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981.
Inside Back Cover: Controlled Electropolymerization of Ruthenium(II) Vinylbipyridyl Complexes in Mesoporous Nanoparticle Films of TiO (Angew. Chem. Int. Ed. 19/2014) 下载免费PDF全文
982.
Hao Sun Xiao You Yishu Jiang Guozhen Guan Xin Fang Jue Deng Peining Chen Dr. Yongfeng Luo Prof. Huisheng Peng 《Angewandte Chemie (International ed. in English)》2014,53(36):9526-9531
Electrically conducting wires play a critical role in the advancement of modern electronics and in particular are an important key to the development of next‐generation wearable microelectronics. However, the thin conducting wires can easily break during use, and the whole device fails to function as a result. Herein, a new family of high‐performance conducting wires that can self‐heal after breaking has been developed by wrapping sheets of aligned carbon nanotubes around polymer fibers. The aligned carbon nanotubes offer an effective strategy for the self‐healing of the electric conductivity, whereas the polymer fiber recovers its mechanical strength. A self‐healable wire‐shaped supercapacitor fabricated from a wire electrode of this type maintained a high capacitance after breaking and self‐healing. 相似文献
983.
Dr. Cheng‐Chung Lee Dr. Manuel Maestre‐Reyna Dr. Kai‐Cheng Hsu Prof. Dr. Hao‐Ching Wang Prof. Dr. Chia‐I Liu Prof. Dr. Wen‐Yih Jeng Li‐Ling Lin Richard Wood Dr. Chia‐Cheng Chou Prof. Dr. Jinn‐Moon Yang Prof. Dr. Andrew H.‐J. Wang 《Angewandte Chemie (International ed. in English)》2014,53(48):13054-13058
Crown ethers are small, cyclic polyethers that have found wide‐spread use in phase‐transfer catalysis and, to a certain degree, in protein chemistry. Crown ethers readily bind metallic and organic cations, including positively charged amino acid side chains. We elucidated the crystal structures of several protein‐crown ether co‐crystals grown in the presence of 18‐crown‐6. We then employed biophysical methods and molecular dynamics simulations to compare these complexes with the corresponding apoproteins and with similar complexes with ring‐shaped low‐molecular‐weight polyethylene glycols. Our studies show that crown ethers can modify protein surface behavior dramatically by stabilizing either intra‐ or intermolecular interactions. Consequently, we propose that crown ethers can be used to modulate a wide variety of protein surface behaviors, such as oligomerization, domain–domain interactions, stabilization in organic solvents, and crystallization. 相似文献
984.
Tunable Surface‐Enhanced Raman Scattering from High‐Density Gold Semishell Arrays with Controllable Dimensions 下载免费PDF全文
Xianzhong Lang Dr. Jiaqi Li Xiaoguang Luo Yan Zhang Yin Yin Prof. Teng Qiu 《Chemphyschem》2014,15(2):337-343
A convenient reproducible technique is reported for the fabrication of large‐area gold semishell arrays by mechanically pressing porous anodic alumina (PAA) stamps into gold/polymer bilayer structures that serve as robust and cost‐efficient surface‐enhanced Raman‐scattering (SERS) substrates. The surface structure can be tuned further to optimize the enhancement factor according to optional PAA fabrication parameters and imprinting pressures. Finite‐difference time‐domain calculations indicate that the structure may possess excellent SERS characteristics due to the high density and abundance of hot spots. 相似文献
985.
建立了饲料中克仑特罗、莱克多巴胺、喷布特罗、妥布特罗等18种β-兴奋剂的QuEChERS结合高效液相色谱-串联质谱的检测方法。饲料样品加水分散后经4%(v/v)氨水乙腈提取,加入25 mg十八烷基硅烷(C18)和50mg N-丙基乙二胺(PSA)吸附剂分散固相萃取净化后,以高效液相色谱-串联质谱进行定性和定量分析。采用Agilent Zorbax Eclipse XDB-C18(50 mm×4.6 mm,1.8μm)分析柱,以甲醇-0.1%(v/v)甲酸水溶液为流动相进行梯度洗脱,串联质谱在多反应监测(MRM)正离子模式下进行检测,基质外标法定量。结果表明,18种待测物在质量浓度为5~200μg/L范围内线性关系良好,相关系数为0.9912~0.9995;在0.05、0.1、0.5 mg/kg 3个浓度加标水平下,饲料中18种β-兴奋剂的平均回收率为78.4%~107.1%,相对标准偏差(RSD)为3.5%~12.3%,定量限(以信噪比≥10计)均为0.05 mg/kg。该方法准确、灵敏,前处理简单,可作为饲料中克仑特罗等18种β-兴奋剂筛选和确认的检测方法。 相似文献
986.
