LaCoO3中自旋态转变现象的超声研究

测量了LaCoO₃单相多晶样品的纵波与横波超声声速和衰减随温度的变化关系, 在材料的自 旋态转变温度附近（≈90K），纵波声速出现明显的软化并伴随一个尖锐的衰减峰，但是在 横波的测量中却没有出现类似的超声异常，分析认为LaCoO₃在90K附近的自旋态 转变是由于Co³⁺离子是从低自旋态(LS,t⁶_2ge⁰ _g)转变到中等自旋态(IS,t⁵ _2ge¹_g )，而不是高等自旋态(HS,t⁴_2ge²_g).随着温度的升高，在 200K附近纵波和横波测量上都观察到一个伴随着微小声速软化的宽大的衰减峰，这可能是随 机分布的IS态Co³⁺离子的Jahn-Teller效应导致的局域晶格扭曲所造成的. 关键词： 超声声速与衰减 自旋态转变 Jahn-Teller效应     

ZnO量子点的制备及其在白光LED中的应用

利用湿化学方法制备合成Zn O量子点,通过改变合成条件(反应时间、反应物浓度、反应温度)对量子点的尺寸及发光性能进行调控。利用透射电子显微镜、吸收光谱、荧光光谱等表征手段,探讨了合成条件对Zn O量子点光学性质的影响,并优化出适用于构建白光LED器件的最佳合成条件。研究结果表明,在反应温度为20℃、反应时间为3 h、前驱体Zn(OAc)_2和Li OH反应浓度比为2∶1时获得的Zn O量子点较为稳定,并在紫外光激发下发出明亮的黄绿色光。在此基础上,以该Zn O量子点为有源层、p-Ga N∶Mg基片为空穴注入层、非晶Al_2O_3薄膜为电子阻挡层构造了p-i-n型异质结LED,在正向注入电流为5 m A时,获得了来自于器件的白光发射,其色坐标为(0.28,0.30),色温为9 424 K。     

Sensor resolution enhancement for remote imaging by synthesizing mask-based camera array images

In this paper, we propose an architecture based on camera array with masks to enhance the sensor resolution of remote imaging system. The sensor resolution is enhanced by multiplexing the sensor images of each camera, in which the angular resolution bandwidth is converted using masks to expand the spatial resolution bandwidth. The improvement of the sensor resolution depends on the number of cameras in the array. The theory of improving the sensor resolution is discussed both in Fourier domain and spatial domain. We verify resolution enhancement of the architecture by ray-tracing imaging simulation. A simulation model is built to verify the resolution-enhancing ability of the camera array architecture. From each camera in the array, we get a resolution-limited image. The reconstructed image is synthesized from all the images of the cameras. The post-synthesized image has finer information details compared with the images of each camera. The resolution improvement varies with the object distance. The optimal resolution improvement of the reconstructed image is equal to the total sensor pixels of the camera array.     

On the stability analysis of microscopic traffic car-following model: a case study

The stability analysis of the microscopic traffic car-following model is an important issue. The present paper systematically discusses the local stability and asymptotic stability of the car-following model; meanwhile, the corresponding Lyapunov stability is also proposed from the viewpoint of control. Moreover, taking the full velocity difference (FVD) car-following model as a case, the difference among the three stability analysis approaches and the simulation are conducted. Finally, the results reveal that it can improve the dynamic performance when keep the value of the gain factor k constant and increase the value of sensitivity coefficient of velocity difference λ; and so is it when it keeps the value of a sensitivity coefficient of velocity difference λ constant and increases the value of the gain factor k, while the value of the gain factor k is dominant in this process.     

An AlGaN/GaN HEMT with enhanced breakdown and near-zero breakdown voltage temperature coefficient

An AlGaN/GaN high-electron mobility transistor (HEMT) with a novel source-connected air-bridge field plate (AFP) is experimentally verified. The device features a metal field plate that jumps from the source over the gate region and lands between the gate and drain. When compared to a similar size HEMT device with conventional field plate (CFP) structure, the AFP not only minimizes the parasitic gate to source capacitance, but also exhibits higher OFF-state breakdown voltage and one order of magnitude lower drain leakage current. In a device with a gate to drain distance of 6 μm and a gate length of 0.8 μm, three times higher forward blocking voltage of 375 V was obtained at V_GS=-5 V. In contrast, a similar sized HEMT with CFP can only achieve a breakdown voltage no higher than 125 V using this process, regardless of device dimensions. Moreover, a temperature coefficient of 0 V/K for the breakdown voltage is observed. However, devices without field plate (no FP) and with optimized conventional field plate (CFP) exhibit breakdown voltage temperature coefficients of -0.113 V/K and -0.065 V/K, respectively.     

