The photolysis reactions of three compounds commonly used as a sunscreen agents, Parsol 1789 (1-[4-(1,1-dimethylethyl)phenyl]-3-(4-methoxyphenyl)-1,3- propanedione), Oxybenzone ((2-hydroxy-4-methoxyphenyl)phenyl-methanone) and Padimate O (2-ethylhexyl-4-(dimethylamino)benzoate), were investigated to provide a chemical background to aid in the understanding of the photosensitization of the sunscreen agents. Photolysis was carried out in cyclohexane for 70–140 h using a mercury vapor lamp (450W) without excluding oxygen.
Irradation of Parsol 1789 in cyclohexane yielded tert-butylbenzene, p-tert-butylbenzoic acid and p-methoxybenzoic acid; products obtained from the combination of the sunscreen with the solvent included the cyclohexyl esters of p-methoxybenzoic acid, p-tert-butylbenzoic acid and methanoic acid; products obtained from the solvent included cyclohexanol, cyclohexanone and dicyclohexyl ether.
Irradiation of Oxybenzone in the cyclohexane for 100 h produced no detectable products by either gas or liquid chromatographic analysis. Oxybenzone was recovered unchanged and no products were observed from the photoinitiated reaction of oxygen with the solvent.
Irradiation of Padimate O in cyclohexane yielded the ethylhexyl esters of p-aminobenzoic acid, p-monomethylaminobenzoic acid and p-dimethylamino (o/m)-methylbenzoic acid, as well as products from the photoinitiated reaction of oxygen with the solvent. 相似文献
The properties of the excitonic luminescence for nanocrystalline ZnO thin films are investigated by using the dependence of excitonic photoluminescence (PL) spectra on temperature. The ZnO thin films are prepared by thermal oxidation of ZnS films prepared by low-pressure metalorganic chemical vapor deposition (LP-MOCVD) technique. The X-ray diffraction (XRD) indicates that ZnO thin films have a polycrystalline hexagonal wurtzite structure with a preferred (0 0 2) orientation. A strong ultraviolet (UV) emission peak at 3.26 eV is observed, while the deep-level emission band is barely observable at room temperature. The strength of the exciton-longitudinal-optical (LO) phonon coupling is deduced from the temperature dependence of the full-width at half-maximum (FWHM) of the fundamental excitonic peak, decrease in exciton-longitudinal-optical (LO) phonon coupling strength is due to the quantum confinement effect. 相似文献
For any self-adjoint realization S of a singular Sturm-Liouville equation on an interval (a,b) with limit-circle endpoints, we construct a family of self-adjoint realizations Sr,r ∈ (0,∞), of this equation on subintervals (ar,br) of (a,b) such that every eigenvalue of S is the limit of a continuous eigenvalue branch of this family. Of particular interest are the cases when at least one endpoint is oscillatory or the leading coefficient function changes sign. In these cases, we show that the index determining each continuous eigenvalue branch has an infinite number of jump discontinuities and give an explicit characterization of these discontinuities. 相似文献
We study the operadic and categorical formulations of (conformal) full field algebras. In particular, we show that a grading-restricted R×R-graded full field algebra is equivalent to an algebra over a partial operad constructed from spheres with punctures and local coordinates. This result is generalized to conformal full field algebras over VL⊗VR, where VL and VR are two vertex operator algebras satisfying certain finiteness and reductivity conditions. We also study the geometry interpretation of conformal full field algebras over VL⊗VR equipped with a nondegenerate invariant bilinear form. By assuming slightly stronger conditions on VL and VR, we show that a conformal full field algebra over VL⊗VR equipped with a nondegenerate invariant bilinear form exactly corresponds to a commutative Frobenius algebra with a trivial twist in the category of VL⊗VR-modules. The so-called diagonal constructions [Y.-Z. Huang, L. Kong, Full field algebras, arXiv: math.QA/0511328] of conformal full field algebras are given in tensor-categorical language. 相似文献
Traditionally spatial transformations such as translations and rotations are formulated in terms of transformations of the entire spatial space. In other words, transformations are taken automatically to be of a global nature. This paper investigates a local approach to spatial transformations; local transformations lead naturally to local observables in quantum mechanics. 相似文献
After the laser was invented in 1960, a phase conjugation mirror has been respected to be the most fantastic one for the laser
resonator composition because it can compensate any distortions of the laser beams occurred by the many inhomogenuities of
the laser media and optical components. Among the many phase conjugation configurations, the stimulated Brillouin scattering
phase conjugation mirror is the most simple one and many researchers have tried to utilize it to develop high power/energy
laser systems. For realizing a high energy/power laser system the thermal problem is the most difficult to solve, and some
researchers suggested a beam combination technique to reduce the thermal load of the big laser media to many small sized ones.
To accomplish the beam combination using stimulated Brillouin scattering phase conjugation mirrors (SBS-PCMs), it is necessary
to lock/control the phases of the SBS-PCMs. And some researchers have developed several ways for it, but they can lock the
phases of a limited number of beams overlapped at the foci less than 5, or lock the phases by back-seeding technique but it
loses the phase conjugation characteristics. For realization of the laser fusion driver, it is necessary to combine more than
10 or 100 beams. And the authors have developed recently a new phase controlling/locking technique which is isolated and independent
totally from other beams and it can be applied to an unlimited number of beams in principle. 相似文献
A nano-surfacing process (NSP) is proposed to directly fabricate three-dimensional (3D) concavo–convex-shaped microstructures such as micro-lens arrays using two-photon polymerization (TPP), a promising technique for fabricating arbitrary 3D highly functional micro-devices. In TPP, commonly utilized methods for fabricating complex 3D microstructures to date are based on a layer-by-layer accumulating technique employing two-dimensional sliced data derived from 3D computer-aided design data. As such, this approach requires much time and effort for precise fabrication. In this work, a novel single-layer exposure method is proposed in order to improve the fabricating efficiency for 3D concavo–convex-shaped microstructures. In the NSP, 3D microstructures are divided into 13 sub-regions horizontally with consideration of the heights. Those sub-regions are then expressed as 13 characteristic colors, after which a multi-voxel matrix (MVM) is composed with the characteristic colors. Voxels with various heights and diameters are generated to construct 3D structures using a MVM scanning method. Some 3D concavo–convex-shaped microstructures were fabricated to estimate the usefulness of the NSP, and the results show that it readily enables the fabrication of single-layered 3D microstructures. PACS 85.40.Hp; 81.16.Nd; 42.82.Cr 相似文献
In weak acidic medium, anticancer antibiotics bleomycin A5 (BLMA5) and bleomycin A2 (BLMA2) can react with halofluorescein dyes such as erythrosin (Ery), eosin Y (EY), eosin B (EB) and rose bengal (RB) by virtue of electrostatic attraction and hydrophobic force to form the ion-association complexes, which can result in the fading reactions of four halofluorescein dyes. The maximum fading wavelengths of these four dyes were located at 527 nm for Ery, 515 nm for EY, 517 nm for EB and 546 nm for RB, respectively. The decrements of absorbance (AA) were directly proportional to the concentrations of bleomycin in a certain range. A new method for the determination of bleomycins anticancer drugs based on fading reactions of halofluorescein dyes has been developed. The method was not only highly sensitive but also simple and rapid. The molar absorptivities (ε) ranged from 1.5 × 10^5 to 7.5 × 10^5 L·mol^-1·cm^-1. It was applied to determination of the bleomycins in human serum, urine and rabbit serum samples. In this work, the spectral properties and the optimum reaction conditions were investigated. The structure of ion-association complexes and the reaction mechanism were discussed. 相似文献