排序方式: 共有65条查询结果,搜索用时 15 毫秒
31.
We have investigated the use of headspace solid phase microextraction (HSSPME) as a sample concentration and preparation technique for the analysis of volatile and semivolatile pollutants in soil samples. Soil samples were suspended in solvent and the SPME fibre suspended in the headspace above the slurry. Finally, the fibre was desorbed in the Gas Chromatograph (GC) injection port and the analysis of the samples was carried out. Since the transfer of contaminants from the soil to the SPME fibre involves four separate phases (soil-solvent-headspace and fibre coating), parameters affecting the distribution of the analytes were investigated. Using a well-aged artificially spiked garden soil, different solvents (both organic and aqueous) were used to enhance the release of the contaminants from the solid matrix to the headspace. It was found that simple addition of water is adequate for the purpose of analysing the target volatile organic chemicals (VOCs) in soil. The addition of 1 ml of water to 1 g of soil yielded maximum response. Without water addition, the target VOCs were almost not released from the matrix and a poor response was observed. The effect of headspace volume on response as well as the addition of salt were also investigated. Comparison studies between conventional static headspace (HS) at high temperature (95 degrees C) and the new technology HSSPME at room temperature ( approximately 20 degrees C) were performed. The results obtained with both techniques were in good agreement. HSSPME precision and linearity were found to be better than automated headspace method and HSSPME also produced a significant enhancement in response. The detection and quantification limits for the target VOCs in soils were in the sub-ng g(-1) level. Finally, we tried to extend the applicability of the method to the analysis of semivolatiles. For these studies, two natural soils contaminated with diesel fuel and wood preservative, as well as a standard urban dust contaminated with polyaromatic hydrocarbons (PAHs) were tested. Discrimination in the response for the heaviest compounds studied was clearly observed, due to the poor partition in the headspace and to the slow kinetics of all the processes involved in HSSPME. 相似文献
32.
Maria Fernandez-Alvarez Marta Lores Eric Jover Carmen Garcia-Jares Josep M. Bayona Maria Llompart 《Journal of chromatography. A》2009,1216(51):8969-8978
Photo-solid-phase microextraction (photo-SPME) has been employed to study the photolysis of three common indoor air pollutants: coumarin, butylated hydroxytoluene, 2,6-diisopropylnaphthalene. Analytes were first extracted by SPME, and the fibre was subsequently exposed to an irradiation source (i.e. xenon arc or low-pressure mercury lamp) for the selected time (from 2 to 120 min). Analyses of the irradiated fibres were carried out by gas chromatography–mass spectrometry (GC–MS) detection. Photodecay kinetics exhibited a first-order behaviour and their rate constants and half-life times were estimated. Twenty-five photoproducts have been tentatively identified by means of their mass spectra. On the basis of the identified transformation compounds, some photodegradation pathways were proposed. The photoformation–photodecay kinetics of the identified by-products were also monitored by photo-SPME. To the best of our knowledge, photolytic routes for coumarin, butylated hydroxytoluene and 2,6-diisopropylnaphthalene have not been previously investigated. 相似文献
33.
Ruth Barro Jorge Regueiro María Llompart Carmen Garcia-Jares 《Journal of chromatography. A》2009,1216(3):540-566
This article reviews recent literature on the analysis of industrial contaminants in indoor air in the framework of the REACH project, which is mainly intended to improve protection of human health and the environment from the risks of more than 34 millions of chemical substances. Industrial pollutants that can be found in indoor air may be of very different types and origin, belonging to the volatile organic compounds (VOCs) and semivolatile organic compounds (SVOCs) categories. Several compounds have been classified into the priority organic pollutants (POPs) class such as polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins and furans (PCDD/PCDFs) and related polychlorinated compounds, and polycyclic aromatic hydrocarbons (PAHs). Many of these compounds are partially associated to the air gas phase, but also to the suspended particulate matter. Furthermore, settled dust can act as a concentrator for the less volatile pollutants and has become a matrix of great concern for indoors contamination. Main literature considered in this review are papers from the last 10 years reporting analytical developments and applications regarding VOCs, aldehydes and other carbonyls, PCBs, PCDDs, PCDFs, and PAHs in the indoor environment. Sample collection and pretreatment, analyte extraction, clean-up procedures, determination techniques, performance results, as well as compound concentrations in indoor samples, are summarized and discussed. Emergent contaminants and pesticides related to the industrial development that can be found in indoor air are reviewed in a second part in this volume. 相似文献
34.