采用电弧放电法,通过阳极棒与不锈钢片的共蒸发,制备了氮掺杂长竹节状碳纳米管(NDLBLCNTs)。借助扫描电子显微镜(SEM)、场发射高分辨透射电子显微镜(HRTEM)及其附带能量色散X射线(EDX)光谱仪和电子能量损失谱(EELS)、透射电子显微镜(TEM)等表征方法,对产物的形貌、结构和组成进行表征。表征结果表明,NDLBLCNTs的长度在640~835 nm之间,其内径在23~35 nm之间,外径在28~47 nm之间;且在每一节"竹节"与另一节"竹节"的连接处形成的内腔中均有一个黑色纳米颗粒,其直径尺寸以及产物中的NDLBLCNTs的含量均与熔化、蒸发的不锈钢片的面积有关。对NDLBLCNTs的生长机理进行了简单的探讨。 相似文献
987.
A simple, cheap and non-enzymatic colorimetric strategy for glucose detection has been designed based on the interactions between a phenylboronic acid (PBA) derivative, which is coupled with gold nanoparticles (AuNPs) as the colorimetric reporters, and glucose. The PBA-AuNPs hybrid system proposed here exhibits ordered photochemistry behaviors upon the addition of glucose at different pH values. There are two linear regions of glucose concentration for the glucose sensor at different pH values, i.e., between 0.1 mmol/L and 9.8 mmol/L at pH 6 with the detection limit of 64μmol/L and between 0 and 6.5 mmol/L with the detection limit of 48 μmol/L at pH 9, respectively. To test the practicality of the sensor system, we also applied this assay to detect a glucose sample in the artificial saliva. 相似文献
988.
Beryllium fluorides are widely used in protein phosphorylation studies to get stable transition state analogs or near attack conformers, which has attracted much attention. BeF3? is one of the optimal phosphoryl (PO3?) analogs for its identical geometry and charge, and Mg2+ naturally participates in the phosphoryl binding in biological systems. In solutions, BeF3? coexists with other beryllium fluorides (BeF42?, BeF2 and BeF+) and magnesium fluorides, and there are equilibriums between these species. In this article, 19F NMR spectroscopy was applied to the investigation of the impact of magnesium(II) on beryllium fluorides. It has been found that when Mg2+ was introduced into the solutions, the chemical shifts, the intensities and the line widths of 19F signals of various beryllium fluoride complexes were changed. After ionic strength correction, these effects were remarkable only for BeF42? and BeF3?, especially BeF42?, when the concentration of the fluoride ion is relatively low. Mechanism of the effects is proposed which involves ion pair formation between Mg2+ and beryllium fluorides. 相似文献
989.
Two calix[4]arene derivatives containing 1,2,3-triazole moiety were synthesized via K2CO3-catalyzed1,3-dipolar cycloaddition reaction between calix[4]arene-based azide and active methylene compounds in good yields.The structures of the two compounds synthesized herein were fully confirmed by 1HNMR,,(13)C NMR,and MS(ESI).The thermal analysis showed that the mass losses of the synthesized compounds 4 and 5 containing 1,2,3-triazole groups are similar to each other. 相似文献
990.
研究了N2/Ar介质阻挡放电处理对负载CuO的TiO2可见光光催化活性的影响.采用X射线衍射、紫外-可见分光吸收光谱、透射电镜、X射线光电子能谱和电子自旋共振进行了表征,详细考察了等离子改性参数包括气氛组成、处理时间和处理功率对改性效果的影响,并通过降解甲基橙溶液考察了可见光光催化活性.结果表明,最佳等离子处理条件为N2与Ar比例为8:2,处理时间为20 min,放电电流为1.0 A.最后,使用改性后的光催化剂对模拟含汞废水进行了处理. 相似文献