The theory of crystal ordering

The phenomenological theory of crystal ordering is formulated in terms of a local crystal-order parameter. This parameter is a set of tensors of rank 4. Phase transition from liquid to crystal phase is studied for a cubic crystal. The temperature interval ΔT of an overheated crystal is small: $\text{Δ}\text{T}{}_{\mathrm{<mtext>c</mtext>}}{}^1\text{? 0.02}$. Pre-melting anomalies are shown to exist.     

On the electrochemical behavior of selanyl azulenes

Journal of Solid State Electrochemistry - The electrochemical behavior of substituted 1-phenylselanyl azulenes has been established by cyclic, differential pulse, and rotating disk electrode...     

Hyperbolic Sequences of Linear Operators and Evolution Maps

For a nonautonomous dynamics defined by a sequence of linear operators on a Banach space, we give a characterization of its nonuniform hyperbolicity in terms of the hyperbolicity of an associated evolution map. We also obtain a generalization of this characterization to the class of nonuniformly hyperbolic cocycles over a locally compact topological space with values on the set of bounded linear operators.     

Preparation and characterization of strontium targets for nuclear astrophysics experiments

Journal of Radioanalytical and Nuclear Chemistry - The present paper describes preparation and characterization of strontium targets for nuclear astrophysical experiments with alpha particles...     

Carbon Xerogel Nanostructures with Integrated Bi and Fe Components for Hydrogen Peroxide and Heavy Metal Detection

Multifunctional Bi- and Fe-modified carbon xerogel composites (CXBiFe), with different Fe concentrations, were obtained by a resorcinol–formaldehyde sol–gel method, followed by drying in ambient conditions and pyrolysis treatment. The morphological and structural characterization performed by X-ray diffraction (XRD), Raman spectroscopy, N₂ adsorption/desorption porosimetry, scanning electron microscopy (SEM) and scanning/transmission electron microscopy (STEM) analyses, indicates the formation of carbon-based nanocomposites with integrated Bi and Fe oxide nanoparticles. At higher Fe concentrations, Bi-Fe-O interactions lead to the formation of hybrid nanostructures and off-stoichiometric Bi₂Fe₄O₉ mullite-like structures together with an excess of iron oxide nanoparticles. To examine the effect of the Fe content on the electrochemical performance of the CXBiFe composites, the obtained powders were initially dispersed in a chitosan solution and applied on the surface of glassy carbon electrodes. Then, the multifunctional character of the CXBiFe systems is assessed by involving the obtained modified electrodes for the detection of different analytes, such as biomarkers (hydrogen peroxide) and heavy metal ions (i.e., Pb²⁺). The achieved results indicate a drop in the detection limit for H₂O₂ as Fe content increases. Even though the current results suggest that the surface modifications of the Bi phase with Fe and O impurities lower Pb²⁺ detection efficiencies, Pb²⁺ sensing well below the admitted concentrations for drinkable water is also noticed.     

Non-linear response of geometrically imperfect sandwich curved panels under thermomechanical loading

This paper deals with the non-linear response of sandwich curved panels exposed to thermomechanical loadings. The mechanical loads consist of compressive/tensile edge loads, and a lateral pressure while the temperature field is assumed to exhibit a linear variation through the thickness of the panel. Towards obtaining the equations governing the postbuckling response, the Extended Galerkin’s Method is used. The numerical illustrations concern doubly curved, circular cylindrical and as a special case, flat panels, all the edges being simply supported. Moveable and immoveable tangential boundary conditions in the directions normal to the edges are considered and their implications upon the thermomechanical load-carrying capacity are emphasized. Effects of the radii of curvature and of initial geometric imperfections on the load-carrying capacity of sandwich panels are also considered and their influence upon the intensity of the snap-through buckling are discussed. It is shown that in special cases involving the thermomechanical loading and initial geometric imperfection, the snap-through phenomenon can occur also in the case of flat sandwich panels.     

On slow flows of the full nonlinear Doi–Edwards polymer model

The full Doi–Edwards model constitutive equation derived by Palierne (Phys Rev Lett 93:136001-1–136001-4, (2004) is discussed in detail. The corresponding configurational probability equation is next solved for slow flows, and the solution is used to calculate the material constants: zero-shear viscosity and the normal stress differences.     

Multilayered metal oxide thin film gas sensors obtained by conventional and RF plasma-assisted laser ablation

Multilayered thin films of In₂O₃ and SnO₂ have been deposited by conventional and RF plasma-assisted reactive pulsed laser ablation, with the aim to evaluate their behaviour as toxic gas sensors. The depositions have been carried out by a frequency doubled Nd-YAG laser (λ = 532 nm, τ = 7 ns) on Si(1 0 0) substrates, in O₂ atmosphere. The thin films have been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrical resistance measurements. A comparison of the electrical response of the simple (indium oxide, tin oxide) and multilayered oxides to toxic gas (nitric oxide, NO) has been performed. The influence on the structural and electrical properties of the deposition parameters, such as substrate temperature and RF power is reported.