Luminescent Property of a Supramolecular Silver(I)‐Thiolate Complex Based on Secondary Ag‐S Interactions and Hydrogen Bonds

The supramolecular silver(I)‐thiolate complex [Ag(μ₂‐SC₄N₂H₄)₂(SCN)]_n has been prepared from the reaction of AgSCN and pyrimidine‐2‐thiol in DMF. X‐ray diffraction analysis shows that the supramolecular structure exhibits one‐dimensional chain through the secondary Ag‐S interactions and the chains are further linked by strong hydrogen bonds to form a three dimensional network. The luminescence effect from the silver‐centered state of S→Ag LMCT in solid state is different from that in solution due to the secondary Ag‐S interactions.     

A Bulk Acoustic Wave Viscosity Sensor for Determination of Lysozyme Based on Lysis of Micrococcus Lysodeikeicus

 A method for determination of lysozyme with a Bulk Acoustic Wave (BAW) viscosity sensor is presented. It is based on the bacteriolytic action of lysozyme on Micrococcus lysodeikeicus (M. lysodeikeicus) and the response of the sensor to the viscosity and density change of this process. There was a good correlation between the frequency shift and the concentration of lysozyme in the range 10–100 μg/ml. The content of lysozyme in human saliva was determined by this method and the results obtained were in good agreement with those from the conventional turbidimetric method. This method has an advantage over the conventional turbidimetric method in that the amount of sample needed is smaller, the procedure is simpler and the concentration range of the bacterium suspension which can be used in the detection was extended. Received September 11, 1998. Revision March 15, 1999.     

氮化镓外延单晶中束缚激子辐射复合的偏振特性

研究发现,氮化镓外延单晶中束缚于中性施主中心和受主中心上的束缚激子BED°和BEA°的复合发光,具有偏振特性。这种偏振特性,会随激发光的强度发生变化。当激发光的强度在104W/cm2和106W/cm2间变化时,偏振度首先以二次方的规律随激发光强的增强而增加,而后超于饱和。本文首先用单轴晶体中介电函数的各向异性解释了荧光固有偏振度的起因,继而采用束缚激子间相互作用的电偶极子模型解释了荧光偏振度随激发光光强的变化规律。     

热处理和紫外辐射对DNA影响的拉曼光谱研究

检测了鲕鱼精ＤＮＡ纤维和经过４０℃，９１℃，２００℃加热处理的拉曼光谱。研究结果表明，在熔融温度以下热处理对ＤＮＡ构象的影响是轻微的，在熔融温度以上则随温度的升高，对ＤＮＡ分子结构的影响有破坏也逐渐加剧，首先受影响的是腺嘌呤和脱氧核糖。     

Analysis of the Structure of Low-Lying States of Four-Boson Systems Based on Symmetry

The structure of inherent nodal surfaces of four-boson systems has been investigated. The most probable structures for each low-lying state have been found. A number of predictions on the structures of individual states and on the systematics of the spectra have been found. Received July 18, 1996; revised March 15, 1997; accepted in final form September 30, 1997     

球型平移网络逼近周期函数

研究了球型平移网络对周期函数的逼近问题．文章首先将基函数eimx分别表示成为两种球型平移网络．进一步,将有关多重Fourier级数的Bochner-Riesz平均表示成为球型平移网络的形式．在此基础上构造出了两类球型平移网络序列,并借助于有关Bochner-Riesz平均对Lp空间中函数的逼近结果给出了这两类球型平移网络序列在Lp空间中的逼近阶．     

吸收式热泵降膜吸收过程传热传质理论分析及实验关联

本文对吸收式热泵的降膜吸收过程中动量、能量及质量传递进行了较全面的理论分析，建立了变膜厚降膜吸收数学模型，揭示了吸收过程中热量、动量、质量传递过程间的相互作用关系并提出以ＰＥ数为核心的凝结式降膜吸收理论。依据该理论，成功地对降膜吸收过程传热实验数据进行关联，获得了实用传热计算的无因次准则公式。     

A study of irradiation in the treatment of wastewater

A grafting copolymer of starch and acrylamide was prepared by ⁶⁰Co-γ pre-irradiation. After purification, the copolymer was modified by a cationic reaction to form a cationic copolymer. The structure of the cationic copolymer was identified by IR and NMR spectroscopy. Using the industrial and sanitary municipal wastewater from the Factory of Wastewater Treatment of Gaobeidian in Beijing as the study sample, three-treatment methods: flocculation deposition, flocculation deposition combined with γ irradiation and the direct irradiation were carried out. COD was applied to evaluate the treatment effect. The preliminary results show that the method of flocculation deposition combined with γ irradiation was effective than the other two.     

Hyperspherical approach to three-electron atomic systems

A computational procedure for carrying out calculations on three-electron atomic systems in hyperspherical coordinates is presented. By adopting an adiabatic approximation, the solution of the Schrödinger equation at a fixed hyperradius is reduced to the solution of a set of coupled partial differential equations involving the two hyperangles. The derivation of such a set of coupled equations is explicitly illustrated.