首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2023篇
  免费   242篇
  国内免费   212篇
化学   1222篇
晶体学   33篇
力学   92篇
综合类   43篇
数学   198篇
物理学   889篇
  2024年   8篇
  2023年   37篇
  2022年   68篇
  2021年   61篇
  2020年   58篇
  2019年   83篇
  2018年   75篇
  2017年   49篇
  2016年   77篇
  2015年   66篇
  2014年   79篇
  2013年   109篇
  2012年   153篇
  2011年   146篇
  2010年   101篇
  2009年   114篇
  2008年   108篇
  2007年   93篇
  2006年   94篇
  2005年   111篇
  2004年   94篇
  2003年   73篇
  2002年   65篇
  2001年   93篇
  2000年   48篇
  1999年   53篇
  1998年   51篇
  1997年   40篇
  1996年   33篇
  1995年   36篇
  1994年   25篇
  1993年   23篇
  1992年   16篇
  1991年   16篇
  1990年   33篇
  1989年   17篇
  1988年   10篇
  1987年   8篇
  1986年   19篇
  1985年   8篇
  1984年   3篇
  1983年   3篇
  1981年   2篇
  1979年   4篇
  1978年   4篇
  1977年   2篇
  1976年   1篇
  1975年   1篇
  1974年   3篇
  1973年   1篇
排序方式: 共有2477条查询结果,搜索用时 15 毫秒
11.
In the strange metal phase of the high-Tc cuprates, it is challenging to explain the linear temperature dependence of the in-plane resistivity and the quadratic temperature dependence of the inverse Hall angle. In this paper, we investigate the temperature dependence of the in-plane resistivity and inverse Hall angle in the nonlinear electrodynamics holographic model developed in our recent work. Maxwell electrodynamics and Born-Infeld electrodynamics are considered. Both cases support a wide spectrum of temperature scalings in parameter space. For Maxwell electrodynamics, the T-linear in-plane resistivity generally dominates at low temperatures and survives into higher temperatures in a narrow strip-like manner. Meanwhile, the T-quadratic inverse Hall angle dominates at high temperatures and extends down to lower temperatures. The overlap between the T-linear in-plane resistivity and the T-quadratic inverse Hall angle, if occurs, would generally present in the intermediate temperate regime. The Born-Infeld case with a 0 is quite similar to the Maxwell case. For the Born-Infeld case with a 0, there can be a constraint on the charge density and magnetic field. Moreover, the overlap can occur for strong charge density.  相似文献   
12.
By swapping the entanglement of genuine four-particle entangled states, we propose a bidirectional quantum secure communication protocol. The biggest merit of this protocol is that the information leakage does not exist. In addition, the ideas of the ``two-step" transmission and the block transmission are employed in this protocol. In order to analyze the security of the second sequence transmission, decoy states are used.  相似文献   
13.
This paper presents a nonmonotone inexact Newton-type method for the extended linear complementarity problem (ELCP). We first reformulate the optimization system of the ELCP problem into a system of smoothed equations. Then we solve this system by a nonmonotone inexact Newton-type algorithm. The global convergence is obtained and numerical tests for some classes of ELCP include linear complementarity, horizontal linear complementarity, and generalized linear complementarity problems are also given to show the e?ciency of the proposed algorithm.  相似文献   
14.
分析归纳了国际市场营销管理与信息的特征,把系统目标分解为三级,依此提出的国际市场营销管理与决策信息系统结构模式,充分考虑了计算机在企业管理中应用的优势与特点,同时又考虑到国情,便于企业开发实施。  相似文献   
15.
B值随机元阵列加权和的收敛性与大数定律   总被引:6,自引:0,他引:6  
令{Xni,1≤i≤kn↑∞,n≥1}为B值随机元阵列,{ani,1≤i≤kn,n≥1}为实数阵列.讨论加权和Sn=kni=1aniXni,n≥1的收敛性.在条件supn,iP(Xni>x)=0(x-r)下给出了一些收敛性结果(1≤r<p≤2),同时用这种收敛性刻划了Banach空间的p型性质  相似文献   
16.
Photoactivatable analogues 4-6 of cholesterol (1), having their cross-linking site in the ring D sterol region, have been synthesized starting from bromotetralone 14 via enantioselective Robinson annulation to enone 13 and Suzuki carbonylative coupling to the appropriate phenylboronic acid. Each of 4-6 was shown to substitute successfully for 1 in an assay of apo A-I-induced cellular cholesterol efflux, indicating that these analogues equilibrated with 1 in all major cellular pools.  相似文献   
17.
