首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   22725篇
  免费   3624篇
  国内免费   3293篇
化学   16943篇
晶体学   301篇
力学   1245篇
综合类   282篇
数学   2758篇
物理学   8113篇
  2024年   51篇
  2023年   421篇
  2022年   786篇
  2021年   831篇
  2020年   908篇
  2019年   954篇
  2018年   762篇
  2017年   718篇
  2016年   1104篇
  2015年   1140篇
  2014年   1381篇
  2013年   1698篇
  2012年   1988篇
  2011年   2050篇
  2010年   1521篇
  2009年   1474篇
  2008年   1572篇
  2007年   1419篇
  2006年   1317篇
  2005年   1023篇
  2004年   922篇
  2003年   708篇
  2002年   799篇
  2001年   608篇
  2000年   469篇
  1999年   463篇
  1998年   364篇
  1997年   317篇
  1996年   289篇
  1995年   230篇
  1994年   193篇
  1993年   207篇
  1992年   142篇
  1991年   133篇
  1990年   118篇
  1989年   101篇
  1988年   86篇
  1987年   56篇
  1986年   53篇
  1985年   61篇
  1984年   35篇
  1983年   30篇
  1982年   31篇
  1981年   16篇
  1980年   11篇
  1979年   8篇
  1978年   12篇
  1976年   7篇
  1973年   6篇
  1972年   6篇
排序方式: 共有10000条查询结果,搜索用时 20 毫秒
51.
Parity violation effects have been studied at 40 neutron p-wave resonances of the even-even nuclei238U and232Th. Of these 11 show parity violation effects larger than 2 standard deviations, making parity violation a rather common phenomenon. Parity mixing up to 10% has been found. The root-mean squared matrix elements for parity violation derived from these resonances are M=0.58 (+0.50/-0.25) meV for238U, respectively 1.39 (+0.35/-0.38) meV for232Th.  相似文献   
52.
1H chemical shift changes of sodium 4-decyl naphthalene sulfonate (SDNS) at 313 K show that its critical micellar concentration lies between 0.82 and 0.92 mmol/dm3, which is in the same range as that of the previous study at 298 K. The spin–lattice relaxation time, spin–spin relaxation time and two-dimensional nuclear Overhauser enhancement spectroscopy experiments give information about the structure of the SDNS micelle and the dynamics of the molecules in the micelle. The size of the SDNS micelle remains almost unchanged in the temperature range from 298 to 313 K as deduced by analyzing the self-diffusion coefficient. Special arrangement of the naphthyl rings of SDNS in the micelles affects the packing of these hydrophobic chains. The methylene groups of the alkyl chain nearest the naphthalene groups penetrate into the aromatic region, which results in a more tightly packed hydrophobic micellar core than that of sodium dodecyl sulfonate.  相似文献   
53.
54.
A one‐dimensional zinc(II) coordination polymer has been constructed from zinc(II), 4,4′‐biphenyldicarboxylate and pyridine in which each zinc(II) atom is coordinated by two pyridine ligands and two monodentate 4,4′‐biphenyldicarboxylate ligands that define a distorted tetrahedral geometry. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
55.
Triterpenoid Constituents of Huperzia miyoshiana   总被引:1,自引:0,他引:1  
Thirteen triterpenoids, including three new ones, miyoshianois A (1), B (2) and C (3), were isolated from Huperzia miyoshiana. The structures of these new compounds were established as 3-O-dihydroferuloyltohogenol (1), 16-oxo-3β,21β-dihydrox-y-serrat-14-en-24-ferulate (2) and 16-oxo-3a, 21β-dihydroxy-serrat-14-en-24-ferulate (3), respectively, on the basis of their spectroscopic analysis.  相似文献   
56.
57.
A novel epoxy system was developed through the in situ curing of bisphenol A type epoxy and 4,4′‐diaminodiphenylmethane with the sol–gel reaction of a phosphorus‐containing trimethoxysilane (DOPO–GPTMS), which was prepared from the reaction of 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) with 3‐glycidoxypropyltrimethoxysilane (GPTMS). The preparation of DOPO–GPTMS was confirmed with Fourier transform infrared, 1H and 31P NMR, and elemental analysis. The resulting organic–inorganic hybrid epoxy resins exhibited a high glass‐transition temperature (167 °C), good thermal stability over 320 °C, and a high limited oxygen index of 28.5. The synergism of phosphorus and silicon on flame retardance was observed. Moreover, the kinetics of the thermal oxidative degradation of the hybrid epoxy resins were studied. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2354–2367, 2003  相似文献   
58.
混沌经济学——混沌与分形   总被引:3,自引:0,他引:3  
本文给出作为混沌经济学的数学基础的混沌与分形的简短介绍 .  相似文献   
59.
A novel and cost-effective sol-gel process for preparation of MgAl2O4 spinel nanometer powders has been developed in this study. A solution of magnesium and aluminum nitrates in stoichiometric proportion was successfully embraced in the biology polysaccharide gel network, formed by the synergistic interaction between xanthan gum (XG) and locust bean gum (LBG) utilizing their broad-spectrum stability of salt tolerance and character of transformation from sol to gel on the condition of proper temperature and relative proportion of polymeric components. Dry gel could be obtained by vacuum dehydration of aqueous gel at low temperatures. Monolithic MgAl2O4 spinel nanometer powders were produced by calcining the dry gel above 800°C, with average crystallite size of 20 nanometers.  相似文献   
60.
研究了 2 0 0 0年 MCM— B题 ,将问题推广到有三层干扰的复杂情况 ,给出并严格证明了 ( k,1,1)问题的最优解  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号