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131.
Two novel poly(amidoamine) (PAMAM) dendrimers, comprising rhodamine B unit in the core and 1-phenyl-3-methyl-5-pyrazolone unit at the periphery, have been synthesized and characterized. Both dendrimers displayed high selectivity and sensitivity towards Cr3+ ion. As considering the potential of being applied as fluorescent sensors for Cr3+ ion, we studied the complexes formed between the dendrimers and Cr3+ ion. Different PAMAM dendrimers had different recognition mechanism towards Cr3+ ion. For dendrimer G2, the recognition of Cr3+ was mainly due to the ring-opening of spirolactam. However, it significantly depended on the simultaneous effect of ring-opening of spirolactam and photoinduced electron transfer (PET) in the case of dendrimer G3. 相似文献
132.
In this paper, we investigate an Al2O3/HfSiO stack as the blocking layer of a metal-oxide-nitride-oxide-silicon-type (MONOS) memory capacitor. Compared with a memory capacitor with a single HfSiO layer as the blocking layer or an Al2O3/HfO2 stack as the blocking layer, the sample with the Al2O3/HfSiO stack as the blocking layer shows high program/erase (P/E) speed and good data retention characteristics. These improved performances can be explained by energy band engineering. The experimental results demonstrate that the memory device with an Al2O3/HfSiO stack as the blocking layer has great potential for further high-performance nonvolatile memory applications. 相似文献
133.
近红外光谱法预测粗皮桉木材气干密度的影响因素分析 总被引:1,自引:0,他引:1
采用近红外光谱分析技术,对粗皮桉木材气干密度校正模型的影响因素进行比较研究.使用直接测量法测量了粗皮桉木材的气干密度,并用近红外光谱仪采集试样的近红外漫反射光谱,对不同切面、厚度、含水率和粗糙度的粗皮桉木材试样的原始光谱进行二阶导数预处理并选择一定光谱段建立回归模型.以50~140个试样作为校正集建立木材气干密度的偏最... 相似文献
134.
采用分子束外延技术生长了两个叠层结构的双色量子阱红外探测器结构,并经过光刻和湿法刻蚀制作成两端结构的量子阱红外探测器单元器件. 通过改变量子阱势垒高度,势阱宽度,掺杂浓度,重复周期数等器件参数,可以使总电压在两个叠层之间产生适当的分布,从而使器件表现出不同的电压响应特点. 光电流谱测量显示,器件1随着外加偏置电压可实现对于中波大气红外窗口(3—5 μm)和长波大气红外窗口(8—12 μm)红外响应的切换,器件2在不同的偏置电压下可以对这两个波段同时做出响应. 本文探讨了两端叠层结构量子阱红外探测器的工作原
关键词:
电压调制
同时响应
量子阱红外探测器
双波段 相似文献
135.
Recent advances in theoretical models of respiratory mechanics 总被引:1,自引:0,他引:1
As an important branch of biomedical engineering, respiratory mechanics helps to understand the physiology of the respiratory system and provides fundamental data for developing such clinical technologies as ventilators. To solve different clinical problems, researchers have developed numerous models at various scales that describe biological and mechanical properties of the respiratory system. During the past decade, benefiting from the continuous accumulation of clinical data and the dramatic progress of biomedical technologies (e.g. biomedical imaging), the theoretical modeling of respiratory mechanics has made remarkable progress regarding the macroscopic properties of the respiratory process, complexities of the respiratory system, gas exchange within the lungs, and the coupling interaction between lung and heart. The present paper reviews the advances in the above fields and proposes potential future projects. 相似文献
136.
Lu Han Yan-Ru Ma Lai-Chen Chen Shu-Min Huo Tao-Run Qiu Rong-Hua Zeng Qun-Hui Meng Yi-Fan Luo 《Journal of chemical crystallography》2011,41(4):596-600
Abstract
A new 4d–4f coordination polymer, [AgGd(pyzc)2(ox)·H2O)] (1) [pyzc = Pyrazine-2-carboxylate, ox = oxalate] has been successfully synthesized under hydrothermal conditions and structurally determined by single-crystal X-ray diffraction, and characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis and power X-ray diffraction. Single-crystal X-ray analysis reveals that it crystallizes in the monoclinic space group P2 1 /c with a = 10.0746(1) ?, b = 18.642(1) ?, c = 8.0525(2) ?, β = 112.470(1)°, Mr = 617.34, Z = 4, V = 1505.6(2) ?3, μ = 5.732, F(000) = 1164. The Gd(III) ion is nine-coordinated by two O-donors and two N-donors of two different chelating pyzc ligands, four O-donors of two different chelating oxalate ligands, and one O-donor of another carboxylate group of one pyzc ligand. The compound represents a 3D microporous polymeric network constructed by gadolinium–oxalate chains and Ag-pyzc subunits. 相似文献137.
Congde Huo Chougu SunDongcheng Hu Xiaodong JiaXiaolan Xu Zhongli Liu 《Tetrahedron letters》2011,52(51):7008-7010
The reaction of ethyl diazoacetate with aryl imines can be initiated by persistent cation radical salt tris(4-bromophenyl)aminium hexachloroantimonate, giving exclusively cis-aziridine carboxylates. 相似文献
138.
Xiaodong Jia Chang Qing Congde Huo Fangfang Peng Xicun Wang 《Tetrahedron letters》2012,53(52):7140-7142
A domino process between iminoethyl glyoxylate and N-vinylamides was achieved under the catalytic radical cation salt induced conditions, producing a series of quinoline-2-carboxylates. N-Vinylamides were involved as an acetylene equivalent. A possible mechanism was proposed to rationalize the formation of the products. 相似文献
139.
Synthesis and Photophysics of Novel Soluble Polymeric Zn Metal Complex Based on Bis(8-hydroxyquinoline) Groups with Benzene Unit 总被引:1,自引:0,他引:1
A novel ligand: 2,2′‐(1,3‐phenylenedivinylene)bis‐8‐hydroxyquinoline (m‐B8QPH) ( 4 ) and the corresponding polymeric metal complex Zn ( m‐B8QPH ) ( 5 ) were designed and synthesized in a convenient way. The luminescence properties of the compounds Zn ( m‐B8QPH ) ( 5 ) and Zn(p‐B8QPH) ( 9 ) were investigated by UV‐vis and fluorescence spectra in DMF at room temperature. The experimental results showed that the polymeric complexes 5 and 9 emitted yellow luminescence at 578 and 554 nm in DMF solution. The polymeric complex 5 has demonstrated good solubility in common organic solvents and good thermal stability with high Tg: 261°C. Furthermore, the molecular interactions of 5 with fullerene (C60) and fulleropyrrolidine containing 3,5‐bis(trifluoromethyl)benzene ( 11 ) were also investigated, which indicated the metal dye 5 can be used as new fluorescent probe. 相似文献
140.
Dipl.-Ing. Y. Huo 《Continuum Mechanics and Thermodynamics》1991,3(2):95-108
Iron has ab.c.c, structure below 1183GK and above 1670GK In between it has anf.e.c, structure. In this paper the free enthalpy of ab.e.c, lattice and af.c.c lattice is calculated from an interatomic potential of the Morse type. The parameters of the Morse potential are considered as functions of temperature and their values are determined from macroscopic measurements of the lattice constant, the enthalpy and the entropy. The calculated free enthalpies exhibit intersections that correspond to the observed phase transitions. The intersections occur at temperatures which are close to the observed transition temperatures. 相似文献