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61.
V. A. Artemov A. M. Shestopalov V. P. Litvinov 《Chemistry of Heterocyclic Compounds》1996,32(4):445-448
The structure of the product of interaction of the sodium salt of 1, 2, S-trimethyl-3 formylpiperid-4-one with cyanothioacetamide was specified. It was shown that the Knoevenagel adduct formed at the first stage in basic conditions undergoes recyclization with the formation of 1, 2,3,5,6, 7, 8, 8a-octahydro-l-oxo-6, 7, 8a-trimethyl-4-cyano-2, 7-naphthyridine-3-thione, the structure of which was confirmed by the data of physicochemical methods of analysis and chemical conversions.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 512–515, April, 1996. 相似文献
62.
V. A. Mamedov I. A. Litvinov F. G. Sibgatullina O. N. Kataeva I. A. Nuretdinov V. A. Naumov 《Chemistry of Heterocyclic Compounds》1994,30(2):169-172
Condensation of benzalaniline with N,N-dimethylamide of dichloroacetic acid under Darzens reaction conditions was used to obtain r-1, t-3-diphenyl-c-2-chloro-2-(NN-dimethylcarbamoyl)aziridine. The structure was established by x-ray diffraction analysis. Stabilization of the position of the substituents at the atoms of the aziridine ring by the hyperconjugation interaction of the unshared electron pair of the nitrogen atom with the antibonding orbital of the C-CI bond is discussed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 189–192, February, 1994. Original article submitted November 30, 1993. 相似文献
63.
S. V. Bukharov I. A. Litvinov A. T. Gubaidullin G. N. Nugumanova N. A. Mukmeneva 《Russian Journal of General Chemistry》2002,72(2):268-271
The structure of 2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)resorcinol in the crystal is virtually identical to that of 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)mesitylene, which is an effective antioxidant. 相似文献
64.
G. N. Nikonov A. S. Balueva A. A. Karasik I. A. Litvinov O. A. Erastov B. A. Arbuzov V. A. Nauraov 《Russian Chemical Bulletin》1988,37(1):143-147
1. | Reactions of ammonium 2,2,5-triphenyl-1,3,2,5-dioxaborataphosphorinanes with alkyl halides, diphenylchlorophosphine, formaldehyde, and ethylene oxide were carried out. |
2. | The molecular structure of the N--hydroxyethyltriethylammonium salt of 2,2,5-tri-phenyl-4,6-dimethyl-1, 3,2,5-dioxaborataphosphorinane was established. |
65.
V. V. Bakharev A. A. Ghidaspov D. B. Krivolapov E. V. Mironova I. A. Litvinov 《Chemistry of Heterocyclic Compounds》2006,42(8):1051-1058
2-Amino-4-azido-1,3,5-triazin-6(1H)-ones were synthesized by successive substitution of the trinitromethyl groups in 2-amino-4,6-bis(trinitromethyl)-1,3,5-triazines
under the influence of azide and nitrite ions. Interaction of 2-amino-4-azido-1,3,5-triazin-6(1H)-ones with bases led to the
azido-tetrazole tautomeric conversion give salts of 5-aminotetrazolo[1,5-a]-1,3,5-triazin-7-one.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1211–1219, August, 2006. 相似文献
66.
Kuznetsov R. M. Balueva A. S. Litvinov I. A. Gubaidullin A. T. Nikonov G. N. Karasik A. A. Sinyashin O. G. 《Russian Chemical Bulletin》2002,51(1):151-156
The reaction of bis(hydroxymethyl)phenylphosphine with 4,4"-diaminodiphenylmethane in DMF afforded 1,1",5,5"-bis[methylenedi(p-phenylene)]di(3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) (1) whose structure was established by X-ray diffraction analysis. Sulfurization and oxidation of macrocyclic tetraphosphine 1 gave rise to products 2 and 3, respectively, compound 3 being obtained as a stable hexahydrate. The reaction of bis(hydroxymethyl)phenylphosphine with bis(4-N-methylaminophenyl)methane in DMF followed by sulfurization yielded monocyclic bis{methylenedi[p-phenylene(N-methyl)aminomethyl]}di(P-phenyl)phosphine sulfide (4). 相似文献
67.
