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991.
992.
993.
You JS Yu XQ Zhang GL Xiang QX Lan JB Xie RG 《Chemical communications (Cambridge, England)》2001,(18):1816-1817
Novel chiral imidazole cyclophane receptors were synthesized by highly selective N-alkylation of the imadazolyl 1N-position of the bridged histidine diester 2 with the dibromide in the presence of NaH; these receptors exhibit good chiral recognition toward the enantiomers of L- and D-amino acid derivatives (up to KD/KL = 3.52, delta delta G0 = -3.11 kJ mol-1) in CHCl3 at 25.0 degrees C. 相似文献
994.
Design and characterization of helical ribbon assemblies of a bolaamphiphilic conjugated polymer and their color-coded transformation into nanofibers are described. An L-glutamic acid modified bolaamphiphilic diacetylene lipid was synthesized and self-assembled into right-handed helical ribbons with micron scale length and nano scale thickness under mild conditions. The ribbon structures were further stabilized by polymerizing well-aligned diacetylene units to form bisfunctional polydiacetylenes (PDAs). Transitions from flat sheets to helical ribbons and tubes were observed by transmission electron microscopy. The helical ribbons appear to originate from the rupture of flat sheets along domain edges and the peeling off between stacked lipid layers. These results point to the applicability of chiral packing theory in bolaamphiphilic supramolecular assemblies. Contact mode atomic force microscopy observations revealed that high order existed in the surface packing arrangement. Hexagonal and pseudorectangular packings were observed in flat and twisted regions of the ribbons, respectively, suggesting a correlation between microscopic morphologies and nanoscopic packing arrangements. The tricarboxylate functionalities of the bolaamphiphilic lipid provide a handle for the manipulation of the bisfunctional PDAs' morphology. Increasing solution pH caused the fraying of helical ribbons into nanofibers accompanied by a sharp blue-to-red chromatic transition. A dramatic change in circular dichroism spectra was observed during this process, suggesting the loss of chirality in packing. A model is proposed to account for the pH-induced morphological change and chromatic transition. The color-coded transition between two distinct microstructures would be useful in the design of sensors and other "smart" nanomaterials requiring defined molecular templates. 相似文献
995.
996.
Reported herein is an example of a solution-state cross-coupling cyclization with an outcome mediated by perfluorophenyl-phenyl electrostatic interactions. 相似文献
997.
In this paper, we consider the following forced higher-order nonlinear neutral difference equation
998.
D. P. Dryanov M. A. Qazi Q. I. Rahman 《Proceedings of the American Mathematical Society》2003,131(9):2741-2751
Extensions of two classical results about polynomials, one due to W. Markov and the other due to Duffin and Schaeffer, are obtained in this paper. An interesting result of S. Bernstein, which went unnoticed until it was rediscovered by P. Erdos, years later, is also generalized. Our results are especially amenable to numerical calculations, and may, therefore, be of some practical importance.
999.
Eisenstein BI Ernst J Gladding GE Gollin GD Hans RM Johnson E Karliner I Marsh MA Plager C Sedlack C Selen M Thaler JJ Williams J Edwards KW Sadoff AJ Ammar R Bean A Besson D Zhao X Anderson S Frolov VV Kubota Y Lee SJ Poling R Smith A Stepaniak CJ Urheim J Ahmed S Alam MS Athar SB Jian L Ling L Saleem M Timm S Wappler F Anastassov A Eckhart E Gan KK Gwon C Hart T Honscheid K Hufnagel D Kagan H Kass R Pedlar TK Thayer JB von Toerne E Zoeller MM Richichi SJ Severini H Skubic P Undrus A Savinov V 《Physical review letters》2001,87(6):061801
Using 12.7 fb(-1) of data collected with the CLEO detector at CESR, we observed two-photon production of the cc states chi(c0) and chi(c2) in their decay to pi(+)pi(-)pi(+)pi(-). We measured gamma(gammagamma)(chi(c))xB(chi(c)-->pi(+)pi(-)pi(+)pi(-)) to be 75+/-13(stat)+/-8(syst) eV for the chi(c0) and 6.4+/-1.8(stat)+/-0.8(syst) eV for the chi(c2), implying gamma(gammagamma)(chi(c0)) = 3.76+/-0.65(stat)+/-0.41(syst)+/-1.69(br) keV and gamma(gammagamma)(chi(c2)) = 0.53+/-0.15(stat)+/-0.06(syst)+/-0.22(br) keV. Also, cancellation of dominant experimental and theoretical uncertainties permits a precise comparison of gamma(gammagamma)(chi(c0))/gamma(gammagamma)(chi(c2)), evaluated to be 7.4+/-2.4(stat)+/-0.5(syst)+/-0.9(br), with QCD-based predictions. 相似文献
1000.
Pedro L. Q. Pergher 《Transactions of the American Mathematical Society》2001,353(1):175-189
Given a collection of real vector bundles over a closed manifold , suppose that, for some is of the form , where is the trivial one-dimensional bundle. In this paper we prove that if is the fixed data of a -action, then the same is true for the Whitney sum obtained from by replacing by . This stability property is well-known for involutions. Together with techniques previously developed, this result is used to describe, up to bordism, all possible -actions fixing the disjoint union of an even projective space and a point. 相似文献