全文获取类型
收费全文 | 440篇 |
免费 | 25篇 |
国内免费 | 44篇 |
专业分类
化学 | 307篇 |
晶体学 | 8篇 |
力学 | 12篇 |
综合类 | 5篇 |
数学 | 62篇 |
物理学 | 115篇 |
出版年
2023年 | 9篇 |
2022年 | 18篇 |
2021年 | 19篇 |
2020年 | 24篇 |
2019年 | 18篇 |
2018年 | 17篇 |
2017年 | 23篇 |
2016年 | 16篇 |
2015年 | 14篇 |
2014年 | 14篇 |
2013年 | 21篇 |
2012年 | 25篇 |
2011年 | 31篇 |
2010年 | 22篇 |
2009年 | 35篇 |
2008年 | 28篇 |
2007年 | 21篇 |
2006年 | 26篇 |
2005年 | 15篇 |
2004年 | 18篇 |
2003年 | 19篇 |
2002年 | 11篇 |
2001年 | 2篇 |
2000年 | 7篇 |
1999年 | 10篇 |
1998年 | 9篇 |
1997年 | 4篇 |
1996年 | 6篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有509条查询结果,搜索用时 15 毫秒
11.
12.
13.
Panse S Dong L Burian A Carus R Schutkowski M Reimer U Schneider-Mergener J 《Molecular diversity》2004,8(3):291-299
Kinases represent one of the largest enzyme families and key regulatory proteins in the cell. Only a small subset of these enzymes has been characterised so far. We have prepared different types of phosphopeptide and peptide microarrays displaying peptides deduced from annotated human phosphorylation sites and cytoplasmic domains of all annotated human membrane proteins. This approach was enabled by fully-automated high throughput micro-scale synthesis of peptides by the SPOT technology combined with chemo-selective immobilisation on modified glass slides. The phosphopeptide microarrays displaying 2923 peptides in total have been used for the characterisation of commercially available generic anti-phosphopeptide antibodies. This enabled us to detect Abl kinase activity on a microarray with anti-phosphotyrosine antibodies yielding results comparable to those obtained from a radioactive assay. More than 13 000 peptides deposited on six glass slides were used to profile casein kinase 2 (CK2) using a radioactive assay, since no generic antibody for the reliable detection of serine or threonine phosphorylation could be identified. All previously identified substrates were detected in the microarray experiment. In order to confirm whether substrates on the microarray are substrates in solution phase assays, more than 700 peptides were synthesised and tested with CK2 in a solution phase assay. All substrates identified in the solution phase assay were also detected on the microarray. 相似文献
14.
Jianing Zhang Baolong Wang Liying Wang Junmin Sun Yongfeng Zhang Zhenzhu Cao Zhenqiang Wu 《应用有机金属化学》2018,32(2)
Low‐cost, highly active and versatile amino‐bis(phenolate) cobalt complexes are developed. The cobalt complexes can control living polymerization of different categories of monomers including lactide (LA) by immortal ring‐opening polymerization in argon and even in air and acrylate via living radical polymerization (LRP). The cobalt‐based catalysts were used for copolymerization of LA and acrylate. The immortal polymerization of LA using the cobalt complexes as initiators proceeds in argon and even in air and without the requirement for extensive drying techniques or inert atmosphere whilst retaining end‐group fidelity. The cobalt complexes are used to mediate LRP of t‐butyl acrylate (tBA) in methanol. The block copolymerization of LA and tBA catalyzed by single‐site cobalt organometallic catalyst is also reported for the first time. This cobalt system offers a versatile and green way to produce homopolymers and block copolymers. 相似文献
15.
Zhang Liying Li Hao Yang Bingwang Zhou Ying Zhang Zhongtao Wang Yu 《Journal of Solid State Electrochemistry》2019,23(12):3287-3297
Journal of Solid State Electrochemistry - Co3O4 has attracted extensive interests as a non-noble-metal electrocatalyst of oxygen evolution reaction, which is critical to many electrical energy... 相似文献
16.
Zhang Meihui Zhang Lizhi Wang Wei Yan Tingchang Xu Liying Dong Jinhua 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(3):1463-1467
Journal of Radioanalytical and Nuclear Chemistry - A convenient and inexpensive approach for the synthesis of deuterium-labeled thiamphenicol was described. DL-threo-Thiamphenicol-methyl-d3 was... 相似文献
17.
MNA/PMMA有机薄膜光波导 总被引:2,自引:0,他引:2
研究出MNA/PMMA有机薄膜光波导。用棱镜耦合器进行了波导参数的测量,发现薄膜呈现各向异性,有较大的双折射。 相似文献
18.
19.
分析了温度梯度和均匀温度对潜望式激光通信终端反射镜形变的影响,利用椭圆域上的Zernike多项式对椭圆反射镜的波前进行拟合,计算由于热形变导致的波前畸变误差,给出了星间激光通信终端反射镜均方根值、发射光束瞄准误差、接收端光强随温度梯度和均匀温度的变化关系。结果表明:温度梯度对反射镜的影响只是引起峰值光强的漂移和少许下降,当温度梯度为14 ℃/m时瞄准误差达2.1 μrad。均匀温度会引起接收端的光强分布变化,从而导致很大的瞄准误差和光强衰减,当均匀温度与参考温度的差值小于0.6 ℃时,由波前畸变误差引起的瞄准误差小于1 μrad,当差值大于0.6 ℃时,瞄准误差突然增大到几μrad,接收端光强分布发生变化,此时反射镜热形变引起的像散项对光强分布起重要作用。 相似文献
20.
Dake Hu Tianqi Zhao Xiaofan Ping Husong Zheng Lei Xing Xiaozhi Liu Jingying Zheng Lifei Sun Lin Gu Chenggang Tao Dong Wang Liying Jiao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(21):7051-7055
Two‐dimensional (2D) PtSe2 shows the most prominent layer‐dependent electrical properties among various 2D materials and high catalytic activity for hydrogen evolution reaction (HER), and therefore, it is an ideal material for exploring the structure–activity correlations in 2D systems. Here, starting with the synthesis of single‐crystalline 2D PtSe2 with a controlled number of layers and probing the HER catalytic activity of individual flakes in micro electrochemical cells, we investigated the layer‐dependent HER catalytic activity of 2D PtSe2 from both theoretical and experimental perspectives. We clearly demonstrated how the number of layers affects the number of active sites, the electronic structures, and electrical properties of 2D PtSe2 flakes and thus alters their catalytic performance for HER. Our results also highlight the importance of efficient electron transfer in achieving optimum activity for ultrathin electrocatalysts. Our studies greatly enrich our understanding of the structure–activity correlations for 2D catalysts and provide new insight for the design and synthesis of ultrathin catalysts with high activity. 相似文献