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61.
35Cr25Ni12奥氏体耐热钢中碳化物的电子显微分析 总被引:1,自引:0,他引:1
应用扫描电镜(SEM)和透射电镜(TEM)研究了长期使用前后的35Cr25Ni12奥氏体耐热钢中的碳化物演变行为;该钢固溶时效后的组织由初晶奥氏体及M23C6共晶碳化物组成,奥氏体基体中析出了二次M23C6,二次碳化物总是与基体保持立方-立方取向关系;长期使用(3、5年)后,奥氏体中析出的二次碳化物量明显增加,部分M23C6已转变为M6C,M6C与奥氏体基体以及二次碳化物M23C6保持[001]M6C//[221]A//[221]M23C6孪晶取向关系。 相似文献
62.
报道一种新颖的用于多波长光纤激光器的超结构光纤Bragg光栅(SFBG)梳状滤波器,其突出特点是仅由单个光栅构成、折射率调制和局部啁啾富于变化、反射峰均匀性好、窄带宽和标准的信道间隔.采用基于LP算法的IS光纤光栅设计技术,将整体加窗切趾法改进为各信道独立加窗切趾,成功地设计出所需的SFBG,同时对SFBG的制作技术也进行了探讨.用传输矩阵法分析反射谱、时延曲线和群时延抖动.结果表明,所设计的SFBG满足各项设计指标要求,在DWDM系统中,这种新颖的SFBG可望成为用于多波长光纤激光器的最理想的高性 能梳
关键词:
超结构光纤Bragg光栅
光栅设计
梳状滤波器 相似文献
63.
64.
Wei‐Lie Xiao Jian‐Xin Pu Rui‐Rui Wang Liu‐Meng Yang Xiao‐Li Li Sheng‐Hong Li Rong‐Tao Li Sheng‐Xiong Huang Yong‐Tang Zheng Han‐Dong Sun 《Helvetica chimica acta》2007,90(8):1505-1513
Seven new highly oxygenated nortriterpenoids, rubriflorins D–J ( 1 – 7 ), were isolated from the leaves and stems of Schisandra rubriflora, and their structures were elucidated on the basis of extensive analysis of spectroscopic data. These new compounds feature the opening of ring A compared with related known nortriterpenoids isolated from the genus Schisandra and showed weak activity against HIV‐1. 相似文献
65.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献
66.
Hydroxyapatite coating on porous silicon substrate obtained by precipitation process 总被引:2,自引:0,他引:2
Chen Shaoqiang Zhu Ziqiang Zhu Jianzhong Zhang Jian Shi Yanling Yu Ke Wang Weiming Wang Xiaohua Feng Xiao Luo Laiqiang Shao Li 《Applied Surface Science》2004,230(1-4):418-424
Hydroxyapatite Ca10(PO4)6(OH)2 (HAP) is known as a bioactive and biocompatible material, HAP coatings were used to improve the biocompatible of substrate by many researcher, In this work, HAP thin films on porous silicon (PS) substrates have been prepared by aqueous precipitation method with rapid thermal annealing (RTA) processes. The HAP films had been prepared under the annealing temperature ranging from 300 to 1000 °C. By the measurement of X-ray diffraction (XRD), it was found that for the crystallinity optimization, the heat-treatment at 850–950 °C for 1 h would be favorable. Atomic force microscopy (AFM) and scanning electron microscope (SEM) measurements reveal a dense and smooth surface of the HAP film, and tightly adherence of the coating on porous silicon substrate after sintered. Thus, by this method, porous silicon could be increased its bioactivity and so that could be used in the biomedical area. 相似文献
67.
Cheng Lu ZHANG Xiao Lei ZHU Ying Ge MA Li Wei ZOU 《中国化学快报》2006,17(2):163-164
12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one 9 was isolated from the twigs ofCroton salutaris1. Many diterpenes exhibit significant bioactivities, such as antibac-terial and antitumour and 9 has a rare structure. In order to study the relationshipb… 相似文献
68.
69.
Xiaoqing Liu Chuncheng Li Dong Zhang Yaonan Xiao 《Journal of Polymer Science.Polymer Physics》2006,44(6):900-913
This article investigated the melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) (PBS) and its copolyester (PBSR) modified with rosin maleopimaric acid anhydride, using wide‐angle X‐ray diffraction, differential scanning calorimeter (DSC), and polarized optical microscope. Subsequent DSC scans of isothermally crystallized PBS and PBSR exhibited two melting endotherms, respectively, which was due to the melt‐recrystallization process occurring during the DSC scans. The equilibrium melting point of PBSR (125.9 °C) was lower than that of PBS (139 °C). The commonly used Avrami equation was used to describe the isothermal crystallization kinetics. For nonisothermal crystallization studies, the model combining Avrami equation and Ozawa equation was employed. The result showed a consistent trend in the crystallization process. The crystallization rate was decreased, the perfection of crystals was decreased, the recrystallization was reduced, and the spherulitic morphologies were changed when the huge hydrogenated phenanthrene ring was added into the chain of PBS. The activation energy (ΔE) for the isothermal crystallization process determined by Arrhenius method was 255.9 kJ/mol for PBS and 345.7 kJ/mol for PBSR. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 900–913, 2006 相似文献
70.
Zhicheng Xiao Ying Li Dongling Ma Linda S. Schadler Yvonne A. Akpalu 《Journal of Polymer Science.Polymer Physics》2006,44(7):1084-1095
Small‐angle light scattering (SALS) measurements were used to study the structure of titanium dioxide (TiO2)/low‐density polyethylene (LDPE) nanocomposites. The results showed that the scattering from LDPE crystalline structures and the scattering from TiO2 nanoparticles can be resolved and separated. It is shown that the independent effects of crystallization conditions and the presence of nanoparticle aggregates on the spherulitic structure of the LDPE matrix can be determined by analyzing the scattering patterns using the methods proposed. From the SALS results, we conclude that the nanoparticle surface chemistry affects both nucleation of spherulites and their structure particularly under rapid cooling conditions. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1084–1095, 2006 相似文献