DISCUSSION ON THE APPLICATION OF NUMERICAL EXPERIMENT IN EXPERIMENTAL TEACHING OF FLUID MECHANICS

为强化学生对流体力学课程理论知识及实验教学环节的掌握,本文针对传统实验教学过程中受限于硬件设施、模型等问题,将数值模拟技术与流体力学实验教学相结合。以伯努利实验为例,应用数值模拟软件进行物理建模、网格划分、变参数数值模拟等实验内容,通过压力云图、流线等模拟结果对能量转换特性进行了分析,增强了学生对流体力学理论知识及相关参数的物理意义、变化特征等的理解,使学生在实验中产生强烈的“参与感”,有效地提高了教学水平和教学质量。     

在线双毛细管-氢化物火焰原子吸收光谱法测定砷、锑、铋、汞、硒和锡

1引言使用氢化物原子吸收光谱(HG-AAS)法测定As、Sb、B、iHg、Se和Sn已有报道。但将氢化物在线引入空气乙炔焰,用火焰法快速测定这些元素的方法少见报道。本实验利用双毛细管装置,建立了在线HG-AAS测定As、Sb、B、iHg、Se和Sn的方法,该方法具有简便、快速、灵敏度高,干扰少和KBH4用量少的优点。2实验部分2.1仪器及试剂GGX-9型原子吸收分光光度计;微型多功能进样装置(自制专利产品);空心阴极灯;盐酸(1 1);硫脲溶液(5%);抗坏血酸溶液(5%);KBH4溶液(1%,2%);邻二氮菲溶液(1%);As、Sb、B、iHg、Se、Sn的标准溶液;蒸馏水;其余试剂…     

Synthesis of polysubstituted 5-hydroxyhydantoins via ring-opening of isatins

A simple and efficient tandem reaction approach was developed for the synthesis of 5-hydroxyhydantoins from one-pot reaction of isatins, phthalic anhydride or succinic anhydride, and 1,3-dimethylurea (1,3-diethylurea). The products were gained through the ring-opening of isatins process. The advantages of this report are simple operation, mild reaction conditions, good yields and easily available raw materials. It was very important for us to obtain the intermediate product and that provided a solid basis for the correct interpretation of the reaction mechanism.     

Dual-axes differential confocal microscopy with high axial resolution and long working distance

We discover that the slight transverse offset of a point detector results in a shift of the axial intensity response curve in a dual-axes confocal microscopy (DCM). Based on this, we propose a new dual-axes differential confocal microscopy (DDCM) with high axial resolution and long working distance, in which two point detectors are placed symmetrically about the collection axis. And a signal is obtained through the differential subtraction of two signals received simultaneously by the two point detectors. Theoretical analyses and preliminary experiments indicate that DDCM is feasible and suitable for the high precision tracing measurement of microstructures and surface contours.     

Reliability measures for two-part partition of states for aggregated Markov repairable systems

Three models for the aggregated stochastic processes based on an underlying continuous-time Markov repairable system are developed in which two-part partition of states is used. Several availability measures such as interval availability, instantaneous availability and steady-state availability are presented. Some of these availabilities are derived by using Laplace transforms, which are more compact and concise. Other reliability-distributions for these three models are given as well.     

Synthesis of propylene carbonate from carbon dioxide using trans‐dichlorotetrapyridineru‐ thenium(II) as catalyst

trans‐Dichlorotetrapyridineruthenium(II) [trans‐RuCl₂(py)₄] was synthesized and the structure was determined by single crystal X‐ray crystallography. Highly efficient formation of propylene carbonate (PC) from carbon dioxide and propylene oxide was achieved by using a catalyst system composed of trans‐RuCl₂(py)₄ and hexadecyl trimethyl ammonium bromide under mild conditions (4h, 80 °C, 3.0 MPa). PC was obtained in nearly 100% selectivity without the formation of a polymer. The catalyst could be recycled constantly many times without any significant loss of its catalytic activity. On the basis of the results, a mechanism for the reaction was proposed. Copyright © 2010 European Peptide Society and John Wiley & Sons, Ltd.     

