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941.
羟基磷灰石及其复合材料对重金属的吸附研究进展 总被引:1,自引:0,他引:1
羟基磷灰石具有特殊的晶体结构,对二价的重金属离子有很强的结合力,是一种可用于环境污染治理的新型功能性材料。它可有效地吸附去除水中的Pb2+,Cd2+,Cu2+,Zn2+,Co2+,Ni2+等重金属离子,但其粉体的结构却限制了它在水环境中的实际应用。随着纳米技术、复合材料技术的发展,在羟基磷灰石的基础上开发出的具有高效吸附性能或分离特性的新型材料在重金属吸附研究中显示了潜在的优势。本文综述了羟基磷灰石及其复合材料对水中重金属去除方面的研究进展,探讨了它对重金属吸附机理,并对羟基磷灰石进一步的研究提出了展望。 相似文献
942.
Kongkai Zhu Junyan Lu Zhongjie Liang Xiangqian Kong Fei Ye Lu Jin Heji Geng Yong Chen Mingyue Zheng Hualiang Jiang Jun-Qian Li Cheng Luo 《Journal of computer-aided molecular design》2013,27(3):247-256
New Delhi metallo-β-lactamase-1 (NDM-1) has emerged as a major global threat to human health for its rapid rate of dissemination and ability to make pathogenic microbes resistant to almost all known β-lactam antibiotics. In addition, effective NDM-1 inhibitors have not been identified to date. In spite of the plethora of structural and kinetic data available, the accurate molecular characteristics of and details on the enzymatic reaction of NDM-1 hydrolyzing β-lactam antibiotics remain incompletely understood. In this study, a combined computational approach including molecular docking, molecular dynamics simulations and quantum mechanics/molecular mechanics calculations was performed to characterize the catalytic mechanism of meropenem catalyzed by NDM-1. The quantum mechanics/molecular mechanics results indicate that the ionized D124 is beneficial to the cleavage of the C–N bond within the β-lactam ring. Meanwhile, it is energetically favorable to form an intermediate if no water molecule coordinates to Zn2. Moreover, according to the molecular dynamics results, the conserved residue K211 plays a pivotal role in substrate binding and catalysis, which is quite consistent with previous mutagenesis data. Our study provides detailed insights into the catalytic mechanism of NDM-1 hydrolyzing meropenem β-lactam antibiotics and offers clues for the discovery of new antibiotics against NDM-1 positive strains in clinical studies. 相似文献
943.
Shaogan Niu Lifen Zhang Jian Zhu Wei Zhang Zhenping Cheng Xiulin Zhu 《Journal of polymer science. Part A, Polymer chemistry》2013,51(5):1197-1204
Well‐defined polyacrylonitrile (PAN) of high viscosity‐average molecular weight (Mη = 405,100 g/mol) was successfully synthesized using reversible addition‐fragmentation chain transfer polymerization. The polymerization exhibits controlled characters: molecular weights of the resultant PANs increasing approximately linearly with monomer conversion and keeping narrow molecular weight distributions. The addition of 0.01 equiv (relative to monomer acrylonitrile) of Lewis acid AlCl3 in the polymerization system afforded the obtained PAN with an improved isotacticity (by 8%). In addition, the influence of molecular weights and molecular weight distributions of PANs on the morphology of the electrospun fibers was investigated. The results showed that, under the same conditions of electrospinning, average diameter (247–1094 nm) of fibers increased with molecular weights of PANs, and it was much easier to get “uniform” diameter fibers while using PANs with narrow molecular weight distributions as the precursor of electrospinning. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
944.
Yuan Zhu F. Y. Jiang Kexin Chen Feiyu Kang Z. K. Tang 《Journal of Sol-Gel Science and Technology》2013,66(1):180-186
Iron oxide/silica core–shell colloidal particles were prepared by basic reverse microemulsion (RM) method and two modified RM methods. By basic RM method, maximum particle size obtained was mere 40 nm. For building photonic crystals working in the visible range, the colloidal particles must be larger than 100 nm. Thus two modified RM methods were used. By alcohol modified RM method, short chain alcohols were used as co-surfactant. The particle size rose to near 100 nm, but the core–shell structure was comparatively poor. By emulsifier pair modified RM method, the particle size leapt to over 200 nm and a narrow growth window was found favorable to enhance the stability and rigidity of the surfactants layers. The core–shell mechanism was also discussed and a new four-step mechanism was proposed. 相似文献
945.
Xingzhong Guo Wenyan Li Hui Yang Kazuyoshi Kanamori Yang Zhu Kazuki Nakanishi 《Journal of Sol-Gel Science and Technology》2013,67(2):406-413
An in situ two-step processing using an initial acid catalysis step accompanied by an epoxide-mediated condensation step in the presence of ammonium chloride (NH4Cl) is reported, and macroporous cocontinuous methylsilsesquioxane (MSQ) monoliths have been successfully prepared by this processing. We explain the hydrolysis, gelation behavior and phase separation of MTMS(methyltrimethoxysilane)-MeOH(methanol)-HCl-PO(propylene oxide) system and the in situ effect of NH4Cl, and examine the macroporous morphology and pore structures of MSQ monoliths obtained under different conditions. Macroporous MSQ monolith under optimized conditions possesses a narrow macropore size distribution between 3 to 10 μm, surface area as high as 366 m2·g?1 and minimal shrinkage of only 1 %. 相似文献
946.
