly reduce the dissipation losses. Analysis of a gain medium waveguide shows that for a given waveguide radius, the low index layer has an optimal thickness for which the lasing threshold gain is minimal. The waveguide analysis is used for the design of a novel three-dimensional cylindrical resonator that is smaller than the vacuum wavelength in all three dimensions and exhibits a low enough threshold gain to lase at room temperature.