Fernández-Alvarez M Lores M Llompart M García-Jares C Cela R 《Analytical and bioanalytical chemistry》2007,388(5-6):1235-1247
In the present study, solid-phase microextraction in photochemical studies was used to investigate UV light induced photodegradation
of five pyrethroids (empenthrin, transfluthrin, allethrin, phenothrin and cyphenothrin) and a synergist (piperonyl butoxide),
which are common ingredients of household insecticides. Gas chromatography coupled with mass spectrometry was used to separate
and tentatively identify the parent compounds and their corresponding photoproducts generated in the same polydimethylsiloxane
fibre. Kinetics curves were obtained and apparent first-order rate constants and half-lives were estimated. Twenty-six photoproducts
were tentatively identified and photodegradation pathways for the compounds investigated were proposed. It is a matter of
some concern that three of the photoproducts identified [(3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid, 3-phenoxybenzaldehyde
and (3-phenoxyphenyl)methanol] have been reported to be endocrine disruptors. There is no record of previous studies of cyphenothrin
and empenthrin photodegradation, and therefore the present study represents the first attempt to elucidate the photochemical
behaviour of these compounds.
Figure Photo-SPME for Pyrethroids 相似文献
35.
A solid-phase microextraction method (SPME) coupled to gas chromatography-mass spectrometry (GC-MS) has been developed for the determination of the six phthalate esters included in the US Environmental Protection Agency (EPA) Priority Pollutants list in water samples. These compounds are dimethyl phthalate (DMP), diethyl phthalate (DEP), di-n-butyl phthalate (DBP), butylbenzyl phthalate (BBP), di-2-ethylhexyl phthalate (DEHP) and di-n-octyl phthalate (DOP). Detailed discussion of the different parameters, which could affect the extraction process, is presented. Main factors have been studied and optimized by means of a multifactor categorical design. Different commercial fibers, polydimethylsiloxane (PDMS), polydimethylsiloxane-divinylbenzene (PDMS-DVB), polyacrylate (PA), Carboxen-polydimethylsiloxane (CAR-PDMS) and Carbowax-divinylbenzene (CW-DVB), have been investigated, as well as the extraction mode, exposing the fiber directly into the sample (DSPME) or into the headspace over the sample (HS-SPME), and different extraction temperatures. The use of this experimental design allowed for the evaluation of interactions between factors. Extraction kinetics has also been studied. The optimized microextraction method showed linear response and good precision for all target analytes. Detection limits were estimated considering the contamination problems associated to phthalate analysis. They were in the low pg mL(-1), excluding DEHP (100 pg mL(-1)). The applicability of the developed SPME method was demonstrated for several real water samples including mineral, river, industrial port and sewage water samples. All the target analytes were found in real samples. Levels of DEP and DEHP were over 1 ng mL(-1) in some of the samples. 相似文献
36.
Meruyert Sergazina Lua Vazquez Maria Llompart Thierry Dagnac 《Molecules (Basel, Switzerland)》2021,26(20)
Seventeen fungicides were determined in different matrices from vineyard areas, including vine leaves, soils, grapes and water, using gas chromatography coupled to tandem mass spectrometry (GC-MS/MS). For leaf analysis, ultrasound-assisted extraction (UAE) was performed evaluating different solvents. UAE was compared with other extraction techniques such as vortex extraction (VE) and matrix solid-phase dispersion (MSPD). The performance of the UAE method was demonstrated on vine leaf samples and on other types of samples such as tea leaves, underlining its general suitability for leaf crops. As regards other matrices, soils were analyzed by UAE and microwave-assisted extraction (MAE), grapes by UAE and waters by SPE using cork as the sorbent. The proposed method was applied to 17 grape leaf samples in which 14 of the target fungicides were detected at concentrations up to 1000 μg g−1. Furthermore, the diffusion and transport of fungicides was demonstrated not only in crops but also in environmental matrices. 相似文献
37.
Casas V Llompart M García-Jares C Cela R Dagnac T 《Journal of chromatography. A》2006,1124(1-2):148-156
A method based on solid-phase microextraction (SPME) and gas chromatography with micro-electron capture detection (GC-microECD) has been optimized for the analysis of pyrethroids in water samples. The influence of parameters such as temperature, fibre coating, salting-out effect and sampling mode on the extraction efficiency has been studied by means of a mix-level factorial design, which allowed the study of main effects as well as two factor interactions. Finally, a method based on direct SPME at 50 degrees C, using polydimethylsiloxane fibre is proposed. The method showed good linearity (R2>0.995) and repeatability (RSD相似文献
38.