Many chiral pesticides exhibit enantioselectivity in biotransformation and ecotoxicity in the environment. A significant class of chiral pesticides is imidazolinone herbicides, of which enantioselectivity has not been well studied. Development of efficient chiral separation methods is the first step for allowing characterization of enantioselectivity in environmental processes. In this study, we attempted to resolve enantiomers of imidazolinone herbicides using reversed-phase and normal-phase high-performance liquid chromatography with polysaccharide-type chiral columns. Enantiomers of imazethapyr, imazaquin, and imazamox were separated on a Chiralcel OD-R column using 50mM phosphate buffer-acetonitrile as mobile phase. Enantiomers of imazapyr, imazapic, imazethapyr, imazamox and imazaquin were resolved on a Chiralcel OJ column using n-hexane (0.1% trifluoroacetic acid)-alcohol as mobile phase. The enantiomers of five methyl derivatives of imidazolinone herbicides were also resolved on the Chiralcel OJ column. The Deltak' values revealed a structure-enantioselectivity relationship for the separation behaviors of the enantiomers on the OJ column. The described method was successfully applied for chiral analysis of two imidazolinone herbicides (imazapyr and imazaquin) in spiked soil samples.  相似文献   
18.
张军  甘志华 《高分子科学》2015,33(12):1640-1649
A new series of cellulose-graft-poly(N-isopropylacrylamide)(cellulose-g-PNIPAM) copolymers were prepared by atom transfer radical polymerization(ATRP) of N-isopropylacrylamide monomers from a cellulose-based macro-initiator, which was homogeneously synthesized in an ionic liquid 1-allyl-3-methylimidazolium chloride(Amim Cl). The composition of cellulose-g-PNIPAM copolymers could be adjusted by altering the feeding ratio and reaction time. The resultant copolymers with relatively high content of PNIPAM segments(molar substitution of PNIPAM ? 18.3) were soluble in water at room temperature. Aqueous solutions of cellulose-g-PNIPAM copolymers exhibited clear temperature-sensitive behavior, and their sol-to-gel phase transition properties were investigated by dynamic light scattering(DLS) and UV measurements. Compared with pure PNIPAM, the cellulose-g-PNIPAM copolymers possessed higher lower critical solution temperatures(LCST) in a range from 36.9 ?C to 40.8 ?C, which are close to normal human body temperature, and could be tuned by adjusting the content of PNIPAM segments in copolymers. Spherical structure of cellulose-g-PNIPAM copolymers formed at temperatures above LCST and its morphology was observed by TEM and SEM. These novel cellulose-g-PNIPAM copolymers may be attractive substrates for some biomedical applications, such as drug release and tissue engineering.  相似文献   
19.
(17)O-(1)H double resonance NMR spectroscopy was used to study the local structure of zeolite H-Mordenite. Different contact times were used in cross-polarization magic angle spinning (CPMAS) NMR, CP rotational-echo double resonance (CP-REDOR) NMR, and heteronuclear correlation (HETCOR) NMR spectroscopy to distinguish between Br?nsted acid sites with different O-H distances. The accessibility of the various Br?nsted acid sites was quantified by adsorbing the basic probe molecule trimethylphosphine in known amounts. On the basis of these experiments, locations of different Br?nsted acid sites in H-Mordenite (H-MOR) were proposed. The use of (17)O chemical shift correlations to help assign sites is discussed.  相似文献   
20.
We report the synthesis of Zn(x)Cd(1-x)S@ZnO nanorod arrays via a facile two-step process and the implementation of these core-shell nanorods as an environmental friendly and recyclable photocatalyst for methyl orange degradation. The band gap of Zn(x)Cd(1-x)S@ZnO core-shell nanorods can be readily tunable by adjusting the ratio of Zn/Cd during the synthesis. These Zn(x)Cd(1-x)S@ZnO core-shell nanorods exhibit a high photocatalytic activity and good stability in the degradation of the methyl orange. Moreover, these films grown on FTO substrates make the collection and recycle of the photocatalyst easier. These findings may open new opportunities for the design of effective, stable, and easy-recyclable photocatalytic materials.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号