Dr. Freddi Philippart Marcus Arlt Steve Gotzen Dr. Stefanie‐Joana Tenne Dr. Marco Bocola Dr. Hsui‐Hui Chen Dr. Leilei Zhu Prof. Ulrich Schwaneberg Prof. Jun Okuda 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(41):13865-13871
A β‐barrel protein hybrid catalyst was prepared by covalently anchoring a Grubbs–Hoveyda type olefin metathesis catalyst at a single accessible cysteine amino acid in the barrel interior of a variant of β‐barrel transmembrane protein ferric hydroxamate uptake protein component A (FhuA). Activity of this hybrid catalyst type was demonstrated by ring‐opening metathesis polymerization of a 7‐oxanorbornene derivative in aqueous solution. 相似文献
947.
Shuwen Li Zhengping Dong Honglei Yang Shujing Guo Galian Gou Ren Ren Zhejun Zhu Prof. Jun Jin Jiantai Ma 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(7):2384-2391
A new catalyst consisting of ionic liquid (IL)‐functionalized carbon nanotubes (CNTs) obtained through 1,3‐dipolar cycloaddition support‐enhanced electrocatalytic Pd nanoparticles (Pd@IL(Cl?)‐CNTs) was successfully fabricated and applied in direct ethanol alkaline fuel cells. The morphology, structure, component and stability of Pd@IL(Cl?)‐CNTs were systematic characterized by transmission electron microscopy (TEM), high‐resolution transmission electron microscopy (HRTEM), Raman spectra, thermogravimetric analysis (TGA) and X‐ray diffraction (XRD). The new catalyst exhibited higher electrocatalytic activity, better tolerance and electrochemical stability than the Pd nanoparticles (NPs) immobilized on CNTs (Pd@CNTs), which was ascribed to the effects of the IL, larger electrochemically active surface area (ECSA), and greater processing performance. Cyclic voltammograms (CVs) at various scan rates illustrated that the oxidation behaviors of ethanol at all electrodes were controlled by diffusion processes. The investigation of the different counteranions demonstrated that the performance of the IL‐CNTs hybrid material was profoundly influenced by the subtly varied structures of the IL moiety. All the results indicated that the Pd@IL(Cl?)‐CNTs catalyst is an efficient anode catalyst, which has potential applications in direct ethanol fuel cells and the strategy of IL functionalization of CNTs could be available to prepare other carbonaceous carrier supports to enhance the dispersivity, stability, and catalytic performance of metal NPs as well. 相似文献
948.
Dr. Lingui Zhu Dr. Shasha Liu Dr. Justin T. Douglas Prof. Dr. Ryan A. Altman 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(38):12800-12805
The conversion of an alcohol‐based functional group, into a trifluoromethyl analogue is a desirable transformation. However, few methods are capable of converting O‐based electrophiles into trifluoromethanes. The copper‐mediated trifluoromethylation of benzylic xanthates using Umemoto’s reagent as the source of CF3 to form C? CF3 bonds is described. The method is compatible with an array of benzylic xanthates bearing useful functional groups. A preliminary mechanistic investigation suggests that the C? CF3 bond forms by reaction of the substrate with in situ generated CuCF3 and CuOTf. Further evidence suggests that the reaction could proceed via a radical cation intermediate. 相似文献
949.
A Rapid and Efficient Way to Dynamic Creation of Cross‐Reactive Sensor Arrays Based on Ionic Liquids
Wei Zhu Weina Li Haowei Yang Yin Jiang Chen Wang Prof. Dr. Yu Chen Prof. Dr. Guangtao Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(35):11603-11612
Based on the simple counterion exchange of ionic liquids, a rapid, facile, and efficient strategy to create a cross‐reactive sensor array with a dynamic tunable feature was developed, and exemplified by the construction of a sensor array for the identification and classification of nitroaromatics and explosives mimics. To achieve a good sensing system with fast response, good sensitivity, and low detection limit, the synthesized ionic liquid receptors were tethered onto a silica matrix with a macro‐mesoporous hierarchical structure. Through the facile anion exchange approach, abundant ionic‐liquid‐based individual receptors with diversiform properties, such as different micro‐environments, diverse molecular interactions, and distinctive physico‐chemical properties, were easily and quickly synthesized to generate a distinct fingerprint of explosives for pattern recognition. The reversible anion exchange ability further endowed the sensor array with a dynamic tunable feature as well as good controllability and practicality for real‐world application. With the assistance of statistical analysis, such as principal component analysis (PCA) and linear discrimination analysis (LDA), an optimized‐size array with a good resolution was rationally established from a large number of IL‐based receptors. The performed experiments suggested that the ionic‐liquid‐based sensing protocol is a general and powerful strategy for creating a cross‐reactive sensor array that could find a wide range of applications for sensing various analytes or complex mixtures. 相似文献
950.
Dr. Junwu Zhu Chi Cheng Xiaowei Yang Yufei Wang Ling Qiu Prof. Dan Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(9):3082-3089
Restacking of graphene sheets to a graphite‐like structure is a prevailing problem that is known to compromise the performance of individual graphene sheets in an assembled bulk form. To address this common problem efficiently and monitor the structure and quality of graphene products comprehensively, it is highly desirable to develop reliable metrology techniques for characterising graphene‐based materials on a bulk assembly level and in a quantitative manner. Here, by revisiting the physicochemical principle of electrosorption, we propose a simple electrochemical approach, namely dynamic electrosorption analysis (DEA), as an easily accessible and effective technique for evaluation of the self‐stacking behaviour of graphene. Taking multilayered chemically converted graphene films as a model, we demonstrate that the DEA technique can effectively reveal very subtle variation in accessible surface area and pore size of graphene assemblies in the liquid phase and thus can provide useful insights to the experimental design relating to restacking control. This work also reveals the huge effect some routine processing conditions, such as heat treatment and drying, can have on the structure and performance of graphene‐based bulk materials, providing useful guidance for future manufacturing of this class of materials. 相似文献