A simple, fast, robust and reliable multicomponent analytical method applicable in control laboratories with a high throughput level has been developed to analyze commercial brands of perfumes. Contents of 52 cosmetic ingredients belonging to different chemical families can be determined in a single run. Instrumental linearity, precision of the method and recovery studies in real samples showed excellent results, so that quantification by external calibration can be effectively applied. Relevant limits of detection and quantification were obtained for all the targets considered, far below the legal requirements and amply adequate for its accurate analytical control.A survey of 70 commercial perfumes and colognes has been performed, in order to verify whether these products complied with the recent changes in European legislation: regarding the maxima allowed concentrations of the ingredients and/or ingredient labelling. All samples contained some of the target ingredients. Several samples do not comply with the regulations concerning the presence of phthalates. Musks data confirmed the trend about the replacement of nitromusks by polycyclic musks; as well as the noticeable introduction of macrocyclic musks in the perfumes composition. The prohibited musk moskene has been detected in one sample in an appreciable concentration. The average number of fragrance allergens is twelve per sample; their presence must be indicated in the list of ingredients when its concentration exceeds the 0.001%, but values higher than 1% have been found in some samples. Preservatives data show that parabens, although ubiquitous in other cosmetic products, are not widely used in perfumery. In contrast, the presence of BHT is indeed widespread. The degree of compliance with the European Regulation on the labelling has been evaluated in a subset of samples, and only about the 38% of the perfumes were properly labelled for the allergens tested. 相似文献
39.
Regueiro J Llompart M Garcia-Jares C Cela R 《Analytical and bioanalytical chemistry》2007,388(5-6):1095-1107
Gas chromatographic analysis of polybrominated diphenyl ethers (PBDEs) has been evaluated in an attempt to achieve better
control of the separation process, especially for highly substituted congeners. Use of a narrow-bore capillary column enabled
adequate determination of tetra, penta, hexa, hepta, octa, nona and decaBDE congeners in only one chromatographic run while
maintaining resolution power similar to that of conventional columns. A micro electron-capture detector (GC–μECD) was used.
Chromatographic conditions were optimized by multifactorial experimental design, with the objective of obtaining not only
high sensitivity but also good precision. In this way two different approaches to maximizing response and minimizing variability
were tested, and are fully discussed. These optimum chromatographic conditions were then used to determine PBDEs extracted
from domestic dust samples by microwave-assisted solvent extraction (MASE). Quantitative recovery (90–108%) was achieved for
all the PBDEs and method precision (RSD < 13%) was satisfactory. Accuracy was tested by use of the standard reference material
SRM 2585, and sub-ng g−1 limits of detection were obtained for all compounds except BDE-209 (1.44 ng g−1). Finally, several samples of house dust were analysed by use of the proposed method and all the target PBDEs were detected
in all the samples. BDE-209 was the predominant congener. Amounts varied from 58 to 1615 ng g−1 and the average contribution to the total PBDE burden of 52%. The main congeners of the octaBDE mixture (BDE-183, BDE-197,
BDE-207 and BDE-196) also made an important contribution (29%) to the total. These are the first data about the presence of
these compounds in European house-dust samples. Finally, the sum of the main congeners in the pentaBDE commercial mixture
(BDE-47, BDE-99, and BDE-100) contributed 14% to the total.
Figure Polybrominated diphenyl ethers in House Dust 相似文献
40.
Casas V Llompart M Garcia-Jares C Cela R Dagnac T 《Analytical and bioanalytical chemistry》2007,387(5):1841-1849
The aqueous instability of pyrethroids and other compounds usually found in commercial pesticide formulations has been demonstrated
in this work. Several types of sample treatment have been studied to avoid analyte losses during sample manipulation and storage.
Analysis was performed by SPME–GC–MS. Addition of sodium thiosulfate to tap water prevented pyrethroid degradation as a result
of oxidation by free chlorine. The amount added was optimized to minimize the effect of the salt on the analytical results.
Analysis of samples that had been stored at 4 °C for several days revealed loss of some of the pyrethroids in the first period
of storage. The effect of freezing the samples was studied and it was confirmed that samples could be stabilized for at least
one week by freezing. Finally, addition of a miscible organic solvent, for example acetone, led to improvement of the analytical
precision. The quality of the SPME–GC–MS method was studied. Linearity (R > 0.993), repeatability (RSD < 15%), and sensitivity
(detection limits between 0.9 and 35 pg mL−1) were good. When the procedure was applied to real samples including run off and waste water some of the target compounds
were identified and quantified.
相似文献