Gold-surface binding of molecular switches studied by M?ssbauer spectroscopy

The nonanuclear coordination compound [Mo^IV{(CN)Fe^III(3-methyl-saldptn)}₈]Cl₄ exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. M?ssbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e.g. in the field of information storage) was laid.     

Solar-blind MSM-photodetectors based on Al<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Ga<Subscript>1-<Emphasis Type="Italic">x</Emphasis></Subscript>N heterostructures

Solar-blind MSM photodetectors based on the AlGaN heterostructures have been fabricated and investigated. The influence of material properties on device parameters is discussed. Effect of different buffer layers on the detector performances has been examined. Detectors exhibit low dark currents and high sensitivity within the range of 250–290 nm. Effect of optical excitation energy on GaN-based MSM-detector performance is analyzed and discussed. At high excitation level the detector speed of response is limited by the field screening caused by the space-charge of the holes. The impulse response of GaN-based MSM-detector is compared favorably with GaAs MSM-device.     

On the potential limitations of conventional sound metrics in quantifying perception of nonlinearly propagated noise

The use of conventional metrics to quantify the perception of nonlinearly propagated noise has been studied. Gaussian noise waveforms have been numerically propagated both linearly and nonlinearly, and from the resulting waveforms, several metrics are calculated. These metrics are overall, A-, C-, and D-weighted sound pressure levels, perceived noise level, Stevens Mark VII perceived loudness, Zwicker loudness, and sharpness. Informal listening demonstrations indicate that perceived differences in annoyance between linearly and nonlinearly propagated waveforms are substantial. Because the metrics studied seem inadequate in representing the perceived differences, rigorous subjective testing is encouraged to properly quantify and understand these differences.     

Threshold 3He and 3H Transverse Electron Scattering Response Functions

The threshold transverse response functions R _T (q, ω) for ³He and ³H are calculated using the AV18 nucleon–nucleon potential, the UrbanaIX three-body force, and the Coulomb potential. Final states are completely taken into account via the Lorentz integral transform technique. Consistent two-body π- and ρ-meson exchange currents as deduced using the Arenhövel-Schwamb technique are included. The convergence of the method is shown and a comparison of the corresponding MEC contribution is made to that of a consistent MEC for the meson theoretical r-space BonnA potential. The response R _T is calculated in the threshold region at q = 174, 324, and 487 MeV/c and compared with available data. The strong MEC contributions in the threshold region are nicely confirmed by the data at q = 324 and 487 MeV/c although some differences between theoretical and experimental results remain. A comparison is also made with other calculations, where the same theoretical input is used. The agreement is generally rather good, but leaves also some space for further improvement.     

Monitoring nanotechnology using patent classifications: an overview and comparison of nanotechnology classification schemes

Patents are an essential information source used to monitor, track, and analyze nanotechnology. When it comes to search nanotechnology-related patents, a keyword search is often incomplete and struggles to cover such an interdisciplinary discipline. Patent classification schemes can reveal far better results since they are assigned by experts who classify the patent documents according to their technology. In this paper, we present the most important classifications to search nanotechnology patents and analyze how nanotechnology is covered in the main patent classification systems used in search systems nowadays: the International Patent Classification (IPC), the United States Patent Classification (USPC), and the Cooperative Patent Classification (CPC). We conclude that nanotechnology has a significantly better patent coverage in the CPC since considerable more nanotechnology documents were retrieved than by using other classifications, and thus, recommend its use for all professionals involved in nanotechnology patent searches.     

Pump−probe experiments at the TEMPO beamline using the low‐α operation mode of Synchrotron SOLEIL

The SOLEIL synchrotron radiation source is regularly operated in special filling modes dedicated to pump–probe experiments. Among others, the low‐α mode operation is characterized by shorter pulse duration and represents the natural bridge between 50 ps synchrotron pulses and femtosecond experiments. Here, the capabilities in low‐α mode of the experimental set‐ups developed at the TEMPO beamline to perform pump–probe experiments with soft X‐rays based on photoelectron or photon detection are presented. A 282 kHz repetition‐rate femtosecond laser is synchronized with the synchrotron radiation time structure to induce fast electronic and/or magnetic excitations. Detection is performed using a two‐dimensional space resolution plus time resolution detector based on microchannel plates equipped with a delay line. Results of time‐resolved photoelectron spectroscopy, circular dichroism and magnetic scattering experiments are reported, and their respective advantages and limitations in the framework of high‐time‐resolution pump–probe experiments compared and discussed.     

Transmission through chiral twist defects in anisotropic periodic structures

A long-lived photonic state is observed in measurements of microwave transmission through a helical stack of anisotropic overhead transparencies with various twist defects in the center of the structure. Once account is taken of absorption and of the angular spread of the source, computer simulations of transmission through a polarized localized state are in agreement with measurements. Unlike for isotropic one-dimensional bandgaps, the intensity of the localized mode is not modulated in space on a wavelength scale.     

Power-dependent shaping of vortex solitons in optical lattices with spatially modulated nonlinear refractive index

We address vortex solitons supported by optical lattices featuring modulation of both the linear and nonlinear refractive indices. We find that when the modulation is out of phase the competition between both effects results in remarkable shape transformations of the solitons that profoundly affect their properties and stability. Nonlinear refractive index modulation is found to impose restrictions on the maximal power of off-site solitons, which are shown to be stable only below a maximum nonlinearity modulation depth.     

Metabolic Profiling of Murine Macrophages Exposed to Silver Nanoparticles at Dose and Time Dependencies

The macrophage time-dependent metabolic profile changing basal metabolism triggered by nanoparticles can be obtained and used to improve wound healing treatments. Herein this study demonstrates that metabolic status responds systematically to cytotoxicity manipulation, providing an interesting way of cellular control. Nuclear magnetic resonance (NMR) based metabolomics and cytotoxic assays are used to study RAW 264.7 cells exposed to AgNPs at different concentrations and incubation times. Cytotoxicity data show a slight decrease in cellular expansion rates accompanied by morphological changes in cells. Metabolomics show that despite the glycolytic activity of treated and non-treated cells remains unchanged; however, only the treated cells present a rich Citrate environment signaling up-regulation of Tricarboxylic-Acid-Cycle (TCA). Cells choose aerobic routes instead of anaerobic ones to produce energy and self-regulate their amino acid metabolism to balance TCA. Choline metabolism is down-regulated once its sub-products, Betaine and Glycine, are reduced, thus compromising Creatine synthesis. Phospholipid metabolism is down-regulated due to the decreasing of Phosphocholine and Sn-Glycerol-3-PC, in agreement with the cytotoxicity results. Pyroglutamate decreases in treated cells, signaling different levels of oxidative stress. These analytical tools can characterize AgNPs-treatments, even distinguishing dose and time dependencies. Therefore, the fine-tuning of exposition parameters can modulate cellular activity to achieve better wound healing.