A theory for grain-size reduction in granular flows of spheres

Summary We derive a kinetic theory for homogeneous granular shear flows of identical spheres in which collisions between particles result in small fractures on their peripheries and, over time, effectively reduce their average diameter. In obtaining statistically averaged constitutive relations for the rates of energy dissipation and mass loss, we employ the integral expression derived by Jenkins and Savage [1983] for the collisional source of a particle property. However, in calculating the stress, we modify their expression for the collisional flux in order to ensure that the stress is symmetric when the particles interact through central forces. The constitutive relations are employed in the balance equations for mass, momentum, and energy in order to predict, for a fixed shear rate and particle number density, the manner in which the solid fraction, granular temperature, and induced stresses vary with time.

---

Zusammenfassung Wir entwickeln eine kinetische Theorie für die homogene Scherströmung von identischen Kugeln, in welcher die Zusammenstösse der Teilchen kleine Risse in ihrer Oberfläche verursachen und sich dadurch ihr mittlerer Durchmesser mit der Zeit verringert. Um die statistisch gemittelten konstitutiven Beziehungen für die Energiedissipations- und Massenverlustraten zu erhalten, verwenden wir den von Jenkins und Savage [1983] hergeleiteten Integralausdruck für die von den Kollisionen verursachte Quellenstärke einer Teilchenzustandsgrösse. Bei der Berechnung der Spannung verwenden wir jedoch einen abgeänderten Ausdruck für den Fluss durch Kollision; dadurch wird sichergestellt, dass der Spannungstensor symmetrisch ist, wenn die Kontaktkraft zwischen den Teilchen normal zur Kontaktebene wirkt. Die konstitutiven Beziehungen werden in die Gleichungen für die Erhaltung von Masse, Impuls und Energie eingesetzt, um zu berechnen, wie sich der Festkörperanteil, die Granulartemperatur und die induzierten Spannungen als Funktion der Zeit verändern; der Geschwindigkeitsgradient und die Anzahl Teilchen pro Volumen sind dabei konstant.

     

Induction of differentiation of human leukemia cells by various combinations of cytokines and low-molecular-weight inducers

To explore agents for differentiation therapy of leukemias, various combinations of cytokines and low-molecular-weight inducers were examined for differentiation-inducing activity toward three kinds of human leukemia-derived cell lines. The strongest differentiation inducing activity on promyelocytic HL60 cells and histiocytic U937 cells was obtained by combining recombinant tumor necrosis factor (rTNF), interferon-gamma (IFN-gamma), retinoic acid (RA), and 1 alpha,25-dihydroxyvitamin D3 (1 alpha,25(OH)2D3). For myeloblastic ML1 cells, the combination of rTNF, IFN-gamma, and RA had the strongest differentiation-inducing activity.     

A lab-scale digital acoustic emission system for source location

Experimental Techniques - A PC-based, fully digital and lab-scale acoustic emission system for 3-D source location was set up. To get good results, a sampling rate higher than the Nyquist frequency...     

A fuzzy simple additive weighting system under group decision-making for facility location selection with objective/subjective attributes

This work presents a new fuzzy multiple attributes decision-making (FMADM) approach, i.e., fuzzy simple additive weighting system (FSAWS), for solving facility location selection problems by using objective/subjective attributes under group decision-making (GDM) conditions. The proposed system integrates fuzzy set theory (FST), the factor rating system (FRS) and simple additive weighting (SAW) to evaluate facility locations alternatives. The FSAWS is applied to deal with both qualitative and quantitative dimensions. The FSAWS process considers the importance of each decision-maker, and the total scores for alternative locations are then derived by homo/heterogeneous group of decision-makers. Finally, a numerical example illustrates the procedure of the proposed FSAWS.     

