Surface-assisted one-dimensional self-assembly of a perylene based semiconductor molecule

Chloroform-vapor annealing of thin films of propoxyethyl perylene tetracarboxylic diimide (PE-PTCDI, an n-type semiconductor) deposited on glass or mica leads to formation of well-defined one-dimensional self-assemblies (e.g. nanobelts), which show optically uniaxial properties as demonstrated by the linearly polarized emission.     

Nonlinear Goos-Hänchen shifts due to surface polariton resonance in Kretschmann configuration with a Kerr-type substrate

As the surface polaritons are excited in Kretschmann configuration with a Kerr-type substrate, the nonlinear Goos-Hänchen (GH) shifts exhibit the optically hysteretic response to the intensity of incident light. For thicker metal films, the GH shifts become very sensitive to the intensity of incident light and the angle of incidence.     

Nonlinear optical properties of Cu nanoclusters by ion implantation in silicate glass

Metal nanocluster composite glass prepared by 180 keV Cu ions into silica with dose of 1 × 10¹⁷ ions/cm² has been studied. The microstructural properties of the nanoclusters were analysed by optical absorption spectra and transmission electron microscopy (TEM). Third-order nonlinear optical properties of the nanoclusters were measured at 1064 nm and 532 nm excitations using Z-scan technique. The nonlinear refraction index, nonlinear absorption coefficient, and the real and imaginary parts of the third-order nonlinear susceptibility were deduced. The mechanisms responsible for the nonlinear response were discussed. Absolute third-order nonlinear susceptibility χ⁽³⁾ of this kind of sample was determined to be 2.1 × 10⁻⁷ esu at 532 nm and 1.2 × 10⁻⁷ esu at 1064 nm, respectively.     

Bias dependence of apparent layer thickness and Moiré pattern on NaCl/Cu(001)

Bias-dependent features of the insulating NaCl layer grown on Cu(001) have been investigated by scanning tunneling microscopy/spectroscopy (STM/STS). The apparent layer thickness of the NaCl film is variable at bias voltages ranging from 2.8 to 3.2 V as well as from 4.0 to 5.0 V, and the Moiré pattern induced by NaCl–Cu lattice mismatch also shows bias dependence. The z–V (dz/dV–V) curves and dI/dV mapping measurements reveal that the resonant tunneling between the image potential states (IPSs) on Cu(001) and the Fermi level of the STM tip leads to drastic variations of these features.     

Measurement of group-velocity dispersion of Bloch modes in photonic-crystal-fiber rocking filters

We use low-coherence interferometry to measure the group-velocity dispersion (GVD) of the fast and slow Bloch modes of structural rocking filters, produced by twisting a highly birefringent photonic crystal fiber to and fro while scanning a focused CO(2) laser beam along it. The GVD curves in the vicinity of the resonant wavelength differ dramatically from those of the unperturbed fiber, suggesting that rocking filters could be used in the optimization of, e.g., four-wave mixing and supercontinuum generation. Excellent agreement is obtained between theory and experiment.     

Quantile regression for linear models with autoregressive errors using EM algorithm

In this paper, we consider the quantile linear regression models with autoregressive errors. By incorporating the expectation–maximization algorithm into the considered model, the iterative weighted least square estimators for quantile regression parameters and autoregressive parameters are derived. Finally, the proposed procedure is illustrated by simulations and a real data example.     

液体冷媒融霜系统回液时间的实验研究

对液体冷媒融霜系统的回液时间进行实验研究。在保温体温度-15℃工况下分别对回液时间7s、27s、25s、30s、40s、50s进行实验,记录并分析被融霜蒸发器融霜前和回液时间内压缩机吸气口的温度和压力变化,相机拍摄制冷压缩机吸气口和机身的结霜状况。实验表明:回液时间7s时,压缩机吸气过潮,回液时间在27s左右可以避免压缩机吸气过潮,确保系统安全正常的运行,大于27s被融霜蒸发器恢复制冷时间过长将影响库房温度的稳定并降低制冷系统的效率。     

小型冷库液体冷媒融霜系统的研究

研究了液体冷媒融霜系统应用于小型冷库制冷系统的性能;介绍了液体冷媒融霜原理和控制操作过程、液体冷媒融霜实验的装置和方法;对实验结果进行了分析;重点通过库温变化、蒸发器进出口温度压力变化、过冷度对系统的影响、系统COP几个方面,研究了液体冷媒融霜应用于小型冷库制冷系统的性能。     

Nonlinear Goos–Hänchen shifts of reflected light from inhomogeneous Kerr-like slabs

We investigate the Goos–Hänchen (GH) shifts of reflected light from Kerr-like slabs, whose permittivities are inhomogeneous in space as well as light intensity dependent. The GH shifts exhibit bistable, multivalued properties or a more complicated hysteretic response to the input light intensity, and the different spatial dependences of the permittivity have a great effect on the hysteretic response. The bistable or multivalued GH shifts can be modulated by various parameters, such as the angle of incidence and the thickness of slab.     

Cations Controlling the Chiral Assembly of Luminescent Atomically Precise Copper(I) Clusters

Chiral assembly and asymmetric synthesis are critically important for the generation of chiral metal clusters with chiroptical activities. Here, a racemic mixture of [K(CH₃OH)₂(18‐crown‐6)]⁺[Cu₅(S^tBu)₆]^? ( 1?CH₃OH ) in the chiral space group was prepared, in which the chiral red‐emissive anionic [Cu₅(S^tBu)₆]^? cluster was arranged along a twofold screw axis. Interestingly, the release of the coordinated CH₃OH of the cationic units turned the chiral 1?CH₃OH crystal into a mesomeric crystal [K(18‐crown‐6)]⁺[Cu₅(S^tBu)₆]^? ( 1 ), which has a centrosymmetric space group, by adding symmetry elements of glide and mirror planes through both disordered [Cu₅(S^tBu)₆]^? units. The switchable chiral/achiral rearrangement of [Cu₅(S^tBu)₆]^? clusters along with the capture/release of CH₃OH were concomitant with an intense increase/decrease in luminescence. We also used cationic chiral amino alcohols to induce the chiral assembly of a pair of enantiomers, [d /l ‐valinol(18‐crown‐6)]⁺[Cu₅(S^tBu)₆]^? ( d /l ‐Cu_5V ), which display impressive circularly polarized luminescence (CPL) in contrast to the CPL‐silent racemic mixture of 1?CH₃OH and mesomeric 1 .