A. M. Shestopalov V. P. Litvinov Yu. A. Sharanin I. A. Aitov L. A. Rodinovskaya 《Russian Chemical Bulletin》1991,40(4):835-838
The reaction of pyridinium, 2-picolinium, and 3-picolinium ylids with tetracyanoethylene, ethoxymethylenemalononitrile, and (dimethylthio)methyl-enecyanamide in the presence of organic bases proceeds regio- and stereo-selectively to give substituted pyridinium 1,4-ylids, 2-(2-propen-1-ylidene)-1,2-dihydropyridines, and 5-(1-pyridino)pyrimidin-4-olates, respectively. The reaction of 1-phenacylpyridinium bromide and tetracyanoethylene leads to 1-phenacylpyridinium tricyanoethenolate.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 939–942 April, 1990. 相似文献
68.
V. V. Dotsenko S. G. Krivokolysko V. P. Litvinov 《Chemistry of Heterocyclic Compounds》2007,43(11):1455-1459
5,11-Disubstituted derivatives of 1′-isopropyl-8-thioxospiro[3,5,7,11-tetrazatricyclo[7.3.1.02,7]tridec-2-ene-13,4′-piperidine]-1,9-dicar bonitrile was obtained by the interaction of 10-amino-9-aza-3-azonia-7,11-dicyano-3-isopropylspiro[5,5]undeca-7,10-diene-8-thiolate
with 2 equiv. of a primary amine and excess of formaldehyde. An anomalous reaction product was obtained with o-toluidine — 7,9-dicyano-1′-isopropyl-3-(2-methylphenyl)-1,2,3,4-tetrahydrospiro[pyrido[1,2-a][1,3,5]triazine-8,4′-piper idinium]-6-thiolate.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, 1709–1713, November, 2007. 相似文献
69.
Khailova N. A. Shaimardanova A. A. Saakyan G. M. Zyablikova T. A. Azancheev N. M. Krivolapov D. B. Gubaidullin A. T. Litvinov I. A. Musin R. Z. Chmutova G. A. Pudovik M. A. Pudovik A. N. 《Russian Journal of General Chemistry》2003,73(8):1213-1226
Phenyl -aminoalkylphosphonates add to phenyl iso(thio)cyanates to give saturated heterocycles, 1,3,4-diazaphospholidin-2-(thi)ones. The reaction of diphenyl (-methylamino)benzylphosphonate with diethyl isothiocyanatophosphate involves initial formation of 1,3,4-tiazaphospholidine-2-thiones containing exo- and endocyclic phosphorus atoms. These products are readily hydrolyzed in air, yielding diethyl isothio- cyanatophosphate and phenyl hydrogen (-methylamino)benzylphosphonate. The final products of the reaction of chloromethyl isocyanatophosphonates with aminoalkylphosphonates are 1,3,4-oxazaphospholines. Phenyl aminoalkylphosphonates react with chloromethyl isocyanatophosphonates to give saturated heterocycles, 1,3,4-diazaphospholidines, whereas with chloromethyl isothiocyanatophosphonates 1,3,4-thiazaphospholines are formed. 相似文献
70.
Olga N. Kataeva Aidar T. Gubaidullin Igor A. Litvinov Olga A. Lodochnikova Lenar R. Islamov Alexander I. Movchan Galina A. Chmutova 《Journal of Molecular Structure》2002,610(1-3):175-179
Crystal and molecular structure of 1-phenyl-3-benzoylamino-4-benzoylpyrazol-2-in-5-one as a product of the benzoylation of 1-phenyl-3-benzoylaminopyrazol-2-in-5-one was characterised by X-ray single crystal diffraction. It is shown that 1-phenyl-3-benzoylamino-4-benzoylpyrazol-2-in-5-one exists in the solid phase in an NH-tautomeric form, which is stabilised by two intramolecular hydrogen bonds and one intermolecular bond with the solvate dioxane molecule, the latter being used as a solvent for recrystallisation. 相似文献