Synthesis of PMMA‐b‐PBA block copolymer in homogeneous and miniemulsion systems by DPE controlled radical polymerization

In this research, poly(methyl methacrylate)‐b‐poly(butyl acrylate) (PMMA‐b‐PBA) block copolymers were prepared by 1,1‐diphenylethene (DPE) controlled radical polymerization in homogeneous and miniemulsion systems. First, monomer methyl methacrylate (MMA), initiator 2,2′‐azobisisobutyronitrile (AIBN) and a control agent DPE were bulk polymerized to form the DPE‐containing PMMA macroinitiator. Then the DPE‐containing PMMA was heated in the presence of a second monomer BA, the block copolymer was synthesized successfully. The effects of solvent and polymerization methods (homogeneous polymerization or miniemulsion polymerization) on the reaction rate, controlled living character, molecular weight (M_n) and molecular weight distribution (PDI) of polymers throughout the polymerization were studied and discussed. The results showed that, increasing the amounts of solvent reduced the reaction rate and viscosity of the polymerization system. It allowed more activation–deactivation cycles to occur at a given conversion thus better controlled living character and narrower molecular weight distribution of polymers were demonstrated throughout the polymerization. Furthermore, the polymerization carried out in miniemulsion system exhibited higher reaction rate and better controlled living character than those in homogeneous system. It was attributed to the compartmentalization of growing radicals and the enhanced deactivation reaction of DPE controlled radical polymerization in miniemulsified droplets. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4435–4445, 2009     

Self‐assembly of H‐bonded side‐chain and cross‐linking copolymers containing diblock‐copolymeric donors and single/double H‐bonded light‐emitting acceptors

A series of diblock‐copolymers were synthesized through anionic polymerization of styrene and tert‐butyl methacrylate (tBuA) with different monomer ratios, and analogous block‐copolymeric derivatives (PS‐b‐PAA)s with monofunctional carboxylic acid groups were obtained by further hydrolyzation as hydrogen‐bonded (H‐bonded) proton donors. Via H‐bonded interaction, these diblock‐coplymeric donors (PS‐b‐PAA)s were incorporated with luminescent mono‐pyridyl/bis‐pyridyl acceptors to form single/double H‐bonded supramolecules, that is, H‐bonded side‐chain/cross‐linking copolymers, respectively. The supramolecular architectures formed by donor polymers and light‐emitting acceptors were influenced by the ratio of acid blocks in the diblock copolymeric donors and the type of single/double H‐bonded light‐emitting acceptors. Their thermal and luminescent properties can be adjusted by H‐bonds, and more than 100 nm of red‐shifted photoluminescence (PL) emissions were observed, which depend on the degrees of the H‐bonding interactions. Self‐assembled phenomena of amphiphilic dibolck copolymers and their H‐bonded complexes were confirmed by TEM micrographs, and supramolecular microphase separation of spherical micelle‐like morphology was demonstrated to affect the photophysical properties. Polymer light‐emitting diode (PLED) devices containing H‐bonded complexes showed electroluminescence (EL) emissions of 503–560 nm under turn‐on voltages of 7.5–9.0 V, maximum power efficiencies of 0.23–0.37 cd/A (at 100 mA/cm²), and maximum luminances of 318–519 cd/m² (around 25 V). © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4685–4702, 2009     

The effect of F substitution on the magnetic properties of Nd−Fe−B based compounds

Various efforts are currently undertaken to raise the relatively low Curie temperature of the otherwise promising Nd?Fe?B type permanent magnet material. The substitution of Fe by several elements was found to increaseT _c, which, on the other hand, can be accompanied by a reduction of the magnetocrystalline anistropy. In the present paper a systematic Mössbauer study was carried out, using Co, Ni, Al, Si and Ga as substituents. The specific influence of each element upon the magnetic properties is attributed to its preference for entering a certain Fe lattice site. Simple atomic size considerations are proved to be insufficient for explaining the preferred occupation observed experimentally. Obviously the local electronic structure has to be studied more carefully. Finally, the interplay between magnetism and metallurgy (particularly the formation of precipitations), is found to be of some importance.