A lateral super-resolution differential confocal technology with phase-only pupil filter

In order to achieve a higher lateral resolution required for ultraprecision measurement of microstructural workpieces, phase-only pupil filtering differential confocal microscopy (PFDCM), a new approach is proposed based on the differential confocal microscopy (DCM), which uses a three-zone phase-only pupil filter with lateral super-resolution capability obtained through optimized design to change the distribution of DCM three-dimensional point spread function, so that the DCM lateral resolution is therefore significantly improved while its axial resolution is slightly improved. Preliminary experimental comparison and analyses indicate that, the lateral and axial resolutions of PFDCM are better than 0.2 μm and 2 nm, respectively, when wavelength of incidence laser beam , numerical aperture of measuring lens NA=0.85, and lateral spot size with a three-zone phase-only pupil filter G_T=0.65. It is therefore concluded that PFDCM is a new approach to further improvement of lateral resolution in laser probe measurement systems.     

Photonic graphene with reconfigurable geometric structures in coherent atomic ensembles

Photonic graphene, possesses a honeycomb-like geometric structure, provides a superior platform for simulating photonic bandgap, Dirac physics, and topological photonics. Here, the photonic graphene with reconfigurable geometric structures is demonstrated in a 5S_1/2 − 5P_3/2 − 5D_5/2 cascade-type ⁸⁵Rb atomic ensembles. A strong hexagonal-coupling field, formed by the interference of three identical coupling beams, is responsible for optically inducing photonic graphene in atomic vapor. The incident weak probe beam experiences discrete diffraction, and the observed pattern at the output plane of vapor cell exhibits a clear hexagonal intensity distribution. The complete photonic graphene geometries from transversely stretched to longitudinally stretched are conveniently constructed by varying the spatial arrangement of three coupling beams, and the corresponding diffraction patterns are implemented theoretically and experimentally to map these distorted geometric structures. Moreover, the distribution of lattice sites intensity in photonic graphene is further dynamically adjusted by two-photon detuning and the coupling beams power. This work paves the way for further investigation of light transport and graphene dynamics.     

Semi-Preparative Scale Separation of Emodin from Plant Extract by Using Molecularly Imprinted Polymer as Stationary Phase

In this work, a core–shell molecularly imprinted polymer (MIP) was synthesized through sol–gel coating procedure by using silica beads, emodin, 3-aminopropyltriethoxysilane, tetraethoxysilane and tetrahydrofuran as supporting matrix, template, functional monomer, cross-linker and solvent, respectively. The selective recognition property for emodin and its analogues (physcion and aloe emodin) of the resultant MIP was evaluated in a chromatographic column for high-performance liquid chromatography (HPLC). The retention time and imprinted factor of MIP column for emodin, physcion and aloe emodin were 5.11, 0.63, 0.69 min and 4.69, 0.75, 1.38, respectively. It showed that the MIP beads had a good binding ability for emodin. Finally, one-step separation of emodin from alcohol extract of Rheum palmatum L. at semi-preparative scale was achieved and 380 mg of emodin was collected in 5 days. The product was characterized by mass spectrometry and HPLC and its purity was 95 %.     

一种新型液晶环氧树脂的合成表征与固化研究

首次合成了一种不对称联苯和芳香酯型液晶环氧树脂4"-环氧丙氧基苯甲酸-4-环氧丙氧基联苯-4'-酯(EBEPC),利用FT-IR、1H NMR、DSC和POM对其结构和性能进行了表征.结果表明,EBEPC在190℃时可形成明显的向列相液晶.对其同普通固化剂DDM体系的固化反应过程、固化动力学进行了研究,与普通环氧树脂E-51/DDM体系比较,液晶环氧树脂EBEPC体系具有较低的固化反应温度,且表观话化能Ea(54.5kJ/mol)较E-51/DDM体系(60.7kJ/mol)低,EBEPC体系具有更高的反应活性.