金属基体上铝溶胶涂层的制备

 以拟薄水铝石为原料,采用HNO3胶溶法制备了铝溶胶,研究了制备条件对胶体性质的影响. 结果表明,拟薄水铝石的含量和HNO3的加入量是影响胶体粒度大小、粒径分布以及胶体稳定性的重要因素. 当拟薄水铝石的含量为4.5%~5.5%、酸加入量为［H+］/［AlOOH］=0.08~0.1(摩尔比)时,可以得到颗粒度小(平均粒径≤19.3 nm),粒径分布范围窄(4.1~53 nm)和稳定性好的胶体溶液. 以该胶体为过渡涂层涂覆在金属基体上. 在能形成稳定胶体的前提下,酸度相同时,胶体的浓度越大,粘度越大,涂覆到基体上的量就越多; 但是过渡涂层的牢固度似乎与胶体的浓度关系不大. 金属基体的前处理条件也是一个重要的因素,它不仅影响过渡层的涂覆量,也影响涂层的牢固度.     

双组分有机低分子凝胶的研究进展

双组分有机低分子凝胶的研究已成为纳米化学新兴研究领域的热点之一, 形成双组分有机低分子凝胶的有机分子具有多种结构, 例如: 巴比妥酸衍生物、氨基酸衍生物、糖类衍生物、金属有机化合物、胆固醇类衍生物和树枝状分子等. 较系统地综述了目前已知的双组分凝胶及其所涉及的有机低分子凝胶因子的主要结构类型, 并展望了双组分有机低分子凝胶的应用前景.     

Total Restrained Domination in Cubic Graphs

A set S of vertices in a graph G = (V, E) is a total restrained dominating set (TRDS) of G if every vertex of G is adjacent to a vertex in S and every vertex of V − S is adjacent to a vertex in V − S. The total restrained domination number of G, denoted by γ _tr (G), is the minimum cardinality of a TRDS of G. Let G be a cubic graph of order n. In this paper we establish an upper bound on γ _tr (G). If adding the restriction that G is claw-free, then we show that γ _tr (G) = γ _t (G) where γ _t (G) is the total domination number of G, and thus some results on total domination in claw-free cubic graphs are valid for total restrained domination. Research was partially supported by the NNSF of China (Nos. 60773078, 10832006), the ShuGuang Plan of Shanghai Education Development Foundation (No. 06SG42) and Shanghai Leading Academic Discipline Project (No. S30104).     

Low-loss subwavelength metal C-aperture waveguide

We present a design of a linear optical waveguide that utilizes a C-shaped metallic nano-aperture that efficiently transports light while maintaining a spot size of lambda/10. The performance of a C-aperture waveguide is superior to both a regular ridge waveguide and other surface plasmon based metal nano-optical waveguides. The energy transport mechanisms are explained by the coupling of an aperture surface resonance and the thickness resonances inside the guide channel. Finite-difference time-domain simulations of gold C-aperture waveguides are performed for a 1.5 microm wavelength incident plane wave. The 1/e decay length in power transmission is predicted to be approximately 2.5 microm. The total power throughput is 1.66 for the 2.55 microm long guide, with an intensity 6 times that of the incident wave at a distance 120 nm from the exit plane, having a spot size of 150 nm.     

Enhanced interface interaction between modified carbon nanotubes and magnesium matrix

Carbon nanotube (CNT)/metal interface interaction is critical to the mechanical properties of CNT-reinforced metal matrix composites (MMCs). In this paper, in order to realize the chemical modification of the interface interaction between CNTs and Mg matrix, different types of defects (monovacancy, carbon and oxygen adatoms, as well as p-type boron and n-type nitrogen substitution) are introduced in CNTs to investigate the effect of the defects on the interface interaction (E_ib) between CNT and Mg (0 0 0 1) surface. Moreover, two models (adsorption model and interface model) are compared and validated to investigate the interface interaction. It is revealed that the CNT with the carbon adatom has the highest E_ib with the Mg (0 0 0 1), and the effect of boron doping on E_ib is superior to the intermediate oxygen which has already been proved experimentally in the enhancement of the interface interaction in MMCs. In terms of the electronic structure analysis, we reveal the micro-mechanism of the increase of E_ib under the action of different types of defects, and propose that the presence of holes (boron dopant) and the unsaturated electrons in CNTs can generate the chemical interaction between CNT and Mg matrix effectively. Our results are of great scientific importance to the realization of robust interfacial bonding between CNTs and Mg matrix via the reinforcement modification, so as to enhance the mechanical properties of CNTs reinforced Mg matrix composites.     

Ab initio exploration of d<Superscript>0</Superscript> digital magnetic heterostructures: the case of MgO and CaO <Emphasis Type="Italic">δ</Emphasis>-doped with potassium

Previous studies of digital magnetic heterostructures have mainly focused on 3d transition metal δ-doped semiconductors. In this work, sp-electron digital magnetic heterostructures without magnetic ions are proposed. Based on a theoretical density functional investigation, electronic structures and magnetic properties of MgO and CaO δ-doped with K were reported. The results show that these heterostructures are half-metallic ferromagnetic materials having semiconducting up spins and metallic down spins, with an exchange interaction much stronger than that of a random alloy with similar K concentration. Our first-principles calculations show that the carriers at the Fermi level are strongly confined within a few monolayers around the KO plane. This strong confinement is responsible for the large exchange coupling and the two-dimensional half-metallic behavior. The thickness of the host semiconducting spacer does not significantly change the global electric and magnetic features.     

Mg-MOF-74对CO2/H2O的吸附性能

以Mg(NO₃)₂·6H₂O和2,5-二羟基对苯二甲酸为原料, 采用溶剂热法制备了金属有机骨架材料Mg-MOF-74. 利用X射线衍射(XRD)、 红外光谱(FTIR)和扫描电子显微镜(SEM)等测试手段对其结构、 形貌和性能进行了分析, 并利用自制穿透实验装置研究了产物吸附CO₂/H₂O的性能. 结果表明: 合成的样品纯度高, 结构完整, 形貌规则有序, 具有较高的CO₂吸附量. 双组分CO₂/H₂O穿透实验结果证实, 在水蒸气存在情况下, 与沸石13X相比, Mg-MOF-74仍具有较高的CO₂吸附能力, 可用于分离高湿烟道气中的CO₂.     

具有服务等级的两台同型机实时在线排序

考虑具有服务等级的两台同型机在线排序问题, 其中工件带有到达时间, 目标为最小化最大完工时间, 设计了竞争比为\frac{7}{4}的在线算法.     

平行共轴线圈的磁场特征研究与实验设计

通过计算机及相关的传感器和数据采集接口辅助,研究了平行共轴双线圈间距分别为0.5R,R,1.5R时,轴线方向磁场强度的分布规律及特征.从平行共轴双线圈间距为R的亥姆霍兹线圈所形成的均匀磁场出发,结合理论推导,自己设计并组装了三线圈实验装置,实现了平行共轴三线圈均匀磁场区域扩大、强度增强的实验设计,在一定程度上弥补了传统亥姆霍兹线圈磁场测量的不足并有助于对其深入的理解和研究.