空心Fe_3O_4纳米微球的制备及超顺磁性

采用水热控制合成法,以六水三氯化铁、柠檬酸三钠和尿素为原料,聚丙烯酰胺为稳定剂, 200?C下反应12 h制备得到了超顺磁性空心Fe_3O_4纳米微球.通过X射线衍射仪、扫描电子显微镜、透射电子显微镜对样品的结构和形貌进行表征,并采用振动样品磁强计测试了样品的磁性能.结果表明:所得样品为具有尖晶石结构的Fe_3O_4纳米微球,尺寸为160 nm左右,呈分等级结构,即整个微球由粒径约18 nm的初级晶粒自组装堆叠而成;室温下表现为典型的超顺磁性,且饱和磁化强度为73.3 emu/g (1 emu/g=1 A·m~2/kg),这种高饱和磁化强度可以由其初级晶粒晶化程度高且粒径较大以及这种特殊的二次自组装结构进行解释.这种Fe_3O_4纳米微球为疏松多孔的空心球状结构,具有粒径分布均匀、分散性良好和超顺磁性的特点,在药物靶向输运和肿瘤热疗中有潜在的应用.     

Investigation of the near-threshold cluster resonance in ~(14)C

An experiment for p(~(14)C,~(14)C~*→~(10)Be+α)p inelastic excitation and decay was performed in inverse kinematics at a beam energy of 25.3 Me V/u.A series of~(14)C excited states,including a new one at 18.3(1)Me V,were observed which decay to various states of the final nucleus of~(10)Be.A specially designed telescope system,installed around zero degrees,played an essential role in detecting the resonant states near theα-separation threshold.A state at 14.1(1)Me V is clearly identified,being consistent with the predicted band-head of the molecular rotational band characterized by theπ-bond linear chain configuration.Further clarification of the properties of this exotic state is suggested by using appropriate reaction tools.     

系统压力对含悬浮颗粒油液的影响研究

油液在运行过程中不可避免地会产生颗粒物,影响油液的正常使用,甚至出现设备故障,因而分析含悬浮颗粒油液的动态特征,掌握在不同压力变化条件下油液及颗粒物的变化规律具有重要意义。利用两相流体理论建立了含悬浮颗粒油液的悬浮流动力学模型,通过特征线法进行了数值求解,将数值结果与实验数据比较,具有较好的一致性;根据所建模型,分析了不同系统压力条件下悬浮流中各相的脉动规律。结果表明,流场中各相参数的脉动幅值随着系统压力的增加而增大;管路始端和终端各相参数的脉动时刻分别位于1/4脉动周期(T)的奇数倍和偶数倍处,管路中段各相参数的脉动时刻则位于T/8的奇数倍处;悬浮颗粒速度会受到油液速度拖曳力作用,其变化趋势与油液速度基本一致,颗粒浓度分布与油液压力的变化趋势完全相反。     

Trapping of helium atom by vacancy in tungsten: a density functional theory study

The interaction between helium (He) atom and vacancy defect in tungsten (W) has been investigated by using first-principles simulations. We have obtained that the most stable site for He in tungsten is the substitutional position because He can keep its own electronic structure at this position. In the studied tungsten system, vacancy can act as a trapping center for surrounding He atom with negative trapping energy. The migration behaviors of He atom at tetrahedral interstitial site in W, which can be trapped by vacancy but the final position is almost unchanged comparing with its initial position through structural relaxation, have been predicted and discussed. It is also found that single He atom prefers to go through an octahedral site rather than through a direct path to the vacancy, and the stronger the interaction between He atom and vacancy is, the lower the migration barrier will be.     

Thermal Radiation Laws of a <Emphasis Type="Italic">q</Emphasis>-deformed Boson System in <Emphasis Type="Italic">m</Emphasis> Dimensions

Within the theoretical framework of multidimensional space and q bosons, we generalize our hypothesis of regarding the CMBR as the radiation of q bosons, and investigate the thermal radiation laws of a q boson system in m dimensions. Utilizing the new radiation laws, we make a numerical calculation and the results show that these new laws have some special features. We consider that this work may provide more insight into the theory of q bosons and the study on the CMBR.     

High-lying excited states in <Superscript>10</Superscript>Be from the <Superscript>9</Superscript>Be(<Superscript>9</Superscript>Be,<Superscript>10</Superscript>Be)<Superscript>8</Superscript>Be reaction

A transfer-reaction experiment of ⁹Be(⁹Be, ¹⁰Be)⁸Be was performed at a beam energy of 45 MeV. Excited states in ¹⁰Be up to 18.80 MeV are produced using missing mass and invariant mass methods. Most of the observed high-lying resonant states, reconstructed from the α + ⁶He and t + ⁷Li decay channels, agree with the previously reported results. In addition, two new resonances at 15.6 and 18.8 MeV are identified from the present measurement. The 18.55 MeV state is found to decay into both the t + ⁷Li_g.s. and t + ⁷Li* (0.478 MeV) channels, with a relative branching ratio of 0.93 ± 0.33. Further theoretical investigations are encouraged to interpret this new information on cluster structure in neutron-rich light nuclei.     

Localized states emission in type‐I GaAsSb/AlGaAs multiple quantum wells grown by molecular beam epitaxy

As an important candidate for novel infrared semiconductor lasers, the optical properties of GaAsSb‐based multiple quantum wells (MQWs) are crucial. The temperature‐ and excitation power‐dependent photoluminescence (PL) spectra of the GaAs_0.92Sb_0.08/Al_0.2Ga_0.8As MQWs, which were grown by molecular beam epitaxy, were investigated and are detailed in this work. Two competitive peaks were observed from 40 K to 90 K. The peak located at the low‐energy shoulder was confirmed to be localized states emission (LE) and the high‐energy side peak was confirmed to be free‐carrier emission by its temperature‐dependent emission peak position. It is observed that the LE peak exhibited a blueshift with the increase of laser excitation power, which can be ascribed to the band filling effect of localized states. Our studies have great significance for application of GaAsSb‐based MQWs in infrared semiconductor lasers.

     

多速率STFT超宽带信号瞬时频率估计研究

提出多速率短时傅里叶变换(Multi Rate Short Time Fourier Transform,MR-STFT)瞬时频率估计算法,提高了超宽带信号瞬时频率估计精度。该方法将多速率信号处理算法与短时傅里叶变换(STFT)技术相结合,兼顾采样频率和被测频率,将宽频范围进行分段采样,对分段处理结果进行拟合,构成多速率STFT算法,实现超宽带信号瞬时频率的高精度测量。论文通过对仿真信号和实测信号进行处理,研究了方法的可行性和频率估计精度,结果表明MR-STFT算法较大提高了超宽带信号瞬时频率估计精度,尤其对低信噪比的超宽带信号效果显著。