全文获取类型
收费全文 | 317篇 |
免费 | 11篇 |
国内免费 | 1篇 |
专业分类
化学 | 214篇 |
晶体学 | 4篇 |
力学 | 8篇 |
数学 | 43篇 |
物理学 | 60篇 |
出版年
2021年 | 3篇 |
2020年 | 5篇 |
2017年 | 4篇 |
2015年 | 8篇 |
2014年 | 5篇 |
2013年 | 7篇 |
2012年 | 12篇 |
2011年 | 11篇 |
2010年 | 6篇 |
2009年 | 3篇 |
2008年 | 8篇 |
2007年 | 10篇 |
2006年 | 12篇 |
2005年 | 7篇 |
2004年 | 13篇 |
2003年 | 14篇 |
2002年 | 16篇 |
2001年 | 10篇 |
2000年 | 10篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 7篇 |
1992年 | 10篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1984年 | 5篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 8篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1975年 | 6篇 |
1974年 | 6篇 |
1973年 | 2篇 |
1972年 | 3篇 |
1971年 | 3篇 |
1970年 | 3篇 |
1969年 | 2篇 |
1938年 | 2篇 |
1930年 | 2篇 |
1923年 | 2篇 |
1920年 | 2篇 |
1916年 | 2篇 |
1914年 | 2篇 |
排序方式: 共有329条查询结果,搜索用时 31 毫秒
91.
92.
J. A. Little 《Chromatographia》2004,59(2):S177-S181
In the case of ligand binding assays the relationship between instrumental response and analyte concentration is non-linear, usually either hyperbolic or sigmoidal. As it is not possible to calibrate an assay at all the levels to be measured a suitable method of constructing a concentration-response relationship (the standard curve), based on a limited number of carefully spaced standards is required. The method should be robust and operator independent. The two main approaches that have been used involve empirical and mechanistic (theoretical) models. Empirical models utilise any mathematical function(s) that appears to have the characteristics of the experimentally derived assay data. Empirical models require no understanding of the principles of the assay. Mechanistic models make assumptions about the physico-chemical processes involved in the assay procedure. In practice either single function or spline models are used. The curve fitting solution may be explicit (in the case of spline interpolation), or by least-squares curve fitting regression methods, including polynomial and logistic equations, the latter involving many iterations. Examples of good curve fitting selection are presented and contrasted with inappropriate models in a number of common assay formats. 相似文献
93.
S.B. Qadri T.M. Keller M. Laskoski C.A. Little P. Lubitz M.S. Osofsky H.R. Khan 《Applied Physics A: Materials Science & Processing》2007,86(3):391-394
Nanoparticles of Ru1-xFex (0≤x≤1) in a carbon matrix were synthesized over the entire composition range using organometallic precursors. For Fe concentrations
with x<0.70, a hexagonal close-packed phase was formed whereas a body-centered cubic phase was observed for x>0.70. The crystallite
sizes varied between 5–10 nm. In addition, multi-wall carbon nanotubes formed during the pyrolysis of the precursors. Increasing
superparamagnetic order was observed with increasing Fe content. 相似文献
94.
Whispering-gallery modes in silica microspheres can be accessed very efficiently with the recently introduced stripline pedestal antiresonant reflecting optical waveguide (SPARROW) structure. This integrated-optics coupling technique creates novel application opportunities for the high-Q spherical cavities. We report the demonstration of a narrow-band wavelength-drop configuration utilizing SPARROW waveguides and a silica microsphere. 相似文献
95.
96.
Summary Five common tricyclic antidepressants are separated on a silica column using an aqueous eluent. The tricyclics are concentrated from serum using an adsorption procedure on a solid phase Sep PakTM C18 cartridge. The method appears to be adequate for monitoring therapeutic levels of these drugs.Dedicated to Professor Dr. István Halász for his 60th birthday. 相似文献
97.
98.
Desmond Cunningham Mark Little Kevin McLoughlin 《Journal of organometallic chemistry》1979,165(3):287-294
New adducts Et4N(RSnCl4 · L) (R butyl and phenyl; L pyridine, trimethylamine, tri-n-butylphosphine, triphenylphosphine oxide, triphenylarsine oxide, dimethylsulphoxide, dimethylformamide) have been isolated and their Mössbauer spectra studied. Definite structural assignments are made for the phosphine and phosphine oxide adducts from Mössbauer quadrupole splitting data. Comments are made on the choice of partial splitting values for phenyl and butyl groups. 相似文献
99.
100.
P Workman C J Little T R Marten A D Dale R J Ruane I R Flockhart N M Bleehen 《Journal of chromatography. A》1978,145(3):507-512