Optimization of a solar-blind and middle infrared two-colour photodetector using GaN-based bulk material and quantum wells

This paper calculates the wavelengths of the interband transitions as a function of the Al mole fraction of Al_xGa_1-xN bulk material. It is finds that when the Al mole fraction is between 0.456 and 0.639, the wavelengths correspond to the solar-blind (250~nm to 280~nm). The influence of the structure parameters of Al_yGa_1-yN/GaN quantum wells on the wavelength and absorption coefficient of intersubband transitions has been investigated by solving the Schr?dinger and Poisson equations self-consistently. The Al mole fraction of the Al_yGa_1-yN barrier changes from 0.30 to 0.46, meanwhile the width of the well changes from 2.9~nm to 2.2~nm, for maximal intersubband absorption in the window of the air (3~μm <λ <5~μm). The absorption coefficient of the intersubband transition between the ground state and the first excited state decreases with the increase of the wavelength. The results are finally used to discuss the prospects of GaN-based bulk material and quantum wells for a solar-blind and middle infrared two-colour photodetector.     

一种激光外差多普勒玻璃厚度测量方法

提出了一种应用激光外差测量技术结合激光多普勒技术的玻璃厚度测量方法.论述了该方法的理论依据,并结合实际应用介绍了外围硬件电路的设计方法,运用Matlab软件结合FFT技术进行了数值仿真实验,结果表明该方法在测量1~10 mm的平板玻璃时,误差小于1%.     

Theoretical Study on Destruction Mechanism of 2,3,7,8-TCDD by O3 and NO3

In order to improve the destruction effciency of dioxins and also for developing new dioxin control technology, the destruction mechanisms of 2,3,7,8-tetrachlorodihenzo-p-dioxin (2,3,7,8-TCDD) by O₃ and NO₃, were investigated employing quantum chemical calcula-tions. For involved reactions, the microcosmic reaction processes were analyzed and de-picted in detail based on geometry optimizations made by the B3LYP/6-31G(d) method. At the same time, the reaction activation energies were also calculated at the MP2/6-311G(d,p)//B3LYP/6-31G(d) level. Configuration analysis indicated that 2,3,7,8-TCDD could be destroyed by O₃ and NO₃ in two different ways. The destruction of 2,3,7,8-TCDD by O₃ proceeded via the addition of O₃ and the cleavage of C=C while the destruction of 2,3,7,8-TCDD by NO₃ proceeded via the substitution of chlorine by NO₃. Calculated re-sults show that, the activation energy of the destruction reaction of 2,3,7,8-TCDD by NO₃ (267.48 kJ/mol) is much larger than that of the destruction reaction of 2,3,7,8-TCDD by O₃ (51.20 kJ/mol). This indicated that the destruction of 2,3,7,8-TCDD by O₃ is much more effcient than that of 2,3,7,8-TCDD by NO₃. The reason why the activation energy for the destruction reaction of 2,3,7,8-TCDD by NO₃ is so large, is also discussed.     

用CE/SE法对弯曲与分叉河道的溃坝洪水波的数值研究

对作者的二维溃坝洪水波的数学模型进一步推广,得到了一般形式的基于任意四边形网格的时空守恒元和解元方法(简称CE/SE法)的新的格式.CE/SE法从守恒积分型浅水方程出发,设立守恒元和解元,严格保证其物理意义上的守恒律,并且构造思想简单,格式通用性好.首先采用CE/SE法计算等宽矩形河道的溃坝洪水波,并与Stoker解析解进行比较,在此基础上,数值模拟了180度强弯曲河道、45度三支分叉河道的二维溃坝洪水波的演进过程,揭示了溃坝洪水波在弯曲河道中内外两岸速度与水位的变化,在分叉河道中自动进行流量与动量的再分配,在分叉点处形成旋涡,水位变化剧烈等复杂的运动特征,算例结果表明基于任意四边形网格的CE/SE法精度高,稳定性好,该格式对各种不规则几何区域内的溃坝问题具有较强的适应性,对溃坝洪水波的间断具有较高的分辨率.