Preparation,thermal properties,and flame retardance of epoxy–silica hybrid resins

A novel epoxy system was developed through the in situ curing of bisphenol A type epoxy and 4,4′‐diaminodiphenylmethane with the sol–gel reaction of a phosphorus‐containing trimethoxysilane (DOPO–GPTMS), which was prepared from the reaction of 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) with 3‐glycidoxypropyltrimethoxysilane (GPTMS). The preparation of DOPO–GPTMS was confirmed with Fourier transform infrared, ¹H and ³¹P NMR, and elemental analysis. The resulting organic–inorganic hybrid epoxy resins exhibited a high glass‐transition temperature (167 °C), good thermal stability over 320 °C, and a high limited oxygen index of 28.5. The synergism of phosphorus and silicon on flame retardance was observed. Moreover, the kinetics of the thermal oxidative degradation of the hybrid epoxy resins were studied. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2354–2367, 2003     

回填材料膨润土对放射性气体滞留能力模拟研究

利用各种分析手段对膨润土的物理特性进行了表征 .X射线衍射分析表明钠基膨润土呈典型的六方晶胞 ,晶胞参数是 :a轴 4 .913,c轴 5 .4 0 5 ;差热分析曲线在低温区和高温区有明显的吸热峰出现 ;元素分析钠、钾离子的含量大于钙、镁离子的含量 ,在性能上表现为钠质膨润土具有较强的离子交换能力 ;显微分析表明其表面呈皱隙状 ,测定比表面积高达 2 4 .5 2m2 /g;吸水率测定表明膨胀率大 ,说明它具有密封功能 ,可有效阻滞地下水的渗入 .利用SF6示踪技术 ,通过采集不同时间段取样池样品 ,分析样品中示踪气体浓度 ,绘制取样池示踪气体浓度随时间的变化关系曲线 ,根据费克扩散定律计算扩散系数 .实验结果表明 ,随着压实膨润土密度的增大 ,示踪气体扩散系数迅速减小 ,当密度大于 1.8g/cm3 时 ,扩散系数降至 10 -9m2 /s.研究结果表明 ,膨润土性能优化是通过在膨润土中添加适量的活性炭 ,可明显改善其对气体的阻滞能力 ;增加其对放射性气体滞留能力 ;添加少量的石英砂增加其机械性能、导热性和减少蠕变性 ,将引起对气体阻滞能力的下降 .综合考虑 ,在膨润土中各添加 5 %活性炭和石英砂 ,既对气体具有较好的滞留能力 ,又具有较好的工程特性 .     

三层干扰下的最优无线电信道问题的研究

研究了 2 0 0 0年 MCM— B题 ,将问题推广到有三层干扰的复杂情况 ,给出并严格证明了 ( k,1,1)问题的最优解     

CreditRisk+模型下商业银行经济资本配置研究

对金融资产风险的度量与经济资本的分配应该体现分散化效应,传统的V aR方式不能保证分散化效应的次可加性.本文讨论了基于T a ilV aR这一新的风险度量与经济资本分配标准,并在违约率均值不变情况下,对C red itR isk+模型下的商业银行经济资本分配进行了实证分析.     

Time-Resolved Femtosecond Degenerate Four-Wave Mixing in LiNbO3：Fe,Mg Crystal

Forward degenerate four-wave mixing （DFWM） processes are investigated with a femtosecond pulsed laser in lithium niobate crystal doubly-doped with magnesium and iron （LiNbO3：Fe, Mg）. The pulse energy dependence reveals a pure third-order nonlinear response, and the third-order nonlinear susceptibility x^（3） in the material is evaluated to be 4.96 × 10^-13 esu. The time-resolved DFWM process shows a response time of x^（3） shorter than 100fs, which is due to the nonresonant electronic nonlinearities. Our results indicate that LiNbO3 crystals have potentials for ultrafast real-time optical processing systems, which require a large and fast x^（3） optical nonlinearity.     

Experimental 511 W Composite Nd：YAG Ceramic Laser

We demonstrate a 511 W laser diode pumped composite Nd：YAG ceramic laser. The optical pumping system is consisted of five laser diode stacked arrays arranged in a pentagonal shape around the ceramic rod whose size is φ6.35×144mm. When the pumping power is 1600 W, the cw laser output up to 511 W at 1064nm can be obtained with a linear piano-piano cavity, and the optical-to-optical efficiency is 31.9%. To our knowledge, this is the highest value of laser output by using a newly invented composite Nd：YAG ceramic rod as the gain medium.     

雷电的形成威力及预防

雷电灾害严重危及生命和财产的安全。因此，了解雷电成因，既有助于认识雷电的危害性，又可加强人类对雷电的防护。     

Regression quantiles for unstable autoregressive models

This paper investigates regression quantiles (RQ) for unstable autoregressive models. The uniform Bahadur representation of the RQ process is obtained. The joint asymptotic distribution of the RQ process is derived in a unified manner for all types of characteristic roots on or outside the unit circle. It involves stochastic integrals in terms of a sequence of independent and identically distributed multivariate Brownian motions with correlated components. The related L-estimator is also discussed. The asymptotic distributions of the RQ and the L-estimator corresponding to the nonstationary componentwise arguments can be transformed into a function of a normal random variable and a sequence of i.i.d. univariate Brownian motions. This is different from the analysis based on the LSE in the literature. As an auxiliary theorem, a weak convergence of a randomly weighted residual empirical process to the stochastic integral of a Kiefer process is established. The results obtained in this paper provide an asymptotic theory for nonstationary time series processes, which can be used to construct robust unit root tests.     

Some New uniform frames with block size four and index one or three

In this paper, some new uniform frames with block size four and index one or three are obtained. The known existence results for (4,1)‐frames and (4,3)‐frames are both improved to the extent that only a finite number of possible exceptions remain. © 2003 Wiley Periodicals, Inc.